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501.
502.
单质硫改性介孔炭对水溶液中汞的吸附性能研究 总被引:2,自引:1,他引:1
对介孔炭CMK-3进行单质硫改性得到OMC-S,并通过静态吸附实验研究了该材料对水溶液中汞的吸附性能。研究结果表明:单质硫改性可以在介孔炭上负载12.33%的硫,从而使得介孔炭对汞的吸附容量从185 mg/g提高到476 mg/g;OMC-S具有较广的适用pH值范围,在pH 3~11.5范围内其对汞的吸附去除率均达到92%以上;氯离子对OMC-S的吸附性能具有一定的抑制作用,原因在于它能和汞离子络合形成一系列吸附性能较差的Hg-Cl络合物,而腐殖酸在所研究的范围内对OMC-S的吸附性能无明显影响。 相似文献
503.
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505.
几种环境因子对塔玛亚历山大藻(大鹏湾株)生长及其藻毒力影响 总被引:6,自引:0,他引:6
在室内条件下研究了温度 (θ/℃ )、盐度 (ρ/gL-1)及pH对有毒甲藻塔玛亚历山大藻 (大鹏株 )的生长及其毒力的影响 .实验表明 ,塔玛亚历山大藻θopt为 15~ 2 5℃ ,最大生长率出现在接种后 6~ 8d ;在盐度为 14~32g/L范围内 ,该藻均可生长 ,盐度 2 3~ 2 7g/L时生长最佳 ;在弱酸弱碱下 ,该藻可较好生长 ,pHopt=6~ 7;用小白鼠法测得本藻株c(HCl) =0 .1mol/L提液的麻痹性贝毒毒力为 0 .5 0× 10 -5~ 3.2× 10 -5Mu/cell,在同种藻株中属低毒藻株 .与其他作者对本藻株用不同毒素抽提方法及测定技术所得结果的比较表明 ,其藻毒力测定值最大相差达 30倍 .图 3表 2参 17 相似文献
506.
WANG Jian-li ZHONG Jun-bo GONG Mao-chu LIU Zhi-min ZHAO Ming CHEN Yao-qiang 《环境科学学报(英文版)》2007,19(6):644-646
Five monolithic catalysts with low noble metal content were prepared by irnmerge method (Pt/γ=Al2O3, Pt/La-Al2O3, Pt/YSZ-AI203, Pt+Pd/La-Al2O3 and Pd/La-Al2O3) and their activity measurements were carried out in a conventional fixed-bed flow reactor. The results show that La-Al2O3 can promote activity of the prepared catalysts and can decrease the complete conversion temperature of cooking fume. The Pt/La-Al2O3 catalyst has the highest activity and can be applied in wide range of gas hourly space velocity (GHSV). Some characterizations (XRD, TPR) were carried out with the objective to explain differences in catalytic behaviors. The prepared catalyst showed a great potential for application. 相似文献
507.
LIU Ting-feng SUN Cheng TA N HONG Jun YANG Shao-gui CHEN Chuan-xiang 《环境科学学报(英文版)》2007,19(10):1235-1238
The influence of coexisting copper (Cu) ion on the degradation of pesticides pyrethroid cypermethrin and cyhalothrin in soil and photodegradation in water system were studied.Serial concentrations of the pesticides with the addition of copper ion were spiked in the soil and incubated for a regular period of time,the analysis of the extracts from the soil was carried out using gas chromatography (GC).The photodegradation of pyrethroids in water system was conducted under UV irradiation.The effect of Cu~(2 ) on the pesticides degradation was measured with half life (t_(0.5)) of degradation.It was found that a negative correlation between the degradation of the pyrethroid pesticides in soil and Cu addition was observed.But Cu~(2 ) could accelerate photodegradation of the pyrethroids in water.The t_(0.5) for cyhalothrin extended from 6.7 to 6.8 d while for cypermethrin extended from 8.1 to 10.9 d with the presence of copper ion in soil.As for photodegradation,t_(0.5) for cyhalothrin reduced from 173.3 to 115.5 rain and for cypermethrin from 115.5 to 99.0 min.The results suggested that copper influenced the degradation of the pesticides in soil by affecting the activity of microorganisms.However, it had catalyst tendency for photodegradation in water system.The difference for the degradation efficiency of pyrethroid isomers in soil was also observed.Copper could obviously accelerate the degradation of some special isomers. 相似文献
508.
硫高温腐蚀及腐蚀产物氧化自燃性的研究 总被引:1,自引:0,他引:1
随着炼制原油硫含量的增加,炼油装置的硫腐蚀问题也日益严重.针对硫高温腐蚀状况,用差热-热重分析仪研究硫与Fe(OH)3、Fe2O3和Fe3O4发生硫化腐蚀反应的初始温度,并采用X射线衍射仪鉴定了360 ℃高温无氧条件下硫化腐蚀产物的组成.结果表明,硫与Fe(OH)3、Fe2O3和Fe3O4发生硫化反应的初始温度分别为287.67 ℃、233.34℃和308.47 ℃;高温硫化腐蚀产物主要是FeS2.对硫化产物FeS2进行氧化反应,氧化升温曲线和耗氧曲线表明,硫化腐蚀产物FeS2具有很高的氧化自燃性,在一定条件下能引发油品火灾和爆炸等事故. 相似文献
509.
Haruhiro Ino Yoshihisa Matsumoto Ryo Takahashi Kazukiyo Takami Junya Nishino Masaaki Itoh 《Journal of Material Cycles and Waste Management》2008,10(2):129-133
H-ZSM-5 zeolite-supported gallium oxides were studied as aromatization catalysts for polyolefin pyrolysate. The catalysts
were prepared by a conventional physical mixing method with a gallium content of 1.0 and 4.5 wt% and were reduced in flowing
hydrogen at 585°C. To test their activity, a polyolefin sample was pyrolyzed and passed over a heated catalyst layer; the
product was analyzed by gas chromatography/mass spectrometry. A continuous-flow fixed-bed reactor was used for aromatization
of a model gas of polyolefin pyrolysate. For chlorine-free sources at 450°C, the catalyst with only 1.0 wt% gallium exhibited
activity comparable to a gallium silicate catalyst. For chlorine-contaminated sources, the catalyst with 4.5 wt% gallium sustained
catalytic activity for long periods. From the activity test results, it was found that zeolite-supported gallium catalysts
prepared by the physical mixing method are suitable for converting polyolefin into aromatic hydrocarbons. 相似文献
510.
水稻土中半胱氨酸分解产生含硫气体的研究 总被引:2,自引:0,他引:2
在室内培养条件下,测定了水稻土中含硫气体的释放.结果表明,该土壤中有硫化氢(H2S),羰基硫(COS),二甲基硫(DMS)三种气体释放.当土壤中加入半胱氨酸后,COS和H2S气体的浓度有了明显增加,并有CS2和CH3SH测出,而DMS的浓度变化不大.这些结果表明半胱氨酸的分解可能是 COS,H2S,CS2和 CH3SH的产生源之一.在好氧(正常大气)条件下,H2S,COS,CS2和CH3SH的释放量低于厌氧(氮气氛围)条件下的释放量,DMS则高于厌氧条件下.这表明水稻土中半胱氨酸分解产生 H2S,COS,CS2和 CH3SH需较强的还原条件,产生这四种气体的微生物需要严格的厌氧条件.产生DMS的微生物则比前者需要高一些的含氧量.在光照条件下,各含硫气体的释放量普遍高于无光照条件下的释放量.释放含硫气体的大多数微生物适宜的含水率为50%且对土壤的pH值有一定要求. 相似文献