Surface Consolidation of Pentelic Marble: Criteria for the selection of methods and materials - The Acropolis case (6 pp)

Goal and Scope In order to realize surface consolidation of Pentelic marble on the Acropolis monuments, we have collected the criteria that have to be fulfilled by the methods and materials without side effects on the marbles (and other stones). When the existing methods and materials did not satisfy the requirements (criteria), we invented new ones.Methods The criteria were collected from the literature, by thermodynamic and kinetic viewpoints, by laboratory experiments and in situ observations on monuments, both in Greece and in several countries in which the various methods and materials were applied. Concerning our method of ‘Inversion of sulfation’, performed by spraying a K2CO3 solution, its concentration and its temperature were controlled in order to have a total inversion (certified by liquid crystals) of gypsum back to CaCO3. For the new material of ours, ‘Reinforced Lime’, in order to eliminate the disadvantages of plain lime (low carbonation rate, low mechanical properties of CaCO3 formed, lack of carbonation in the bulk of lime), measurements of the rate of carbonation were performed in plain lime and in lime with a different CaCO3 concentration beforehand as well as in a different CO2 environments, using DTG and XRD to measure the rate of carbonation. The detachment (kg/cm2) of marble specimens stuck by lime in each case was also measured. A microscope was also used to measure the dimensions of the grain in each case as well as ammonium citrate and thymolphthalein to certify the depth of carbonation in each case. Part of the work was communicated in an international congress.Results A table with the criteria of the selection of the methods and materials for the consolidation of Pentelic marble surfaces (and other stones) was established. None of the employed methods and materials fulfilled the criteria. Only the ‘Inversion of gypsum ‘ and the ‘Reinforced Lime’ were adopted and applied to the Acropolis monuments and to other monuments in Greece and in several other countries.Recommendation and Outlook All criteria must be used for the selection of methods and materials for the consolidation of the monument surfaces. This is why we have already studied with the same procedures, methods and materials for restoration, surface cleaning and protection.     

焦炉装煤烟尘治理方案的探讨

焦炉装煤烟尘含有害物质，污染环境，危害人体健康。袋式除尘器的使用，消除了烟尘的污染，但因投资大、运行费用高、操作复杂，难以得到快速、广泛的推广。根据实验结果和已有应用情况，本文推荐了三相流化床除尘装置和颗粒层除尘器，它们可用于焦炉装煤烟尘治理，其投资和运行费用会大大降低。     

Measurements of peroxyacyl nitrates (PANS) in Mexico City: implications for megacity air quality impacts on regional scales

Peroxyacyl nitrates (PANs) were measured using gas chromatography with electron capture detection (GC/ECD) in north central Mexico City during February–March of 1997. Peroxyacetyl nitrate (PAN) was observed to exceed 30 ppb during five days of the study, with peroxypropionyl nitrate (PPN) and peroxybutryl nitrate (PBN) reaching 6 and 1 ppb maximum, respectively. Levels of total PANs typically exceeded 10 ppb during the period of measurement and showed a very strong diurnal variation with PANs maximum during the early afternoon and falling to less than 0.1 ppb during the evening hours. These levels of PANs are the highest reported values in North America (and the world) for an urban center, since levels of approximately 30 ppb were reported during the late 1970s in the Los Angeles area (South Coast Air Basin, Tuazon et al., 1978). Hydrocarbon measurements indicate that the levels of olefins, specifically butenes are significant in Mexico City. A time series taken of source indicator hydrocarbons taken before and during a Mexican National Holiday with reduced automobile traffic clearly show that mobile sources of butenes are as important as liquefied petroleum gas. Observations of 10–40 ppb C methyl-t-butyl ether (MTBE) are consistent with MTBE/gasoline fuel usage as a source of isobutene and formaldehyde. Both these reactive species can lead to increased oxidant and PAN formation. The strong diurnal profiles of PANs are consistent with regional clearing of the Mexico City air basin on a daily basis. Estimates are given using a simple box model calculation for a number of key primary and secondary pollutant emissions from this megacity on an annual basis. These calculations indicate that megacities can be important sources of both primary and secondary pollutants, and that PANs produced in megacity environments are likely to contribute strongly to regional scale ozone and aerosol productions during long range transport.     

宁波市城市污水处理厂污泥处置方案探讨

随着城市污水处理率提高导致的污水污泥产量的增长趋势也使得污水污泥的处理问题更为突出。在总结国内外城市污泥处置技术发展趋势的基础上,结合宁波市的实际情况,根据无害化、减量化和资源化的原则,提出城市污泥近远期处置方案,并对处置方案作出可行性分析。     

氧化亚铁硫杆菌对亚铁离子的氧化及其动力学研究

采用9K培养基研究了氧化亚铁硫杆菌氧化Fe^2＋过程中,pH和氧化还原电位的变化规律,并对Fe^2＋的氧化过程进行动力学分析,确定了其反应级数及反应速率常数。结果表明,（1）在温度为30℃,摇床转速为150r／min的条件下,氧化亚铁硫杆菌的最佳接种量为10．0％;（2）Fe^2＋初始质量浓度在11．39～21．72g／L时,随着浓度的增大,Fe^2＋达到100％转化率需要的时间增加;（3）氧化亚铁硫杆菌对Fe^2＋的氧化可近似看作一级反应,反应速率常数为0．0527～0．0788h。     

基于化工园区整体风险量分析的安全规划研究

通过对园区安全容量和危险量的分析,得到园区整体的风险评估值;提出并定义园区危安比最大临界点,用其反映园区的最大可接受风险量;运用"二八法则",确定危安比上限;当危安比在3种不同值域区间下,对应的园区安全规划的重点不同;从园区整个生命周期考虑,提出包含各个阶段的园区安全规划主要内容。     

采掘诱发地震的成因及对策

根据煤或岩体的赋存特征及采动后的受力特点，将采矿及掘进等工程进行过程中诱发的地震灾害分为三类，即完整煤岩体受压应力作用的失稳、顶底板受拉应力型地震及断层走滑受剪型诱发地震。文章在分别分析其成因的基础上，研究了采矿诱发三种类型地震的发生条件，提出了防治发生诱发地震的对策。     

论湘中城市群经济的融合耦动与可持续发展

本文以湘中（长株潭）城市群作为研究对象,概述了湘中城市群经济融合的总体特征,对其城市群空间生长演化过程中存在的问题和应采取的对策,经济如何实现可持续发展进行了探讨。     

农地整治权属调整中农户认知对行为响应的作用机制--基于改进TPB及多群组SEM

农地整治权属调整是实现农业规模化和现代化的重要手段,而农户有效参与是推动权属调整的内在动力,研究农地整治权属调整中农户认知对其行为响应的作用机制,有助于高效引导农户参与权属调整,并为制定农地整治权属调整的政策提供科学依据。基于改进计划行为理论和湖北省11个县(市、区)1044份农户抽样调查数据,采用多群组结构方程模型探究了农地整治权属调整中不同类型农户认知对其行为响应的作用机制。结果表明:农地整治权属调整中农户行为逻辑符合改进计划行为理论,农户的行为态度、主观规范、知觉行为控制交互影响行为意愿,进而转换为行为响应,政府支持在行为意愿和行为响应之间起到部分中介作用。总体上,农户行为响应是"自发性""诱发性"和"约束性"三重行动逻辑的结合,且"自发性"占主导地位。多群组结构方程估计结果表明,纯农型与兼业Ⅰ型农户的行为响应受到"自发性""诱发性"和"约束性"三重影响,兼业Ⅱ型农户受到"自发性"和"诱发性"双重影响,非农型农户仅受到"诱发性"单一影响。因此,为引导农户积极参与农地整治权属调整,应该分别针对各类农户相应地提高其参与的"自发性"和"诱发性",降低"约束性",充分发挥农村社会经济组织的作用,将四种不同类型农户的利益需求统筹考虑,降低权属调整过程中利益协调难度。     

社会资本对农村贫困代际传递影响机制研究

社会资本在反贫困领域的重要作用已被理论和实践所证实。在新时代脱贫攻坚的决胜阶段,有效发挥社会资本的周急济贫功能,缓解乃至阻断贫困代际传递,已成为当前反贫困战略推进中亟待探讨的问题。研究整合了四期中国家庭追踪调查(CFPS 2010、2012、2014、2016)个体家庭和村庄的嵌套数据,建立了“认知型”和“结构型”两种类型以及“个体家庭”和“村庄”两个层级的社会资本框架,并基于探索性因子分析构建了社会网络、社会信任、社会声望、社会参与、集体参与以及公共服务6个社会资本变量。研究利用HLM软件构建了多层广义线性模型(HGLM),通过四阶段的空模型、截距模型、随机效应模型以及完整模型分析了绝对贫困背景下社会资本对农村贫困代际传递的影响机制。研究结果表明:①个体社会资本总量与贫困代际传递呈显著负相关。②在个体家庭层面,社会网络、社会声望、社会参与对贫困代际传递有显著负向影响,但社会信任和地方信任对贫困代际传递的影响并不显著。③在村庄层面,公共服务对贫困代际传递具有显著负向影响,集体参与对贫困代际传递具有显著正向影响,且公共服务水平对社会网络和贫困代际传递具有正向调节作用。研究提出要大力培植贫困群体和乡村两个层级的社会资本以缓解农村贫困代际传递趋势:①要通过协调“乡政”与“村治”以形成良性的乡村治理格局。②要促进精准扶贫与乡村振兴战略紧密衔接,在保障个体脱贫的同时完善农村公共服务及基础设施建设,推进城乡基本公共服务均等化;③须提振贫困群体脱贫信心,增强村级自治与集体参与的水平和能力。