资源型城市转型绩效特征及其碳减排效应

基于中国资源型城市2003—2018年面板数据综合测度城市转型绩效,采用空间马尔科夫链、空间计量模型和空间双重差分模型,探究资源型城市转型绩效特征及其对碳排放的影响。结果表明：（1）资源型城市转型绩效逐渐提升,与此对应的是区域差异呈波动上升趋势,且四种类型资源型城市之间区域差异主要来源于地区内差异,成熟型城市贡献最大;资源型城市转型绩效存在明显的空间分异性,发展格局由以跨越区为核心的“多点式”零星分布向先行区为核心的“组团式”聚集形态演变。（2）资源型城市转型绩效在不同时期存在状态转移的可能性,具有滞后区、起步区、跨越区和先行区4个趋同俱乐部特征,空间马尔科夫链表明转移趋势存在明显空间关联性,状态转移通常出现在相邻等级之间,较少有“跳跃式”转移现象,具有长期性和持续性特征。（3）资源型城市转型具有显著碳减排效应,而且这种效应存在不同资源类型、不同发展阶段和不同空间区位的异质性特征,经济产业转型、社会生活转型和生态环境转型是发挥碳减排效应的重要因素;进一步的政策冲击分析表明,产业转型升级示范区和高新技术产业开发区的设立对城市碳减排具有积极的政策效应。     

An Analysis of Secondary Pollutants in Buenos Aires City

Air pollutant concentrations from a monitoring campaign in Buenos Aires City, Argentina, are used to investigate the relationships between ambient levels of ozone (O₃), nitric oxide (NO) and nitrogen dioxide (NO₂) as a function of NO _x (=NO + NO₂). This campaign undertaken by the electricity sector was aimed at elucidating the apportionment of thermal power plants to air quality deterioration. Concentrations of carbon monoxide (CO) and sulphur dioxide (SO₂) were also registered. Photo stationary state (PSS) of the NO, NO₂, O₃ and peroxy radicals species has been analysed. The ‘oxidant’ level concept has been introduced, OX (=O₃ + NO₂), which varies with the level of NO _x . It is shown that this level is made up of NO _x -independent and NO _x -dependent contributions. The former is a regional contribution that equates the background O₃ level, whereas the latter is a local contribution that correlates with the level of primary pollution. Furthermore, the anticorrelation between NO₂ and O₃ levels, which is a characteristic of the atmospheric photo stationary cycle has been verified.The analysis of the concentration of the primary pollutants CO and NO strongly suggests that the vehicle traffic is the principal source of them. Levels of continuous measurements of SO₂ for Buenos Aires City are reported in this work as a complement of previously published results.     

Factors influencing Aerosol Characteristics over Urban Environment

Atmospheric aerosols are an important contributing factor to turbidity in urban areas besides having impact on health. Aerosol characteristics show a high degree of variability in space and time as anthropogenic share of total aerosol loading is quite substantial and is essential to monitor the aerosol features over long time scales. In the present study extensive observations of columnar aerosol optical depth (AOD), total columnar ozone (TCO) and precipitable water content (PWC) have been carried over a tropical urban city of Hyderabad, India. Significant variations of AOD have been observed during course of the day with low values of AOD during morning and evening hours and high values during afternoon hours. Spectral variation of AOD exhibits high AOD at smaller wavelengths and vice versa except a slight enhancement in AOD at 500 nm. Anomalies in AOD, particulate matter and black carbon concentrations have been observed during May, 2003. Back trajectory analysis of air mass during these episodes suggested variation in air mass trajectories. Analysis of the results suggests that air trajectories from land region north of study area cause high loading of atmospheric aerosols. The results are discussed in the paper.     

中国水资源环境问题及可持续发展管理对策

以可持续发展的观点为指导思想,深入剖析了由于人类对水资源的不合理开发利用而诱发的主要环境问题,并探讨了中国现阶段水资源管理中存在的主要问题,提出了可持续发展的管理对策。     

清洁生产的回顾与展望——世界及中国推行清洁生产的进程

为促使清洁生产在新的世纪里持久深入地进行 ,有必要对其过去二十多年的发展历程进行回顾总结 ,也非常有必要对其发展趋势做出判断预测。本系列文章共包含两个部分 ,第一部分回顾了世界范围内及我国推行清洁生产的进展情况 ,第二部分归纳了国际上清洁生产的成功做法和发展趋势 ,并在此基础上指出了我国未来几年内的清洁生产工作重点     

Effect of unburned carbon on lead, zinc, and copper recovery from molten fly ash by chloride-induced volatilization

The present work focuses on investigation of the effective recovery of heavy metals from molten fly ash by applying chloride-induced volatilization. In particular, the effect of unburned carbon on the chloride-induced volatilization of lead, zinc, and copper from model and real molten fly ashes was investigated in the temperature range 873–1173 K under a N₂ atmosphere. As a result, almost 100% of lead and a significant proportion of zinc were volatilized from the real molten fly ash samples at 1173 K. In contrast, for the model fly ash, volatilization ratios of lead and zinc at 1173 K were only 85% and 25%, respectively. Further, the results of X-ray diffraction analysis suggested that PbO in molten fly ash was converted either to Pb₂OCl₂ or Pb by respective chlorination and reduction reactions. Meanwhile ZnO and CuO in the molten fly ash were reduced to Zn and Cu by reaction with unburned carbon. Subsequently, Pb, Zn, and Pb₂OCl₂ were volatilized, but Cu remained in the solid residue. Finally, the volatilization ratio of zinc increased with the addition of carbon, and more than 98% of zinc was volatilized at 1173 K from a fly ash with a carbon content of 20%.     

微型反应柱在含铬废水处理试验研究中的应用

针对镀铬车间废水,采用活性炭吸附处理法对Cr6 和Cr3 的去除效果进行了系统的试验.通过微型反应柱集成装置对穿透时间、吸附容量及活性炭再生方法进行了研究,动态试验表明该装置能有效地处理含铬废水.     

Heterogeneous oxidation of SO2 by O3-aged black carbon and its dithiothreitol oxidative potential

Ozone (O₃) is an important atmospheric oxidant. Black carbon (BC) particles released into the atmosphere undergo an aging process via O₃ oxidation. O₃-aged BC particles may change their uptake ability toward trace reducing gases such as SO₂ in the atmosphere, leading to different environmental and health effects. In this paper, the heterogeneous reaction process between O₃-aged BC and SO₂ was explored via in-situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS). Combined with ion chromatography (IC), DRIFTS was used to qualitatively and quantitatively analyze the sulfate product. The results showed that O₃-aged BC had stronger SO₂ oxidation ability than fresh BC, and the reactive species/sites generated on the surface had an important role in the oxidation of SO₂. Relative humidity or 254 nm UV (ultraviolet) light illumination enhanced the oxidation uptake of SO₂ on O₃-aged BC. The oxidation potentials of the BC particles were detected via dithiothreitol (DTT) assay. The DTT activity over BC was decreased in the process of SO₂ reduction, with the consumption of oxidative active sites.     

煤质活性炭在饮用水处理应用中值得探讨的问题

本文介绍了煤质活性炭在饮用水处理应用中存在的如何选择活性炭的性能指标,煤质活性炭新旧国家标准的变化及煤质活性炭的再生等值得探讨问题。本文对煤质活性炭饮用水处理的应用具有一定的意义。     

Explosion suppression of porous materials in a pipe-connected spherical vessel

To study the suppression of different porous materials on the explosion of combustible gas, some experiments were implemented. The porous materials were categorized into three kinds, including six subcategories, and the explosion suppression characteristics of the thin iron hoop, one-layer porous materials, two-layer composite porous materials, and three-layer composite porous materials were studied and analyzed. The results show that a rarefaction wave appears in the spherical vessel during the rapid development stage of combustion explosion. Further, the thin iron hoop could enhance the gas explosion intensity. And the explosion intensity suppression effect of the porous materials is obvious, the best effects of one-layer, two-layer and three-layer porous materials are from Fe–Ni 10 mm/40 PPI, Fe–Ni 10 mm/90 PPI + Al₂O₃ 10 mm/30 PPI, and Al₂O₃ 10 mm/50 PPI + Fe–Ni 10 mm/40 PPI + SiC 20 mm/20 PPI, respectively. According to the surface morphology of the porous materials, the anti-sintering ability of the three categories of porous materials follows the order of Al₂O₃ > SiC > Fe–Ni. Besides, the thickness and pore size of the combined porous material was changed, which has a great influence on the explosion pressure and the explosion intensity.