碱性化学镀镍废液的净化处理

找到了一种处理碱性化学镀镍废液的新方法 ,研究了镀液组成、温度、时间、漂白粉浓度对化学镀镍废液处理结果的影响。结果表明 ,用漂白粉处理碱性化学镀镍废液是可行的。     

煤系高岭土开发利用中存在的问题与对策

煤炭行业开发利用煤系高岭土具有许多有利的条件,但也存在一些问题。作者针对目前煤系高岭土开发利用中存在的问题提出了相应的对策,以供有关决策部门参考。     

高浓度臭氧水溶液研究

采用涡流叶轮泵、射流器和喷嘴等物理方法可将高浓度臭氧气体（＞100g/m³）有效地溶解于水,使臭氧溶解率达到98.6％,臭氧水溶液的臭氧浓度达到8.06g/m³,生成无残留物的绿色强氧化药剂、强消毒杀菌剂．     

复配表面活性剂水溶液处理甲苯气体的研究

以非离子表面活性剂吐温-20(Tween-20)为主表面活性剂,添加助表面活性剂十二烷基苯磺酸钠(SDBS)以及助剂氯化钠,形成复配水溶液吸收剂处理VOCs废气.以甲苯为VOCs的典型代表,研究了Tween-20,Tween-20/SDBS和Tween-20/SDBS/氯化钠3种水溶液吸收剂的临界胶束浓度(CMC)及其对甲苯去除率的影响.结果表明,当表面活性剂浓度达到CMC时,水溶液对甲苯的吸收效果开始明显增强,加入助表面活性剂SDBS和助剂氯化钠有利于甲苯的去除,同时可降低溶液的CMC,减少表面活性剂的用量,降低水溶液吸收法处理VOCs成本.当空气流量G为300mL/min、液体喷淋量L为75mL/min、进口甲苯浓度800mg/m3、温度T为30℃时,分别以Tween-20、Tween-20/SDBS(摩尔比1/4)和Tween-20/SDBS/氯化钠(摩尔比1/4/0.1)的水溶液为吸收剂,且浓度均为1CMC时,甲苯去除率分别为56%、70%和77%,三元复配表面活性剂水溶液的吸收效果最佳.     

Optimization of methyl orange removal from aqueous solution by response surface methodology using spent tea leaves as adsorbent

The effective disposal of redundant tea waste is crucial to environmental protection and comprehensive utilization of trash resources. In this work, the removal of methyl orange （MO） from aqueous solution using spent tea leaves as the sorbent was investigated in a batch experiment. First, the effects of various parameters such as temperature, adsorption time, dose of spent tea leaves, and initial concentration of MO were investigated. Then, the response surface methodology （RSM）, based on Box- Behnken design, was employed to obtain the optimum adsorption conditions. The optimal conditions could be obtained at an initial concentration of MO of 9.75 mg·L-1, temperature of 35.3℃, contact time of 63.8 min, and an adsorbent dosage 3.90 g· L-1. Under the optimized condi- tions, the maximal removal of MO was 58.2%. The results indicate that spent tea leaves could be used as an effective and economical adsorbent in the removal of MO from aqueous solution.     

改良ADA法脱硫废液中硫氰酸钠的分离研究

以乙醇和丙酮的混合液作为溶析剂,采用溶析结晶法从改良ADA法脱硫废液中分离硫氰酸钠。考察了结晶温度、溶析剂配比(V丙酮/V乙醇)、溶析剂/脱硫废液体积比、流加速率和搅拌速率对硫氰酸钠提取率的影响,通过单因素和正交实验确定了硫氰酸钠的最佳提取条件。结果表明,当温度为35℃,流加速率为160 mL/h,溶析剂/脱硫废液体积比为3,搅拌速率为150 r/min,溶析剂配比为V丙酮/V乙醇=2时,分离效果最好,在此条件下硫氰酸钠提取率为95.37%。     

基于Fluent软件的角联通风网络数值模拟

首先采用拟牛顿法(Broyden方法),基于MATLAB编程对地下矿山角联通风网络进行了编程解算,此种方法避免了复杂的数学方程建立过程,使解算过程在计算机上便可全部完成,并且收敛快,精度高。通过对解算结果的对比分析,可以了解角联分支对通风系统的影响,论文重点通过FLUENT软件,对角联通风网络进行了数值模拟,分别模拟了角联分支内有风流流过以及无风流流过的情况,通过选取不同的通风巷道截面,观察速度云图以及矢量图等,可以清楚的看到角联巷道内风流的特性以及效果,为角联巷道内风流特性的研究提供了一定的依据,文章最后指出了在矿山实际情况中,在处理角联通风网络时应注意的一些问题。     

焙烧条件对废干电池中汞的释放影响研究

在小型管式炉中进行废干电池的焙烧实验,分析了焙烧温度、时间及其交互作用对汞释放的影响.结果表明,焙烧时间对汞释放影响最大,温度也有显著影响,它们对汞释放有交互作用且作用显著,废干电池焙烧过程中汞在低温下更易释放.在温度650 ℃,焙烧时间120 min情况下,汞释放率达99%以上.焙烧前后干粉的X衍射分析结果表明,焙烧后电池中含有的晶态物增加,结构更复杂.     

UNSATURATED FLOW THROUGH SOLID WASTE LANDFILLS: MODEL AND SENSITIVITY ANALYSIS1

ABSTRACT: The movement of precipitation water infiltrating through the material (refuse) of solid waste landfills is examined via numerical solution of the equations of continuity, and motion (Darcy's Law). The solution of the equations is obtained by a fully implicit, finite-difference scheme. Both unsaturated and saturated surface conditions are considered, making the scheme suitable for real-time simulation of net precipitation and moisture redistribution events. A sensitivity analysis showed that for unsaturated surface conditions the solution is primarily affected by hydraulic conductivity and capillary diffusivity, and is relatively independent of the space and time steps. In addition, the precipitation averaging process is shown to be critical in the correct computation of moisture transport during the time period where the transition from unsaturated to saturated conditions occurs. The model presented herein is suitable for analysis of water movement through landfills, and the design of bottom collection systems.     

COD_(Cr)分析废液中银的回收再利用研究

COD_(Cr)分析中使用的硫酸银属于重金属溶液,若直接排入下水道,对环境影响较大,而且也是对贵重金属的浪费。文章对COD_(Cr)分析废液中银的回收进行了实验研究,将废金属银回收,配制成硫酸银溶液回用于实验中,与购买的硫酸银溶液相比,误差在可接受范围内。