全文获取类型
收费全文 | 2431篇 |
免费 | 296篇 |
国内免费 | 2324篇 |
专业分类
安全科学 | 183篇 |
废物处理 | 112篇 |
环保管理 | 243篇 |
综合类 | 2846篇 |
基础理论 | 397篇 |
环境理论 | 1篇 |
污染及防治 | 1212篇 |
评价与监测 | 33篇 |
社会与环境 | 22篇 |
灾害及防治 | 2篇 |
出版年
2024年 | 19篇 |
2023年 | 93篇 |
2022年 | 149篇 |
2021年 | 198篇 |
2020年 | 180篇 |
2019年 | 189篇 |
2018年 | 180篇 |
2017年 | 209篇 |
2016年 | 245篇 |
2015年 | 267篇 |
2014年 | 289篇 |
2013年 | 309篇 |
2012年 | 321篇 |
2011年 | 294篇 |
2010年 | 242篇 |
2009年 | 299篇 |
2008年 | 162篇 |
2007年 | 289篇 |
2006年 | 258篇 |
2005年 | 171篇 |
2004年 | 121篇 |
2003年 | 139篇 |
2002年 | 79篇 |
2001年 | 70篇 |
2000年 | 68篇 |
1999年 | 59篇 |
1998年 | 26篇 |
1997年 | 32篇 |
1996年 | 19篇 |
1995年 | 23篇 |
1994年 | 16篇 |
1993年 | 12篇 |
1992年 | 11篇 |
1991年 | 3篇 |
1990年 | 1篇 |
1989年 | 2篇 |
1986年 | 2篇 |
1982年 | 2篇 |
1977年 | 1篇 |
1972年 | 1篇 |
1971年 | 1篇 |
排序方式: 共有5051条查询结果,搜索用时 0 毫秒
61.
62.
Industrial wastewater pre-treatment for heavy metal reduction by employing a sorbent-assisted ultrafiltration system 总被引:1,自引:0,他引:1
This work examined the adoption of a sorbent-assisted ultrafiltration (UF) system for the reduction of Pb(II), Cu(II), Zn(II) and Ni(II) from industrial wastewater. In such a system metals were removed via several processes which included precipitation through the formation of hydroxides, formation of precipitates/complexes among the metal ions and the wastewater compounds, adsorption of metals onto minerals (bentonite, zeolite, vermiculite) and retention of insoluble metal species by the UF membranes. At pH = 6 the metal removal sequence obtained by the UF system was Pb(II) > Cu(II) > Zn(II) > Ni(II) in mg g−1 with significant amount of lead and copper being removed due to chemical precipitation and formation of precipitates/complexes with wastewater compounds. At this pH, zinc and nickel adsorption onto minerals was significant, particularly when bentonite and vermiculite were employed as adsorbents. Metal adsorption onto zeolite and bentonite followed the sequence Zn(II) > Ni(II) > Cu(II) > Pb(II), while for vermiculite the sequence was Ni(II) > Zn(II) > Cu(II) > Pb(II) in mg g−1. The low amount of Pb(II) and Cu(II) adsorbed by minerals was attributed to the low available lead and copper concentration. At pH = 9 the adoption of UF could effectively reduce heavy metals to very low levels. The same was observed at pH = 8, provided that minerals were added. The prevailing metal removal process was the formation of precipitates/complexes with wastewater compounds. 相似文献
63.
改性硅藻土用于巢湖水脱磷研究 总被引:5,自引:1,他引:4
采用改性硅藻土强化混凝处理巢湖水,以达到除磷的目的.研究了改性硅藻土除磷最适操作条件,并将改性硅藻土同几种常规混凝剂的处理效果和其经济性进行了对比.结果表明:改性硅藻土和水的混合搅拌速度梯度为260 s-1左右,絮凝反应速度梯度为20 s-1左右,絮凝时间15 min,沉淀时间1 h,改性硅藻土投加量50~100 mg... 相似文献
64.
It has been shown that starch can effectively stabilize nanoscale magnetite particles, and starch-stabilized magnetite nanoparticles (SMNP) are promising for in situ remediation of arsenic-contaminated soils. However, a molecular level understanding has been lacking. Here, we carried out XAFS studies to bridge this knowledge gap. Fe K-edge XAFS spectra indicated that the Fe-O and Fe-Fe coordination numbers of SMNP were lower than those for bare magnetite particles, and these coordination numbers decreased with increasing starch concentration. The decrease in the average coordination number at elevated stabilizer concentration was attributed to the increase in the surface-to-volume ratio. Arsenic K-edge XAFS spectra indicated that adsorbed arsenate on SMNP consisted primarily of binuclear bidentate (BB) complexes and monodentate mononuclear (MM) complexes. More BB complexes (energetically more favorable) were observed at higher starch concentrations, indicating that SMNP not only offered greater adsorption surface area, but also stronger adsorption affinity toward arsenate. 相似文献
65.
采用浸渍-热分解法制备了含IrOx-TiO2中间层的IrO2-SnO2电极,得到的电极具有较高的析氯电催化活性和较强的稳定性,并通过电化学氧化法对Na2SO3海水脱硫模拟液进行处理,考察了电流密度、温度、pH值和电解时间等电解工艺参数对Na2SO3去除率和化学需氧量COD的影响。结果表明,在电流密度为200 mA/cm^2,pH值为3.5,电解440 mg/L的Na2SO3海水脱硫模拟液,15 min时Na2SO3去除率可达96.5%,COD去除率可达82.6%。 相似文献
66.
为探讨Cu2+、p H和流速对固定化斜生栅藻去除畜禽废水中NH+4-N、TP效果的影响,在实验室条件下模拟实际污水处理过程,并采用正交实验方案对结果进行分析。结果表明低质量浓度Cu2+(0~0.05 mg/L)改善藻的净化效果,高质量浓度Cu2+(0.50~5.00 mg/L)抑制藻的净化效果;在p H较高的条件下(p H=9),固定化斜生栅藻的净化效果明显提高;流速对结果没有明显影响。通过正交实验,得出固定化斜生栅藻去除畜禽废水中NH+4-N、TP的优化条件如下:Cu2+质量浓度为0.05 mg/L,p H为9,流速为0.3 m/s。此时NH+4-N去除率为96.11%,TP去除率为97.53%。 相似文献
67.
Erdal Yabalak Özkan Görmez Ahmet Murat Gizir 《Journal of environmental science and health. Part. B》2018,53(5):334-339
This study was conducted to investigate the degradation of propham, which is a compound that pollutes water and seriously threatens human health, by subcritical water oxidation and using H2O2 as an oxidising agent. The maximum total organic carbon removal rate of propham was obtained as 73.65% at 40 min of treatment time and 60 mM of H2O2 concentration and 373 K of temperature. In addition, response surface method based on the Box-Behnken design was applied to design the degradation experiments of propham for determination of the combined effects of process variables, namely temperature, concentration of oxidising agent and treatment time. The proposed quadratic model of propham degradation, which was examined with the analysis of variance, was used for navigating the design space. The R2 and adjusted R2 values of the model were determined as 0.9921 and 0.9819 respectively. It was shown that propham was effectively degraded, thus could be removed from the water by using an environmentally friendly method. 相似文献
68.
69.
异养硝化及其在污水脱氮中的作用 总被引:23,自引:0,他引:23
通过与传统自养硝化作用的比较,异养硝化作用不仅是客观存在的过程,而且某些特殊的异养菌,可以同步进行异养硝化和好氧反硝化,对于污水脱氮具有重要的理论意义和应用价值。 相似文献
70.
根据染料废水的特点 ,研究了自制产品新型氧化 混凝剂处理染料废水的情况 ,探索了药剂用量、pH值等因素对COD、色度去除率的影响。试验表明 ,当pH >10、“染清”氧化 混凝剂的加入量万分之三左右、絮凝时间 6min、静置沉淀3 5min时 ,该药剂对染料废水具有良好的效果 ,COD和色度的去除率最高分别可达 97%和 86% ,从而证明该方法对于染料废水的处理是可行的。该处理工艺设备简单 ,系统运行稳定 ,操作方便 ,成本低 相似文献