宁波市区道路机动车综合排放因子

机动车综合排放因子是计算城市机动车污染物排放总量和排放分担率的基础,是降低城市机动车排放的重要依据,是控制城市道路交通污染的源头.根据宁波市区道路机动车运行工况的研究成果,利用加速模拟工况(ASM)排放测试系统,检测主要污染物HC,CO和NO_x的排放浓度;依据试验车变速器和主减速器的结构参数,以及试验车在宁波市区道路运行时的档位分布计算排污值,并依据机动车的年代和车型分布对该值进行修正,计算宁波市区道路机动车综合排放因子.结果表明,宁波市区道路机动车主要污染物HC,CO和NO_x的综合排放因子分别为5.89,21.22和18.91 g/(km·辆).      

水流模拟断面中硝基苯的迁移转化规律

采用实验室模拟装置研究了4,10和20 ℃条件下,封闭、开放状态和不同环境因素影响下硝基苯污染水团流经模拟断面前后, 硝基苯在上覆水与沉积物中的迁移转化规律. 结果表明:封闭、开放状态模拟断面上覆水和沉积物中硝基苯迁移分配受温度变化影响显著;开放状态下,上覆水、沉积物中硝基苯变化量均低于封闭状态. 挥发不但影响硝基苯在沉积物-上覆水间的迁移分配,而且能促进沉积物中硝基苯的解吸;光照对模拟断面硝基苯迁移转化无影响. 对于相同的沉积物和上覆水,影响模拟断面系统中硝基苯迁移、分配的因素依次为温度、挥发和光照. 分析实验结果和材料推测,硝基苯在该实验条件下不存在降解转化.      

四川省餐饮源挥发性有机物组分特征和清单

选取四川省12家典型餐饮单位开展了NMHCs浓度和VOCs组分监测,结合已有数据,综合建立了含117种VOCs组分的餐饮源组分谱,获得本地化NMHCs排放因子,基于自下而上的研究方法,建立了四川省餐饮源挥发性有机物排放清单.结果表明,含氧和烷烃两类组分为川菜、烧烤和食堂餐饮的最主要的组分,二者合计质量分数在75%以上,主要VOCs物种为乙醇、甲醛、乙烷、己醛、乙烯、 1,3-丁二烯和丙烯醛等;含氧组分对OFP的贡献最大,其次是烯烃,主要OFP贡献物种为甲醛、乙烯、乙醇、 1,3-丁二烯、丙烯醛和己醛等. 2019年四川省餐饮源VOCs排放量和OFP值分别为32 kt和141 kt,分别占四川省人为源VOCs排放量和OFP值的5%左右,餐饮源对臭氧生成可能有重要贡献,应加大餐饮源挥发性有机物管控力度.     

Some characteristics of the distribution of heavy metals in urban topsoil of Xuzhou,China

An assessment is presented of distribution characteristics of heavy metals in the urban topsoil from the city of Xuzhou. The concentrations of Ag, Al, As, Au, Ba, Be, Bi, Cd, Co, Cr, Cu, Fe, Ga, Hg, Li, Mn, Mo, Ni, Pb, Pd, Pt, Sb, Sc, Se, Sn, V and Zn have been determined from 21 soil samples. Examination of lognormal distribution plots indicates that the diagrams of Al, Be, Fe, Ga, Li, and V are almost linear suggesting that these metals are almost unaffected by anthropogenic activities while the plots for As, Cd, Cu, Pb, Pd, Pt, Se, Zn and others are not linear probably due to anthropogenic activities from which these metals are delivered to the soils. Al is used for mineralogical normalization of these data. An evaluation of background values for topsoil is also carried out by means of lognormal distribution plots. The results show our background values obtained from the lognormal distribution plots are comparable to those values of uncontaminated soils of Xuzhou obtained by previous work except for Cd and Hg. At present, no explanation for the exceptions Cd and Hg can be given.     

悬浮法聚氯乙烯化工离心母液的生化处理中试

采用4级内循环式好氧生物膜反应器串联工艺对悬浮法聚氯乙烯(PVC)离心母液废水进行中试试验,研究了不同停留时间下系统对有机物和浊度的处理效果以及系统的抗冲击能力;观察了生物膜的生长和发展规律;对影响系统稳定运行的主要因素(悬浮物、摇蚊幼虫和营养物)进行了分析,并提出了相应的控制措施.试验结果表明:该工艺启动迅速,在HRT为14h时,废水COD总去除率可达75%以上,出水COD浓度低于50mg/L ,完全可以达到排放标准,也可经深度处理回用于生产.     

Investigation of natural VOC emitted from tropical vegetations in China

Twenty-three kinds of typical plants in Xishuangbanna, the tropical area of southwestern China, were screened to estimate the emission rates of isoprene and monoterpenes by adopting bag-enclosure and curette sampling methods followed by a GC-FID analysis. It was found that the Ficus species were mainly emitting isoprene and most tropical vegetations were mainly releasing monoterpenes. The results also showed that the emissions of isoprene were affected by both temperature and PAR( Photosynthetic Active Radiation), while monoterpene emissions were mainly temperature-dependent.     

酯类化合物对四膜虫毒性的拓扑研究

提出了拓扑方法,即考虑分子图顶点的性质,直接用酯类化合物的分子碎片的特征值为主元来构建邻接矩阵。定义并计算了酯类化合物的修正的氢连接性指数^mHA及其倒指数^mHB,分析了30个酯化合物对四膜虫的毒性与分子结构之间的关系,结果表明由酯化合物对四膜虫毒性与^mH的回归方程得出的估算值与实验测定值之间能较好地吻合,平均误差为0．22。     

荷电水雾除尘器捕尘效率的实验研究

实验分析了影响荷电水雾除尘器除尘效率的主要因素,在此基础上提出了一种新的除尘效率数学模型,该模型明确地表达了过滤风速、喷雾量以及雾滴荷质比对除尘效率的贡献情况。对实验结果及数学模型的分析表明,对于带有振弦栅的荷电水雾除尘系统,喷雾量对除尘效率的影响比过滤风速及荷质比更为显著,新除尘效率模型的提出对指导生产具有重要意义。实验中同时确定了荷电水雾除尘器最佳操作参数,在粉尘入口浓度为412 mg/m3的情况下,当过滤风速为16 m/s,喷雾量为12×10-3 m3/min,雾滴荷质为3.5×10-4 c/kg时,除尘效率可达99.5%。     

基于GFI模型的工业能源强度变动因素分解研究

在前人研究的基础上,核算了2001-2010年天津市34个工业行业的能源强度,利用GFI(Generalized Fisher Index)模型将能源强度的变动分解为技术进步、能源结构和产业结构3个因素.结果表明,从逐年各因素效应的累积值来看,产业结构对天津市能源强度变动的影响最大,其次是能源结构,技术进步的影响较小;在各因素效应值的波动方面,能源结构与技术进步对能源强度变动的影响波动较小,产业结构的影响效应值波动较大.从产业结构的角度来看,天津市2001-2010年重工业产值的增加快于轻工业,二者的差距逐渐加大,这种态势抑制了能源强度的降低;从技术进步的角度来看,由于绿色生产技术的广泛使用,天津市重工业与轻工业的单位产值能源消耗都呈下降趋势.因此,天津市进一步降低能源强度的重点还应该放在产业结构调整方面,发展绿色产业,促进产业升级;同时,不能忽视能源结构和技术进步因素的作用,大力发展绿色能源和新能源,推广清洁生产技术.     

On Uncertain Sightings and Inference about Extinction

The extinction of many species can only be inferred from the record of sightings of individuals. Solow et al. (2012, Uncertain sightings and the extinction of the Ivory‐billed Woodpecker. Conservation Biology 26: 180–184) describe a Bayesian approach to such inference and apply it to a sighting record of the Ivory‐billed Woodpecker (Campephilus principalis). A feature of this sighting record is that all uncertain sightings occurred after the most recent certain sighting. However, this appears to be an artifact. We extended this earlier work in 2 ways. First, we allowed for overlap in time between certain and uncertain sightings. Second, we considered 2 plausible statistical models of a sighting record. In one of these models, certain and uncertain sightings that are valid arise from the same process whereas in the other they arise from independent processes. We applied both models to the case of the Ivory‐billed Woodpecker. The result from the first model did not favor extinction, whereas the result for the second model did. This underscores the importance, in applying tests for extinction, of understanding what could be called the natural history of the sighting record. Sobre Avistamientos Inciertos e Inferencia de la Extinción