全文获取类型
收费全文 | 652篇 |
免费 | 80篇 |
国内免费 | 189篇 |
专业分类
安全科学 | 113篇 |
废物处理 | 47篇 |
环保管理 | 77篇 |
综合类 | 417篇 |
基础理论 | 82篇 |
污染及防治 | 100篇 |
评价与监测 | 48篇 |
社会与环境 | 17篇 |
灾害及防治 | 20篇 |
出版年
2024年 | 2篇 |
2023年 | 11篇 |
2022年 | 17篇 |
2021年 | 19篇 |
2020年 | 14篇 |
2019年 | 19篇 |
2018年 | 16篇 |
2017年 | 33篇 |
2016年 | 35篇 |
2015年 | 35篇 |
2014年 | 37篇 |
2013年 | 43篇 |
2012年 | 54篇 |
2011年 | 67篇 |
2010年 | 43篇 |
2009年 | 52篇 |
2008年 | 31篇 |
2007年 | 54篇 |
2006年 | 51篇 |
2005年 | 33篇 |
2004年 | 34篇 |
2003年 | 21篇 |
2002年 | 33篇 |
2001年 | 19篇 |
2000年 | 30篇 |
1999年 | 19篇 |
1998年 | 16篇 |
1997年 | 16篇 |
1996年 | 15篇 |
1995年 | 14篇 |
1994年 | 7篇 |
1993年 | 7篇 |
1992年 | 6篇 |
1991年 | 4篇 |
1989年 | 1篇 |
1988年 | 2篇 |
1986年 | 2篇 |
1982年 | 1篇 |
1978年 | 1篇 |
1977年 | 1篇 |
1973年 | 1篇 |
1972年 | 1篇 |
1971年 | 2篇 |
1970年 | 1篇 |
1969年 | 1篇 |
排序方式: 共有921条查询结果,搜索用时 9 毫秒
51.
为评价海港疏浚淤泥对倾倒海区海洋动物的影响,对疏浚淤泥悬浮相进行了生物急性毒性试验。研究结果表明:疏浚淤泥悬浮相对浮游甲壳类的致毒效应明显。22.0~24.0℃试验水温时,悬浮相对卤虫无节幼体和浮游挠足类的急性毒性试验结果分别为:96hLC50为71.6mg/L(卤虫无节幼体),48hLC50为61.3mg/L(浮游挠足类)。低浓度和低温时,悬浮相对前鳞鲻(Mugilophuyseni)幼鱼的致毒效应不明显。随温度的升高,毒性效应亦增强。试验水温为18.8~20.0℃时,悬浮相对前鳞鲻幼鱼24h和96hLC50分别为5801.3mg/L和5045.5mg/L;而当试验水温升至22.0~24.0℃时,悬浮相对前鳞鲻幼鱼24、48、72、96hLC50分别为1996.4、769.9、592.8及556.3mg/L。 相似文献
52.
Bryan Butter Paola Santander Guadalupe del C. Pizarro Diego P. Oyarzún Federico Tasc Julio Sánchez 《环境科学学报(英文版)》2021,33(3):304-312
Chromium (Cr) is used in many manufacturing processes, and its release into natural waters is a major environmental problem today. Low concentrations of Cr(VI) are toxic to human health and living organisms due to the carcinogenic and mutagenic nature of this mineral. This work examined the conversion of Cr(VI) to Cr(III) via electrochemical reduction using gold electrode in an acidic sodium alginate (SA) solution and subsequent removal of the produced Cr(III)-SA by the polymer-enhanced ultrafiltration (PEUF) technique. A solution of SA in nitric acid was used both as an electrolytic medium during the voltammetric measurements and bulk electrolysis and as an extracting agent during the PEUF technique. The electroanalysis of Cr(VI) was performed by linear sweep voltammetry in the presence of acidic SA solution to study its voltammetric behavior as a function of the Cr(VI) concentration, pH, presence of Cr(III), SA concentration and scan rate. In addition, the quantitative reduction of Cr(VI) to Cr(III) was studied through the bulk electrolysis technique.The results showed efficient reduction with well-defined peaks at approximately 0.3 V vs. Ag/AgCl, using a gold working electrode. As the pH increased, the reduction signal strongly decreased until its disappearance. The optimum SA concentration was 10 mmol/L, and it was observed that the presence of Cr(III) did not interfere in the Cr(VI) electroanalysis. Through the quantitative reduction by bulk electrolysis in the presence of acidic SA solution, it was possible to reduce all Cr(VI) to Cr(III) followed by its removal via PEUF. 相似文献
53.
硒的生物可利用性、毒性、环境行为和生物效应等不仅仅与硒的总量有关,更取决于硒的形态。硒的连续化学提取技术是硒形态研究的一个重要手段。在硒七步连续提取方案的基础上,重点探讨了有机结合态、元素态、硫化物/硒化物结合态硒的提取技术细节,讨论了不同液固比和提取剂对硒提取的影响,并对不同结合态硒提取中存在的问题进行了相应讨论。研究结果表明:在硒的连续化学提取过程中,液固比为20:1到50:1时能够满足不同结合态硒提取的要求;在水浴加热条件下,NaOH浓度0.1~0.5mol/L时能有效提取有机结合态硒;1mol/LNa2SO3溶液是元素硒的较好提取剂;而对于硫化物/硒化物结合态硒,600~700ml/min的载气气流能保证其还原所产生HSe气体的完全吸收。 相似文献
54.
森林合理年伐量分析确定方法研究 总被引:1,自引:0,他引:1
森林合理年伐分析确定是年森林采伐限额编制的关键技术之一,也是森林经理学的重要内容之一。本文从森林永续利用理论出发,以消长比度、成熟林采伐度、龄级结构改善度、流量均衡度、需要满足度5个指标建立了分析确定的综合评价模型,提出了森林合理年伐量分析确定的精确化方法,从而有效地保证了结果的科学性和准确性。 相似文献
55.
56.
57.
58.
Qing YE Donghui LI Jun ZHAO Jiansheng ZHAO Tianfang KANG Shuiyuan CHENG 《Frontiers of Environmental Science & Engineering》2011,5(4):497-504
Au-supported 13X-type zeolite (Au/13X) was synthesized using a common deposition–precipitation (DP) method with a solution of sodium carbonate as a precipitate agent. Further testing was conducted to test for catalytic oxidation of CO. A study was conducted on the effects of different preparation conditions (i.e., chloroauric acid concentration, solution temperature, pH of solution, and calcinations temperature) on Au/13X for CO oxidation. In respect to the catalytic activity, the relationship between different the preparation conditions and gold particles in 13X zeolite was analyzed using X-ray diffraction, TEM and XPS. The activity of Au/13X catalysts in CO oxidation was dependent on the chloroauric acid concentration. From XRD results, a higher chloroauric acid concentration induced larger gold nanoparticles, which resulted in lower catalytic activity. Results revealed that higher temperatures induced higher Au loading, homogeneous deposit, and smaller gold clusters on the support of 13X, resulting in higher CO activity. Furthermore, a pH of 5 or 6 generated greater amounts of Au loading and smaller Au particles on 13X than at a pH of 8 or 9. This may be a result of an effective exchange between A u ( O H ) 2 C l 2 - and Au(OH)3Cl- on specific surface sites of zeolite under the pH’s 5 and 6. The sample calcined at 300°C showed the highest activity, which may be due to the sample’s calcined at 200°C inability to decompose completely to metallic gold while the sample calcined at 400°C had larger particles of gold deposited on the support. It can be concluded from this study that Au/13X prepared from a gold solution with an initial chloroauric acid solution concentration of 1.5 × 10-3 mol·L-1 gold solution pH of 6, solution temperature of around 90°C, and a calcination temperature of 300°C provides optimum catalytic activity for CO oxidation. 相似文献
59.
为获得某金矿尾砂胶结充填材料最优配比,基于试验结果,以海水比例、灰砂比和料浆质量浓度为输入参数,以充填体强度、塌落度及泌水率为输出参数,建立了充填配比与其响应量的高斯过程回归模型,分析了不同因素对充填性能的影响程度;采用遗传算法对高斯过程回归模型进行多目标参数优化,获得了Pareto非劣解,在此基础上,引入多属性决策的TOPSIS法对Pareto非劣解进行方案优选,确定了充填最优配比。研究结果表明:高斯过程回归模型相对误差值均小于6%,可靠性高;灰砂比及料浆质量浓度对充填性能影响较为显著,采用海水作为充填水源将降低充填体的强度;经优化后的充填配比与试验结果相符。 相似文献
60.