Vertical infiltration of fuel oil hydrocarbons in an agricultural soil

The influence of rainfall, air temperature and soil moisture on the vertical mobility in the soil of fuel oil hydrocarbons (HC) was investigated in a field experiment. A controlled spreading of fuel oil (nC10‐nC25) was performed at a rate of 5 L HCm^‐2 on an agricultural soil in summer and in winter. Concentration, chemical composition of HC and soil moisture were regularly determined at different soil depths between 0 and 140 cm, 1 h, 3, 8and 15 days (d) after the spreading of oil. Sorption of hydrocarbons onto the organo‐mineral matrix of the soil was studied in laboratory experiments. The results showed that in summer, with an air temperature of 24°C and without water leaching in the soil profile, 65% of the initial HC remained trapped in the 0–140 cm soil layer, about 20% of the HC volatilized and around 15% migrated deeper. A vertical selective migration of the lightest (nC10‐nC15) HC (naphthas) was shown lSd after the spreading of fuel oil. Naphthas progressively reached the 120–140 cm soil layers whereas the heavy fractions of oil (nC17‐nC25) migrated and concentrated in the 0–60 cm soil layers. In winter, when soil was regularly watered by rainfalls and at low air temperatures, only 47% of the initial HC remained in the 0–140 cm profile after 15 d. A fast vertical infiltration of naphthas occurred within the first 3 d. After 15 d, all HC were detected in the same relative amounts as in the initial oil in the whole profile. Volatilization was negligible in winter and an increase in the migration of total oil at depth in the soil profile was shown. As inferred from the laboratory experiments, the high soil moisture led to the decrease in HC sorption on the organo‐mineral matter of the soil.     

我国重工业企业烟气脱硫技术及存在的问题

为使企业在"十二五"期间达到SO2减排指标,总结出几种目前应用普遍,技术成熟,投资、运行成本较低的脱硫工艺,包括烟气脱硫的基本原理、主要设备、技术难点及存在的问题。供企业新建,改建或扩建脱硫系统借鉴。     

喹啉为MFC阳极燃料的微生物群落结构演化分析

通过构建填料型微生物燃料电池(MFC),首次对以喹啉为燃料时的MFC阳极表面的微生物群落进行了分析.PCR-DGGE的试验结果表明,随着燃料的改变,微生物群落也发生改变.当以喹啉和葡萄糖的混合溶液稳定地作为燃料时,由于受到喹啉毒性的抑制,微生物多样性降低,优势菌也发生明显的改变.与葡萄糖共基质相比,以单一喹啉为燃料时的阳极微生物优势菌落发生明显改变.新增加一类菌,这类菌与Pseudomonas sp. DIC5RS 的同源性为100%,推测该菌在单一喹啉为MFC燃料时喹啉的降解过程中起到关键作用.     

反硝化微生物燃料电池的基础研究

在启动双室型反硝化微生物燃料电池的基础上,研究了阴极溶解氧及外电阻对其产电性能和污染物去除效果的影响.结果表明,以乙酸钠为阳极电子供体,硝酸钠为阴极电子受体,在25℃的环境温度下,采用先间歇后连续培养的方式,42d内成功启动了反硝化微生物燃料电池.在阴极进水含氧的情况下,氧和硝酸盐可共同用作阴极电子受体.在较小电流密度区域内,氧是阴极的主要电子受体,相应的最大功率密度为26.0W/m3NC;电流密度增加到一定程度后,硝酸盐逐步变为阴极的主要电子受体,相应的最大功率密度为20.9W/m3NC.外阻变化对COD去除及反硝化程度影响较小,阳极COD去除负荷维持在1.2kg/(m3NC·d)左右,出水NO-2-N保持在0.05mg/L以下;但外阻减小有利于提高阴极脱氮效果,外阻为5 Ω时NO-3-N去除负荷达0.111kg/(m3NC·d).     

污泥为燃料的微生物燃料电池运行特性研究

实验采用单室无膜悬浮阴极微生物燃料电池(MFC),考察了运行特性对污泥为燃料的MFC(SMFC)的影响.研究表明,相对于未搅拌情况,搅拌时SMFC最大输出功率由45.94mW/m2分别增加到124.03mW/m2(1300r/min)和136.5mW/m2(2600 r/min),主要是由于搅拌有利于改善SMFC内物质的传递. 温度对SMFC的产电特性影响较明显,但在一定区间内(如20~25℃;30~40℃;45~50℃)变化不明显,说明产电微生物有一定的温度适应范围,这也可能是在不同温度下产电微生物不同导致.相对于采用未经处理的剩余污泥为燃料,微波处理后的污泥和微波处理过滤后的上清液做燃料时SMFC输出功率迅速增加,这主要是由于污泥中的微生物竞争作用引起.阴极面积的增加有利于降低阴极电势,降低SMFC内阻,从而促进功率密度的增加.     

Recent advances in three typical configurations and applications of bioelectrochemical systems北大核心CSCD

As the world's freshwater resources and available energy are alarmingly decreasing, the bioelectrochemical system (BES) is a cutting-edge technology for the resolution of the resource and energy issue. Researchers have paid much attention to t he application of t he BES configuration. Based on t he brief i ntroduction of m icrobial f uel cell a nd m icrobial electrolytic cell structure, principles, and domestic and foreign research, the BES and its influencing factors are introduced, specifically including: microbial activity, electrode materials, and configuration. Three important aspects (i.e., the electrode chamber, the reaction chamber, and micro-sensor) are summarized, and the advantages and disadvantages of single-electrode and multi-electrode chambers are compared, based on the microbial desalination cell. Microbial electrolysis desalination cell: Microbial electrolysis desalination and chemical-production cell have been discussed to introduce increasing reaction chamber configuration; this review focuses on the research of BES monitoring with regards to biochemical oxygen demand. The potential applications of the research progress are explored. The results show that the configuration of multi-chamber microbial fuel cell is complex and its efficiency is low, while the single chamber configuration is advantageous. The reaction chamber added is mainly aimed at desalination, and the study of the desalination pool still needs to be focused on optimizing the cation exchange membrane to maintain the anode pH balance and reduce the air cathode dissolved oxygen. Microbial electrode sensor can be applied in more areas, and its sensitivity and long-term stability need to be further improved. However, there is relatively less research on the abundance and activity of electricigen communities; the configurations and scopes of application of BES are still the research priority. © 2018 Science Press. All rights reserved.     

个人乘用车用可替代燃料与我国未来的选择

个人乘用车排放量占道路交通运输二氧化碳(CO2)排放量的三分之一。因此,逐步实现其燃料由传统石化燃料汽柴油向新能源转变是交通运输行业低碳减排和绿色发展的重要抓手之一。本文对当前可供个人乘用车使用的4大类新能源即生物燃油、燃料乙醇、氢和电的属性,特别是其CO2减排效果和使用成本进行了分析和对比,并对新能源加注(充电)设施在欧盟和美国的布局战略和实施成果进行了介绍。结合欧美的实践和中国的实际,本文提出了未来个人乘用车用可替代燃油布局的建设,建议我国直接从传统石化汽油跨越至氢和/或电,并将其作为未来个人乘用车的燃料。     

基于交通冲突技术的交织区交通安全评价

为了分析城市快速路多个交织区之间的相对交通安全状况,及比选同一个交织区的多个设计方案,建立基于交通冲突技术的交织区交通安全评价方法。首先,使用微观交通仿真软件模拟一定道路交通条件下车流运行状态及其随时空变化的过程,并生成车辆轨迹文件;然后,运用交通安全替代评价模型(SSAM)分析车辆轨迹文件,识别和统计交通仿真过程中"发生"的交通冲突;最后,以交织区交通冲突数与交织区交通量、交织区长度的比值作为评价指标,评价交织区的交通安全状况。案例分析表明,交织区交通冲突率越高,其服务水平往往越低;交织区的交通冲突率有随交织区交通量增加而增加,随交织区长度、交织区车道数的增加而降低的趋势。     

城市高污染燃料禁燃区规划方法及案例研究

在总结高污染燃料禁燃区实际规划过程中的经验、参考已有的大气污染控制规划方法的基础上,针对目前高污染燃料禁燃区规划实践中的不足,将情景分析法、模型分析法以及地理信息系统技术(GIS)应用于规划中,提出并发展了一套解决城市或地区高污染燃料禁燃区规划的整体技术方案,并通过该方法体系在珠海市高污染燃料禁燃区规划中的实际案例分析,显示了该方法的可行性与可操作性,为全国其他城市的高污染燃料禁燃区的合理规划提供了一个实例和参考。     

Pre-feasibility study of stand-alone hybrid energy systems for applications in eco-houses

In light of rising cost of fossil fuels and fears of its depletion, coupled with the increase in energy demand and the rise in pollution levels, governments worldwide have had to look at alternative energy resources. Combining renewable energy generation like solar power with superior storage and conversion technology such as hydrogen storage, fuel cells and batteries offers a potential solution for a stand-alone power system. The aim of this paper was to assess the techno-economic feasibility of using a hybrid energy system with hydrogen fuel cell for application in an eco-house that will be built in Sultan Qaboos University, Muscat, Oman. Actual load data for a typical Omani house of a similar size as the eco-house was considered as the stand-alone load with an average energy consumption of 40 kW/day and 5 kW peak power demand. The National Renewable Energy Laboratory's Hybrid Optimisation Model for Electric Renewable software was used as a sizing and optimisation tool for the system. It was found that the total annual electrical energy production is 42,255 kW and the cost of energy for this hybrid system is 0.582 $/kW. During daylight time, when the solar radiation is high, the photovoltaics (PV) panels supplied most of the load requirements. Moreover, during the evening time the fuel cell mainly serves the house with the help of the batteries. The proposed system is capable of providing the required energy to the eco-house during the whole year using only the solar irradiance as the primary source.