海南岛地表水的区域地球化学特征及其影响因素

始于2004年的海南岛多目标生态地球化学调查,对全岛的地表水进行了区域调查取样,分析测试了24项指标(部分样品增加测试12项)。测试结果表明,大多数指标优于国家地表水环境质量标准(GB3838-2002)中III类水体水质标准,只有Hg和总氮存在区域性的超Ⅲ类水体水质。经对样品的聚类分析研究表明,全岛地表水样品主要分为4类,分别反映了地表植被、海水入侵、灌溉水田排水、矿山废水排放对地表水化学成分的控制作用。在此认识的基础上,依地表水样品所处的土地利用方式的不同,按一定顺序对样品进行编号赋值(沿海的土地视为"海洋利用方式"),该赋值与聚类分析所得到的样品类别值之间存在极显著的正相关性,相关系数达0.8280,表明海南岛的土地利用方式是控制地表水地球化学特征的关键因素,从而为海南岛地表水环境质量的保护和提高指出了方向。     

Determination of polyfluoroalkyl compounds in water and suspended particulate matter in the river Elbe and North Sea, Germany

The distribution of polyfluoroalkyl compounds (PFCs) in the dissolved and particulate phase and their discharge from the river Elbe into the North Sea were studied. The PFCs quantified included C₄-C₈ perfluorinated sulfonates (PFSAs), 6:2 fluorotelomer sulfonate (6:2 FTS), C₆ and C₈ perfluorinated sulfinates (PFSiAs), C₄-C₁₂ perfluorinated carboxylic acids (PFCAs), perfluoro-3,7-dimethyl-octanoic acid (3,7m₂-PFOA), perfluorooctane sulfonamide (FOSA), and n-ethyl perfluroctane sulfonamidoethanol (EtFOSE). PFCs were mostly distributed in the dissolved phase, where perfluorooctanoic acid (PFOA) dominated with 2.9–12.5 ng/L. In the suspended particulate matter FOSA and perfluorooctane sulfonate (PFOS) showed the highest concentrations (4.0 ng/L and 2.3 ng/L, respectively). The total flux of ΣPFCs from the river Elbe was estimated to be 802 kg/year for the dissolved phase and 152 kg/year for the particulate phase. This indicates that the river Elbe acts as a source of PFCs into the North Sea. However, the concentrations of perfluorobutane sulfonate (PFBS) and perfluorobutanoic acid (PFBA) in the North Sea were higher than that in the river Elbe, thus an alternative source must exist for these compounds.     

某校区路面径流污染特性和控制措施的研究

以某校区的水体（A水库、B湖）为受纳水体,对降雨产生的路面径流及A水库和B湖水体进行采样,水质分析项目分别为pH、COD（化学需氧量）、SS（悬浮物）、TN（总氮）、TP（总磷）。以COD、SS作为主要的水质分析项目进行比较分析,确定路面降雨径流污染的主要特征,径流污染对校园水库、湖泊水质的影响。经过比较分析,提出采用植被控制法作为该校区路面径流污染控制措施对受纳水体进行保护。     

地表水水质模型概述

近些年来,我国水环境问题日益凸显,借助水质模型对水污染问题进行研究,并为相关管理和规划提供技术支持已经成为水环境研究的热点。本文阐述了地表水水质模型的概念、发展以及分类,介绍了几种当前比较成熟的地表水水质模型,并对地表水水质模型的未来发展做了展望。     

响应面方法优化光催化降解抗生素类污染物过程研究

近年来抗生素类污染物对环境的影响及其生态毒性日益引起广大研究者的关注。对TiO2光催化降解典型抗生素类污染物磺胺二甲嘧啶（SMT）进行了研究。采用中心组合设计方法（CCD）进行试验设计,使用响应面方法（RSM）对光催化过程中的影响因素（TiO2浓度、初始磺胺二甲嘧啶浓度、双氧水浓度）进行了探讨和分析,并对反应过程进行了优化。优化结果表明,最佳反应条件为：TiO2浓度1.74 g/L、初始磺胺二甲嘧啶浓度20.0 mg/L、双氧水浓度106.28 mg/L,在优化条件下的磺胺二甲嘧啶光催化实际去除率为83.6%。响应面方法能够优化光催化条件,预测光催化结果,有利于优化光反应器的设计,对于工程化光催化水处理技术的发展具有一定的参考价值。     

广州市生活饮用水地表水源地微量元素调查

对广州市秀全、巴江、江村、石门、西村、刘屋洲、南洲和沙湾等主要生活饮用水地表水源地中钼、钴、铍、硼、锑、镍、钒、钛、锡、银和钡等微量元素含量水平进行了调查,并采用单因子污染指数法和内梅罗综合污染指数法对微量元素水质进行了评价。结果表明,硼和锡在所有地表水源地均未检出,铍在部分地表水源地有检出,其他检测项目在所有地表水源地均有检出。整体而言,微量元素含量水平不高,地表水源地由北往南微量元素内梅罗指数呈逐渐降低态势,南部水源地水质优于北部水源地。巴江和西部水源地镍含量相对较高,电镀企业排污监管力度有待进一步加强。     

丰水期地表河流水中泥沙沉降时间对总磷样品测定结果的影响分析

地表河流水中总磷含量高低是评定水质优劣的一项重要指标,分析数据表明丰水期中总磷主要来源于泥沙中吸附的有机磷和无机磷;水样中总磷含量随着泥沙沉降时间的延长而逐渐降低。因此样品采集回来后,样品的泥沙沉降时间是影响地表河流中总磷测定结果的一个主要原因。     

Characteristics of contaminants in water and sediment of a constructed wetland treating piggery wastewater e uent

Constructed wetland (CW) is the preferred means of controlling water quality because of its natural treatment mechanisms and function as a secondary or tertiary treatment unit. CW is increasingly applied in Korea for secondary e uent of livestock wastewater treatment. This study was conducted to recognize the characteristics of contaminants in the accumulated sediment at the bottom soil layer and to reduce the phosphorus release from sediments of the free water surface CW for the treatment of secondary piggery wastewater e uent from a livestock wastewater treatment facility. The results revealed that the dominant phosphorus existence types at near the inlet of the CW were non-apatite phosphorus (59%) and residual phosphorus (32%) suggesting that most of the particles of the influent are made up of inorganic materials and dead cells. Sediment accumulation is important when determining the long-term maintenance requirements over the lifetime of CW. Continuous monitoring will be performed for a further assessment of the CW system and design.     

Modelling sulphate-enhanced cadmium uptake by Zea mays from nutrient solution under conditions of constant free Cd2+ ion activity

A controlled hydroponic experiment was undertaken to investigate Cd uptake in relation to the activity of Cd species in solution other than the free ion (Cd²⁺) by maintaining a constant Cd²⁺ activity under variable SO₄₂⁻ and Cl⁻ concentrations exposed to maize (Zea mays var. Cameron) plants. The objectives of these experiments were: (1) to distinguish and quantify the different uptake rates of free and inorganic-complexed Cd from nutrient solution, and (2) to model the uptake of Cd by maize with a Biotic Ligand Model (BLM) in a system which facilitates the close examination of root characteristics. Results of the current experiments suggest that, in addition to the free ion, CdSO₄⁰ complexes are important factors in determining Cd uptake in nutrient solution by maize plants. Higher nominal SO₄²⁻ concentrations in solution generally resulted in a greater Cd accumulation by maize plants than predicted by the Cd²⁺ activity. A better integration of the complete dataset for the 3 harvest times (6, 9 and 11 days after treatment) was achieved by including consideration of both the duration of Cd exposure and especially the root surface area to express Cd uptake. Similarly, the fit of the BLM was also improved when taking into account exposure time and expressing uptake in terms of root morphological parameters.     

基于响应面优化条件下柚皮对Pb2+的吸附

采用Plackett-Burman(P-B)法和中心复合设计(Central Composite Design,简称CCD)对影响柚皮吸附Pb2+的6个条件进行筛选优化.P-B实验设计与统计学分析表明:pH值、Pb2+初始浓度、吸附剂用量是影响吸附率的3个关键因素.以吸附率为响应目标,对3因素进行中心复合设计,并经响应面法优化分析得到影响吸附率的二阶模型,确定了Pb2+吸附实验的最优操作条件:pH值5.4.Pb2+初始浓度为265.86mg·L-1,吸附剂用量为2.56 g·L-1,实测吸附率达到92.47%,吸附量为96.01 mg·g-1;整个吸附过程吸附剂柚皮没有经过任何化学预处理.效果优于一般的天然吸附剂.研究结果表明,柚皮是一种很具潜力的环保型廉价吸附剂.