Evaluation of the spontaneous combustion characteristics of coal of different metamorphic degrees based on a temperature-programmed oil bath experimental system

Research on the micro- and macrocharacteristics of different metamorphic degrees of coal helps improve the control and protection techniques used during spontaneous combustion. Nine coals with different properties were thoroughly investigated in this study. Fourier transform infrared spectroscopy and a self-designed temperature-programmed oil bath experimental system were adopted to analyze the molecular structure and macrocharacteristic parameters of the spontaneous combustion of coal. Additionally, the influence of particle size on spontaneous combustion was considered. Various functional groups were employed as microcharacteristic parameters to capture the principal active groups in oxidation. The gas production rate, oxygen consumption rate, gas concentration, heat energy release rate, and characteristic temperatures were evaluated as macrocharacteristic parameters to investigate the changes in coal during oxidation. The results establish that the microcharacteristics of coal molecules determine the degree of spontaneous combustion based on intrinsic properties and that changes in the macrocharacteristics of the spontaneous combustion of coal reflect the microstructural changes. The contents of the hydroxyl groups, carbonyl groups, alkyl ether and aryl ether in the coal molecules gradually decrease with the metamorphic increase. Oxygen-containing functional groups have higher reactivities and easily react with oxygen, causing the macroparameters, such as the oxygen consumption rate, the gas generation rate and the heat energy release rate, to consistently decrease with the increase of the metamorphic degree. Small-particle-size coal molecules have more active aliphatic hydrocarbons, oxygen-containing functional groups and a larger specific surface area, increasing the chances of adsorbing the oxygen of active groups and promoting the reaction between coal and oxygen. The experimental results indicate that coal samples with higher metamorphic degrees or larger sizes exhibit lower tendencies toward spontaneous combustion. Evaluation of the spontaneous combustion of coal based on a temperature-programmed oil bath experimental system is of great practical importance for preventing the spontaneous combustion of coal during storage, processing and utilization and can serve as a convenient reference for production safety in mining applications.     

西部水资源开发利用风险现状评价

我国实施西部大开发战略后,西部水资源开发利用问题变得越来越突出.为了弄清楚西部水资源开发利用存在的风险现状,本文在风险概念的基础上探讨了水资源开发利用风险概念和影响因素,并构建了西部水资源开发利用风险评价指标体系.根据水资源系统表现出多模态、突跳和发散的基本突变特征,论述了运用突变理论评价水资源开发利用风险具有一定的可行性,将突变理论引入到水资源开发利用风险评价中,对西部水资源开发利用风险进行评价.首先对各项风险评价指标按照重要性排序,并对各指标值进行无量纲化;然后利用突变模型的归一公式和突变模型的评价准则进行递归运算,最后求出各层指标相对风险值(突变隶属度),将评价结果与风险等级对照,综合判断和分析各层各项指标相对风险状况.计算结果表明:在西部12个省份中,各层指标的风险值差异显著,但是水资源开发利用综合风险值分布在0 66-0.92之间,总体上属于中高度风险水平,12省份风险从小到大排序为:西藏→陕西→重庆→四川→青海→云南→贵州→广西→内蒙→甘肃→新疆→宁夏,这一结果与西部12省份水资源开发利用实际状况相符,可以为西部大开发过程水资源合理有效利用和管理提供风险决策参考依据.     

中国土地财政地域差异与转型研究

土地财政是当前政府管理中的热点问题,分地域研究土地财政差异情况,对于提出科学合理的转型对策具有重要的理论与现实意义.总结土地财政各项收入来源发展概况,考虑土地储备抵押融资为借债收入,故只以土地出让金与土地、房产税收计算1999-2010年全国31个省(市)土地财政收入总规模,同时考虑各省(市)年均土地财政收入规模占地方财政总收入的比重(贡献率),找出土地财政情况地域差异的基本规律.进一步采用SPSS19.0层次聚类分析方法,将全国31个省(市)土地财政情况划分为5种集群类型:土地财政发展期、较旺盛期、旺盛期、中期、后期.从土地财政收入规模与增长趋势及对地方财政总收入的贡献程度,分析各集群土地财政情况存在差异的原因.在此基础上,考虑土地财政不可持续性及存在的诸多弊端,针对不同集群地域从国家层面制度改革、征收物业税、改变土地财政为动力源泉的城市化、发挥闲散土地的财政作用等4方面,提出土地财政转型的政策建议.     

Spatial-temporal analysis of wetland landscape pattern under the influence of artificial dykes in the Yellow River delta

The influence of anthropogenic activities,especially artificial dykes,on the coastal wetland landscape is now considered as a serious problem to the coastal ecosystem.It is important and necessary to analyze changes of coastal landscape pattern under the influence of artificial dykes for the protection and management of coastal wetland.Our study aimed to reveal the quantitative characteristics of the coastal wetland landscape and its spatial-temporal dynamics under the influence of artificial dykes in the Yellow River delta(YRD).It was analyzed by the methods of the statistical analysis of landscape structure,five selected landscape indices and the changes of spatial centroids of three typical wetland types,including reed marshes,tidal fiats and aquaculture-salt fields.The results showed that:(1)Reduction of wetland area,especially the degradation of natural wetlands,had been the principal problem since the dykes were constructed in the YRD.The dykes created conditions for the development of artificial wetlands.However,the new born artificial wetlands were still less than the vanished natural wetlands.(2)Compared with the open area,the building of artificial dykes significantly speeded up the changes of landscape patterns and the aggravation of the landscape fragmentation in the closed area.(3)The changes of area-weighted centroids of three typical wetland landscapes were greatly affected by dykes,and the movement of the centroid of the aquaculture-salt field was very sensitive to the dykes constructed in the corresponding period.     

Study on Development of the West of Shandong Province Based on Overall Regional Development Planning Pattern

The overall regional development planning pattern has been considered to be a new and effective pattern as for development of provincial economy. The article analyzed the current conditions of the west of Shandong Province and tried to find the generation mechanisms of current non-balanced economic development of Shandong Province. And then approaches to regional development were put forward according to the theory of regional development pattern as a whole.     

Impacts of the Rising Opportunity Cost of Farm Labor on Agricultural Land Use Structure: Theory and Empirical Evidences

Abstract

Nowadays the rising of opportunity cost of farm labor comes to the forefront of attention in China. In order to understand its impact on agricultural land-use structure, a theoretical framework of household economics is formulated drawn on Low’s model. Under the theoretical framework, the impact of the rising opportunity cost of on-farm on cropping structure is deduced in theory. And then, using statistic and survey data, taking mountain area of southern Ningxia as an example, the theoretical assumes are verified. The results show that the rise of opportunity cost of farm labor leads to less diversified cropping structure.     

Mountains and Handrails: Risk,Meaning, and Responsibility in Three National Parks

Where we live, the relationships we maintain, or the experiences we have can tell us about the way we perceive risk and the responsibility for its management. Perceptions of risk and responsibility are particularly relevant in US national parks, where unintentional injury is prevalent, yet support exists for allowing risk exposure. If experiencing risk may be both desirable (e.g., self-affirming) and undesirable (e.g., injury-causing), what is its role in a national park? Moreover, what are the expectations for visitors to encounter or to avoid it? In-depth interviews with National Park Service employees suggest that desired risk is contingent upon the circumstances in which it is encountered, and the values and prior experience of individuals. Employees perceive visitors as responsible for avoiding undesirable risk through information seeking and awareness, but also recognize considerable barriers to doing so. Theoretical and practical implications and avenues for future research are presented.     

Optimizing a warranty–based sustainable product service system using game theory

Abstract

In recent years, the concepts of sustainability and product service system have been closely associated with each other. In today’s competitive markets, due to Extended Producer Responsibility and customer environmental awareness, producers shift from ‘product-seller’ towards ‘product-service provider’ for using the environmental and economic advantages of coupling a product with services. This paper proposes a novel approach to determine the optimal warranty period and the out-of-warranty replacement period, from the point of view of the producer and the customer to minimise the total cost of usage and end of life of product. As regards the fact that adopted strategies by producers and customers sometimes are in conflict and it affects choosing the optimal product usage period, a game theory model was developed in this study. Finally, a case study with data from chain of local notebook service centres was applied to demonstrate some practical aspects of the developed model.     

中国水资源与水工业的可持续发展

可持续发展是当今世界发展的一种新模式,已成为全世纪普遍关注的热点。 可持续发展的基本观点。分析了影响我国水工业可持续发展的主要限制因素;（１）水资源写水污染严惩）水工业基础设施薄弱,传统的水工业对污染水处理难以相适应;（３）水工业管理存在多种问题。针对目前我国水资源开发利用和水工业发展２及存在的主要问题,提出了我国水工业面向可持续发展的优化对策与途径;（１）保护水源,防治水污染;（２）开源节流,节     

论湘中城市群经济的融合耦动与可持续发展

本文以湘中（长株潭）城市群作为研究对象,概述了湘中城市群经济融合的总体特征,对其城市群空间生长演化过程中存在的问题和应采取的对策,经济如何实现可持续发展进行了探讨。