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211.
废弃饱和盐水钻井液的固液分离 总被引:2,自引:0,他引:2
采用化学破胶脱稳和压滤机械分离的化学强化固液分离技术处理江汉油田废弃饱和盐水钻井液(简称废钻井液).最佳固液分离工艺为:调节废钻井液的pH为6.5左右,先加入无机破胶剂(HWJ),HWJ的加入量为15 000 mg/L,以400 r/min的转速搅拌3 min,稀释1倍后,再加入有机破胶剂(HYJ),HYJ的加入量为300 mg/L,以120 r/min的转速搅拌5min.固液分离结果表明,分离后出水率达68.2%,而泥饼湿含量只有55.8%,废钻井液的COD由67 886.8 mg/L降至8 898.9 mg/L. 相似文献
212.
渗透汽化复合膜分离废水中的低浓度甲醇 总被引:3,自引:1,他引:2
采用两种商品化渗透汽化复合膜--GKSS-GS膜和PDMS-P膜分离模拟低浓度甲醇废水,考察了操作温度、甲醇质量分数、废水流量对膜渗透汽化性能的影响.实验结果表明:随温度升高、废水中甲醇质量分数的增大,两种膜的渗透通量都呈增加趋势;GKSS-GS膜的分离系数变化较明显,而PDMS-P膜的分离系数变化较小;废水流量对渗透通量和分离系数的影响均较小.在最佳条件下,GKSS-GS膜的渗透通量为914.6 g/(m~2·h),分离系数为5.6;PDMS-P膜的渗透通量为1 887.2 g/(m~2·h),分离系数为4.8. 相似文献
213.
Takanori Hino Ryuichi Agawa Youichi Moriya Minoru Nishida Yasuhiro Tsugita Takao Araki 《Journal of Material Cycles and Waste Management》2009,11(1):42-54
Waste printed circuit boards contain valuable metals such as Au, Pd, Ag, and Cu that can be reutilized and harmful elements
such as Pb, Br, and Cr that must be removed from the viewpoint of environmental conservation. In this research, we examined
a method that separates the materials from printed circuit boards contained in discarded personal computers. After cutting
the printed circuit boards to a size of 20 × 20 mm, they were heated at 873 K under an Ar atmosphere to remove organic resins
containing elements such as C, H, and N. After heat treatment, the printed circuit boards were crushed using a planetary ball
mill and the pulverized powders were filtered. The fraction with a granularity of greater than 250 μm was separated into magnetic
and nonmagnetic materials by a magnetic field. Because the fraction with a granularity of less than 250 μm contained 39 mass%
of C, it was heated at 1273 K in an atmosphere of 95% Ar and 5% O2 to allow carbon combustion to take place, followed by metal reduction processing at the same temperature in an atmosphere
of 97% Ar and 3% H2. The basicity of the resulting powder was adjusted and the powder was heated at 1773 K under an Ar atmosphere. The proposed
method separated the slag and metal, and 80% of the valuable metals contained in printed circuit boards could be collected. 相似文献
214.
215.
Manfred Fehr 《Environment, Development and Sustainability》2009,11(2):319-328
As biodegradable material represents approximately 70% of household waste in Brazil, any strategy to divert appreciable waste
quantities from landfills of necessity has to include valorization and recycling of this material. A societal change of attitude
is required to perceive this challenge. Experiments in an urban apartment building are described that produced this change
of attitude with a success factor of 80%. Divided waste collection was implemented that separated at the source biodegradable
from inert material. Correct collection, handling and display procedures were established. Composting of biodegradable material
was carried out under the rooftop of the building as an alternative to using it as animal feed. Half of the inert material
entered the reverse logistics chain and was also diverted from the landfill. Waste related material flow through the building
is completely quantified, food intake and waste production are related, diversion of both biodegradable and inert waste components
from the landfill is measured and the composting process is described. The landfill diversion stands at 61%, mass reduction
through the composting process is 80% and matured compost is returned to residents for use in flower cages. The system has
been operational for two years and stands out as a precedent in successful decentralized household waste management supported
by material flow analysis.
Readers should send their comments on this paper to: BhaskarNath@aol.com within 3 months of publication of this issue. 相似文献
216.
217.
Permeation of Cu(II) from its aqueous solution through a supported liquid membrane (SLM) containing di(2-ethylhexyl)phosphoric acid (D2EHPA) carrier dissolved in coconut oil has been studied. The effects of Cu(II), pH (in feed), H2SO4 (stripping) and D2EHPA (in membrane) concentrations have been investigated. The stability of the D2EHPA-coconutoil has also been evaluated. High Cu(II) concentration in the feed leads to an increase in flux from 4.1 × 10-9 to 8.9 × 10-9 mol/(m2·s) within the Cu(II) concentration range 7.8×10-4-78.6×10-4 mol/L at pH of 4.0 in the feed and 12.4 × 10-4 mol/L D2EHPA in the membrane phase. Increase in H2SO4 concentration in strip solution leads to an increase in copper ions flux up to 0.25 mol/L H2SO4, providing a maximum flux of 7.4 × 10-9 mol/(m2·s). The optimum conditions for Cu(II) transport are, pH of feed 4.0, 0.25 mol/L H2SO4 in strip phase and 12.4 × 10-4 mol/L D2EHPA (membrane) in 0.5 (m pore size polytetrafluoroethylene (PTFE) membrane. It has been observed that Cu(II) flux across the membrane tends to increase with the concentration of copper ions. Application of the method developed to copper plating bath rinse solutions has been found to be successful in the recovery of Cu(II). rane. It 相似文献
218.
Crosslinkable poly(4-methyl-2-pentyne) (PMP) membranes were cast from carbon tetrachloride solutions containing PMP and either 4,4′-diazidobenzophenone or 4,4′-(hexafluoroisopropylidene)diphenyl azide. The composite membranes were transparent and homogeneous and were crosslinked by UV irradiation at room temperature or thermal treatment at 180 °C. Low levels of the bis(aryl azide) (1–4.5 wt%) were effective in rendering the membranes insoluble in cyclohexane and carbon tetrachloride, both are good solvents for PMP, thus PMP can easily be converted to mechanically stable membranes with permeabilities and selectivities comparable or higher than those of the well-known poly(dimethylsiloxane) (PDMS). The permeabilities of O2, N2, H2, CH4 and CO2 were measured. Compared to pure PMP, the crosslinked membranes containing bis(aryl azide) had lower permeabilities and higher selectivities, consistent with a reduction in free volume. 相似文献
219.
220.
印染废水处理的磁混凝-高梯度磁分离协同作用 总被引:8,自引:3,他引:5
混凝过程作为工业废水的预处理技术普遍受到重视,在混凝过程中降低污泥产生量并提高污泥分离速度是该技术发展的方向,基于上述目标,通过将磁粉引入絮体使之磁化并在自行研制的高梯度磁分离装置中实现磁混凝与磁分离的协同作用.以高浊度的印染废水作为试验废水,以色度、COD及SS作为考核指标,重点考察了磁混凝反应及磁分离的影响因素.当印染废水的色度约为900倍、COD约为595 mg/L、SS约为500 mg/L时,在pH=8.5、FeSO4500 mg/L、PAM3.5 mg/L、磁粉400 mg/L的适宜磁混凝反应条件下,相应指标去除率比传统混凝法分别高出17.3%、21.7%及24.2%,此时絮团沉降速度增大了64.3%,污泥体积减少了61%,污泥压缩比为0.39.在电流强度8 A、流速2.5 L/min和介质填充率1%的操作条件下,该磁性絮体流经高梯度磁分离装置时的水力表面负荷达到61.0 m3/m2·h,处理出水达到国家二级排放标准. 相似文献