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431.
432.
Ester Heath Nives Ogrinc Jadran Faganeli Stefano Covelli 《Water, Air, & Soil Pollution: Focus》2006,6(5-6):605-614
To reconstruct a history of polycyclic aromatic hydrocarbon (PAH) pollution in the Gulf of Trieste, one of the largest urbanized
areas in the Adriatic Sea, we analyzed three long sediment cores collected between 1996 and 1997. Concentrations of total
PAHs, the sum of 16 PAH compounds and six of their methylated analogues, in all three cores show a decrease from 600–800 ng
g−1, at the surface, to levels below 250 ng g−1 in deepest layers (down to 3 m). The same trend was shown with separate representative pyrogenic PAHs (pyrene, benzofluoranthene
and phenanthrene). Using Hg as a recent geochronological tracer, we observe an increasing input of PAHs since the beginning
of the 20th Century and, especially, after the Second World War coinciding with increasing industrialization and urbanization
of the region. This correlation is supported by PAH ratios that are indication of combustion processes and represent a marker
for anthropogenic inputs. No correlation exists between PAHs and black carbon within the core profiles, indicating two different
fractions of the ‘black carbon continuum’. 相似文献
433.
J.??áslavskyEmail author P.?Kotla?íková K.?Bene?ová 《Environmental Chemistry Letters》2004,2(2):89-92
Semipermeable membrane devices (SPMDs) are nowadays used as passive samplers of organic pollutants. The knowledge of the sampling rate values (RS) of each substance trapped on membranes is necessary to calculate their average concentration. Here we calculate RS values for 16 polycyclic aromatic hydrocarbons using the comparison of active sampling method results and the amounts sequestered by SPMDs at varying exposure times.Selected article from the Regional Symposium on Chemistry and Environment, Krusevac, Serbia, June 2003, organized by Dr. Branimir Jovancicevic. 相似文献
434.
Fernández Pilar Rose Neil L. Vilanova Rosa M. Grimalt Joan O. 《Water, Air, & Soil Pollution: Focus》2002,2(2):261-274
Spheroidal carbonaceous particles (SCP) and polycyclicaromatic hydrocarbons (PAH) have been measured in the dated sediment cores of 10 remote lakes distributed across Europe. The geographic trends were evaluated by examination of the superficial sediment fluxes and total sediment inventories. The highest levels of both markers were observed in the Eastern European lakes whereas the minimal values corresponded to the lake located in the Arctic. However, this SCP-PAH correlation was not observed after exclusion of the end member lakes from the series. The temporal trends of both pollutant markers are consistent with the history of pyrolytic emissions over Europe. However, the downcore SCP distributions are shorter than the PAH profiles in nearly all lakes. The differences are probably related to the different size particle fractions involved in the measurement of each marker, >5 and >1 m for SCP and PAH, respectively. Thus, the two proxies probably reflect pollution inputs from closer (SCP) and more distant sites (PAH). 相似文献
435.
436.
对杭州湾潮滩表层沉积物样品中的多环芳烃(PAHs)进行了定量分析.结果表明,沉积物中PAHs总含量范围为45.78~849.93ng/g.PAHs的空间分布总体呈现钱塘江杭州河段>杭州湾南岸>杭州湾北岸.PAHs含量分布与有机碳(TOC)含量存在良好的线性关系,受人类活动和水动力条件的影响较大.样品中PAHs的燃烧来源所占的比重较大,呈现出油料燃烧与木材、煤燃烧的混合污染来源特征.该地区表层沉积物样品中的PAHs尚未对生物造成显著的负面影响. 相似文献
437.
生态毒理学研究中分子构效相关的应用 总被引:3,自引:1,他引:2
分子定量构效相关(QSAR)理论方法是当前生态毒理学研究领域发展的重要方向和前沿,QSAR法运用多种数学模式和化合物特征表示参数,系统地探究化合物的生态毒理学机制,进行分子水平的综合研究。笔者系统阐述并应用目前生态毒理学研究中采用的分子构效新方法,对取代芳烃类等典型有机物的生态毒理学效应进行了举证性预测研究。 相似文献
438.
D. Golomb E. Barry G. Fisher P. Varanusupakul M. Koleda T. Rooney 《Atmospheric environment (Oxford, England : 1994)》2001,35(36)
Wet and dry deposition of polycyclic aromatic hydrocarbons (PAHs) was measured at Nahant, Massachusetts, a peninsula jutting into Massachusetts Bay and Wolf Neck, a peninsula jutting into Casco Bay, Maine. Wet deposition (rain and snow) was collected in a funnel which drains into a shielded, temperature controlled receiving bottle. Dry deposition of gaseous and particulate PAHs was collected onto an exposed water surface. PAHs were analyzed by solid phase extraction and gas chromatography-mass spectrometry. Sixteen PAH species were analyzed, ranging from acenaphthylene to coronene. The mean wet deposition rate of the sum of the 16 species is 720 ng m−2 cm−1 precipitation at Nahant, and 831 ng m−2 cm−1 precipitation at Wolf Neck. Wet deposition is attributed to regional PAH emitting sources. Storm patterns appear to bring somewhat higher wet deposition of PAHs to Wolf Neck than to Nahant. The mean dry deposition rate is 95 ng m−2 h−1 at Nahant and 9.3 ng m−2 h−1 at Wolf Neck. The large difference is attributed to the fact that Nahant is close to the urban-industrial metropolitan Boston area and Logan International Airport, whereas Wolf Neck has no major PAH-emitting sources nearby. Individual measurements have an error bracket of ±30%. The Chemical Mass Balance model was used to apportion the dry deposition to source categories. At Nahant, nine samples gave valid statistical attributes with a mean apportionment: jet exhaust 35%, gasoline fueled vehicles 32%, diesel fueled vehicles 17%, wood combustion 13%, others 3%. At Wolf Neck, six samples yielded a mean apportionment: jet exhaust 30%, gasoline vehicles 28%, diesel vehicles 18%, wood combustion 16%, others 8%. There is a considerable variation between the samples. The apportionment is greatly dependent on the quality and selection of the model inputs, i.e. source signatures, which for PAHs are questionable. 相似文献
439.
扎龙湿地沉积物垂向剖面中多环芳烃分布特征 总被引:1,自引:0,他引:1
对扎龙湿地核心区沉积物分层取样,以正己烷/二氯甲烷为提取剂,用超声波方法提取沉积物中16种优控PAHs,采用GC/MS法定量分析w(PAHs). 结果表明,扎龙湿地剖面沉积物中2环和3环PAHs占PAHs总量的86%以上,4环以上的PAHs所占比例较小. 在各层沉积物中含量较高的萘、菲、芴及PAHs总量随深度的增加而减小,沉积物表层0~10 cm内的w(PAHs)最高,达396.61 ng/g. 表层沉积物中含量较高的PAHs为萘>菲>芴>荧蒽>芘>二氢苊>苊烯>. w(PAHs)与沉积物中w(TOC)呈正相关关系,相关系数为0.9347. 从扎龙湿地的低环PAHs污染特征以及同周边地区大气颗粒物中的PAHs对照分析表明,扎龙湿地沉积物中的PAHs主要来源于石油类污染. 相似文献
440.
Posada-Baquero R Niqui-Arroyo JL Bueno-Montes M Gutiérrez-Dabán A Ortega-Calvo JJ 《Environmental geochemistry and health》2008,30(2):159-163
The aim of this work was to develop a method to assess the microbial accessibility of native phenanthrene present in soils
and sediments. We developed an accelerated biodegradation assay, characterized by (a) inoculation with a sufficient number
of phenanthrene-degrading microorganisms, (b) monitoring of the biodegradation activity through 14C-mineralization measurements, and (c) single-step chemical analysis of the native compound in the residue. The use of 14C-labeling allowed the determination of the time period needed for biodegradation of the bioaccessible fraction of the native
chemical. The method was tested with environmental samples having a wide range of phenanthrene concentrations, i.e., from
background levels (μg kg-1) originating in soil from atmospheric deposition, to acute concentrations (g kg-1) corresponding to industrial pollution of soils and sediments. The results showed a wide range of bioaccessibility (15–95%
of the initial amount). The method can be used for the assessment of bioaccessibility involved in the management of polycyclic
aromatic hydrocarbon (PAH) pollution. 相似文献