自动增氧型潜流人工湿地处理农村生活污水的研究

采用人工配水模拟太湖地区农村生活污水水质,利用改进的自动增氧型潜流人工湿地对其进行处理,结果表明:COD、NH4 -N、TP进水浓度分别在132.4～392.6mg·L-1、21.58～50.26mg·L-1、3.60～13.17mg·L-1范围内变化时,COD、NH4 -N、TP的去除负荷随着进水浓度的升高而增大,其最高去除负荷分别为226.38 kg·d-1·hm-2、44.40 kg·d-1·hm-2、10.44 kg·d-1·hm-2,相应的去除率为89.45%、88.93%、90.25%,且系统有较强的抗冲击负荷能力.     

模糊综合评价法在乐安河水质评价中的应用

根据模糊数学的原理,建立了地表水环境质量模糊综合评价模型,模型不仅计算简便而且充分体现了其系统性、综合性的特点。利用建立的模型对江西省重点整治的河流乐安河进行了水质评价,为污染控制提供了科学依据。     

Monitoring of Pesticide Residues in Fruits

Fruit samples of ber, grapes and guava analysed for pesticide residues employing multiresidue analysis by gas liquid chromatography equipped with ECD and NPD detectors and capillary columns showed contamination with organochlorine, synthetic pyrethroid and organophosphate insecticides. Among organochlorines, HCH, DDT and endosulfan were detected in almost all the samples. Residues of HCH and DDT were maximum in ber followed by grapes and guava where as of endosulfan were maximum in guava followed by grapes and ber. All the fruit samples showed the presence of residues with one or the other group of pesticides. Residues of none of the pesticides exceeded the MRL values in any sample. On the basis of these studies, it is suggested that monitoring studies should be extended to other fruits grown in different agro climatic regions which may serve as basis for future policy in chemical use.     

VOCs治理技术及合成橡胶装置尾气VOCs治理项目进展

综述了VOCs的来源以及我国VOCs治理的相关政策法规。介绍了冷凝、吸收、吸附-脱附、膜分离、生物法、等离子体法、光催化法、热氧化法等主要的VOCs治理技术各自的特点。概述了中国石化合成橡胶装置尾气VOCs治理项目建设情况。中国石化在“十三五”期间累计投入6亿元,实施合成橡胶装置尾气治理项目14个,到“十三五”末,所有合成橡胶装置的尾气均能实现达标排放。     

中国碳排放权交易促进低碳技术创新机制的研究

碳排放权交易已成为我国实施以市场为基础的重要环境规制之一,但此交易市场建设能否诱发我国低碳技术创新的有关研究仍然不足。以我国七个碳排放权交易试点为研究对象,采用合成控制法进行准自然实验,选取2004—2016年全国282个城市的面板数据,评估碳排放权交易试点政策对低碳技术创新的诱发效果,并使用排列检验法进行有效性检验;进而,定量分析碳排放权交易试点正式运行后对低碳技术创新的影响因素,探索七个试点效果差异的成因。研究发现:①碳排放权交易试点政策整体上诱发了试点地区的低碳技术创新活动。②各试点的政策效果存在一定差异,除重庆外的六个试点对政策响应较为迅速,其中北京、上海的诱发效果最显著,天津、广东、深圳和湖北次之,而重庆试点未能对政策作出充分的响应。③碳排放权交易对低碳技术创新作用中的政策"信号-预期"机制在我国首次得到验证,该机制在除重庆外的试点地区都得到了较好的构建。④碳排放权交易市场建设与区域产业结构升级产生了良好的协同作用,促进低碳技术创新,但其未能与外商直接投资形成相同作用;除重庆外,碳排放权交易这一市场型环境规制与控制型环境规制也呈现出协同作用。据此,应积极推进全国性碳排放权交易市场建设,以发挥其对低碳技术创新的诱发作用;但在统一市场建设过程中应重视地区差异,分步骤稳步推进;还应注重加强政府政策信号管理,引导企业开展低碳技术创新活动。     

畜牧业污水中大环内酯和拟除虫菊酯类驱虫剂物质的LCMSMS检测

采用无需衍生化的同相萃取为前处理手段,高效液相色谱-串联四极杆质谱联用技术(LCMSMS)为检测手段,在电喷雾电离正离子模式下,对澳大利亚畜牧业污水中常见的大环内酯和拟除虫菊酯两类共7种驱虫剂物质的残留,建立了一次进样下的有效快速分析方法.经一系列优化试验,确定了以50%丙酮+50%乙腈为洗提剂、每次4 mL共8 mL的洗提方法.结果表明,该固相萃取技术(SPE)的加标回收试验结果较好,各化合物的平均回收率为95.50%～108.00%,相对标准差范围为0.73%-8.82%.以含10mmoL/L醋酸铵、0.1%甲酸的超纯水和甲醇混合溶液为流动相,以准分子离子峰[M+NH_4]~+、[M+H]~+作为母离子的定量离子对,所建立的1～500 ng/mL范围内的8点校正曲线中.各物质的相关系数均高于0.998 0,定量限范围为0.03-2.47 ng/mL.实际样品测定时.不同处理流程中各化合物的残留浓度有较好地体现.     

新疆宏观生态环境质量综合评价研究——以布尔津县为例

新疆地处中国西北典型干旱内陆区,生态环境比较恶劣,建立适合新疆的省区一级生态环境质量综合评价指标体系,将对科学、客观了解新疆乃至整个西北干旱区生态环境状况都具有十分重要的理论和实践意义。采用综合指数法,从降水量、植被指数、生态功能价值、土壤侵蚀、降尘量、悬浮物等6个方面选取指标,分别以景观单元和县市为评价单元,建立了简易合理、具可操作性的不同尺度的新疆生态环境质量评价指标体系,并确定了各指标的权值和相对的分级标准,为新疆生态环境现状的准确评价提供了可靠依据,对新疆社会经济的可持续发展和生态环境管理将起到积极作用。     

Uptake,translocation, and control of trumpet flower (Tecoma stans) with aminocyclopyrachlor

To gain a better understanding of the physiology of the herbicide aminocyclopyrachlor in young plants of trumpet flower, the uptake and translocation were evaluated after the application of herbicide. This was determined by treating individual leaves with formulated herbicides plus ¹⁴C-aminocyclopyrachlor after the application of the formulated herbicide. This experiment used a randomized experimental design with three replications. In addition, field studies were conducted to assess the effectiveness of foliar applications of aminocyclopyrachlor in association with metsulfuton-methyl. The plant absorbed 20% of the herbicide applied. The translocation percentage did not surpass 5% of the total amount applied. Only 1% of the herbicide applied was translocated to the roots. Rate of 40 + 13 g a.i. 100 L^?1 of aminocyclopyrachlor+metsulfuron-methyl was effective to control T. stans.     

Polybrominated diphenyl ethers, polychlorinated naphthalenes and polycyclic musks in human fat from Italy: Comparison to polychlorinated biphenyls and organochlorine pesticides

Prior to this study, reports of occurrence of polycyclic musks and polychlorinated naphthalenes (PCNs) in human tissues from Italy were not available. In this study, concentrations of PCNs and polycyclic musks were determined in human adipose tissue from Italy collected during 2005-2006; for comparison, legacy organohalogen pollutants such as organochlorine pesticides (OCPs), polychlorinated biphenyls (PCBs), and polybrominated diphenyl ethers (PBDEs) were determined. ΣPCN concentrations ranged from 0.5 to 14 ng/g lipid wt (lw). Polycyclic musks such as HHCB and AHTN were found in 92% and 83% of the human samples, respectively. Concentrations of PBDEs in Italian adipose tissue ranged between 3.2 and 35.6 ng/g lw.     

The Potential Use of Synthetic Aperture Radar for Estimating Methane Ebullition From Arctic Lakes1

Abstract: Arctic lakes are significant emitters of methane (CH₄), a potent greenhouse gas, to the atmosphere; yet no rigorous quantification of the magnitude and variability of pan‐Arctic lake emissions exists. In this study, we demonstrate the potential for a new method using synthetic aperture radar (SAR) imagery to detect methane bubbles in lake ice to scale up whole‐lake measurements of CH₄ ebullition (bubbling) to regional scales. We estimated ebullition from lakes, which is often the dominant mode of lake emissions, by mapping the distribution of bubble clusters frozen in early winter ice across surfaces of seven tundra lakes and one boreal forest lake in Alaska. Applying previously measured ebullition rates associated with four distinct classes of bubble clusters found in lake ice, we estimated whole‐lake emissions from individual lakes. The percent surface area of lake ice covered with bubbles (R² = 0.68) and CH₄ ebullition rates from lakes (R² = 0.59) and were correlated with radar return values from RADARSAT‐1 Standard Beam mode 3 for the tundra lakes, suggesting that with appropriate scaling and consideration for variability in lake‐ice conditions, this technique has the potential to be used for estimating broader‐scale regional and pan‐Arctic lake methane emissions.