MIL-101前体制备多孔铁碳材料构建高效异相电芬顿体系

通过水热法合成MIL-101(Fe)材料,并在N2氛围中进行高温碳化制备多孔铁碳(N-MIL-FeC)电极材料,探究其电催化氧还原性能及阴极电芬顿降解模拟染料废水性能。将制备的N-MIL-FeC材料进行电催化氧还原反应(ORR)性能测试,结果表明,Fe/H2BDC摩尔比为2∶1,碳化温度为900 ℃,N-MIL-FeC材料CV扫描所得图形峰电位最小且峰电流最高,具有最优的ORR催化活性。在此基础上,将最佳条件下制得的N-MIL-FeC负载在碳纸上制成催化阴极应用于电芬顿反应催化降解模拟染料废水RhB。在催化剂负载量为1.5 mg·cm-2,pH为7条件下,浓度10 mg·L-1的RhB溶液经过70 min降解率达到99%以上。通过淬灭实验和电子顺磁共振(EPR)测试证明羟基自由基(·OH)是参与催化降解反应的主要活性中间体。以MIL-101(Fe)为前驱体制备的多孔铁碳材料性能较好,有一定的应用前景。     

Valuation of ecotoxicological impacts from tributyltin based on a quantitative environmental assessment framework

In the scientific literature, few valuations of biodiversity and ecosystem services following the impacts of toxicity are available, hampered by the lack of ecotoxicological documentation. Here, tributyltin is used to conduct a contingent valuation study as well as cost–benefit analysis (CBA) of measures for improving the environmental status in Swedish coastal waters of the Baltic Sea. Benefits considering different dimensions when assessing environmental status are highlighted and a quantitative environmental assessment framework based on available technology, ecological conditions, and economic valuation methodology is developed. Two scenarios are used in the valuation study: (a) achieving good environmental status by 2020 in accordance with EU legislation (USD 119 household⁻¹ year⁻¹) and (b) achieving visible improvements by 2100 due to natural degradation (USD 108 household⁻¹ year⁻¹) during 8 years. The later scenario was used to illustrate an application of the assessment framework. The CBA results indicate that both scenarios might generate a welfare improvement.

Electronic supplementary material

The online version of this article (doi:10.1007/s13280-015-0682-4) contains supplementary material, which is available to authorized users.     

经济发展成本分析:可持续发展经济学的理论基础

可持续发展战略存在着理论与实践上的严重反差，其主要原因是可持续发展经济缺乏统一的理论基础，本文通过对经济学不同流派关于可持续发展问题研究的评析，认为可持续发展经济学需要建立一个统一的理论基础，并提出经济发展成本分析是可持续发展经济学的理论基础，围绕这一理论基础对可持续发展的概念进行了重新界定，并主张要把制度的激励与约束以及政策的引导纳入可持续发展经济途径研究的视野之中。     

Exploring the information literacy of professionals in safety management

With the rapid development of increasingly complex technology and large scale industrial projects, all kinds of safety problems become extremely intricate in daily safety management (SM). It is therefore indispensable to effectively collect, analyze, assess, and synthesize information that is relevant to accident risk. In this paper, the concept of the information literacy (IL) of professionals in SM is proposed, and a conceptual framework is put forward. Further, determinants of the IL of safety professionals are suggested, including individual attributes, safety climate and culture, information infrastructure, information technology (IT) human resources, production technology and management, and national information policy, law and ethics. Of course, further research on the IL of safety professionals should be carried out for effective SM.     

水资源多目标协同配置:全价值基础上的框架研究

从资源的视角而言,水资源具有的社会、经济、生态属性中,社会属性和生态属性所提供的生态功能和服务多是外部性和非市场的,其价值在纯粹的市场驱动下难以充分实现。从资源管理视角而言,水资源多目标协同配置的实质是水资源多重属性功能和服务的均衡。因此,将具有外部性的社会、生态功能和服务与具有经济价值的功能和服务同时纳入配置框架,是实现多目标协同配置实践的关键问题。本文在回顾水资源配置和水资源非市场价值评估的相关研究的基础上,围绕我国现行水资源配置存在的主要问题,通过水资源的全价值(市场价值和非市场价值)将其多属性功能和公众意愿纳入水资源多目标协同配置中,从水资源管理信息系统、全价值评估和配置管理的绩效评价三个方面构建了水资源配置的多目标协同框架,最后提出相关的保障政策建议。     

生物降解途径的理论预测与QSBR研究

本文把有机污染生生物降解途径理论预测的结果与ＱＳＢＲ模型中化合物选择相结合，所遵循相同理论生物降解途径作为化合物分组的原则，以分子连接性接数和ＥＨＯＭＯ作为结构参数与电性参数，采用逐步回归的方法建立了新的ＱＳＢＲ模型，新模型的预测民实验结果能较好地吻合。     

建立我国生态环境标准体系的初步构想

我国的生态环境标准极其薄弱，建立生态环境标准体系是我国生态环境保护的迫切需要。借鉴我国目前针对污染防治的环境标准体系，提出了我国生态环境标准体系的基本框架，以及生态环境标准制订的原则和重点。     

加压溶气气浮设备理论溶气量的计算

本文通过对加压溶气过程的分析 ,建立了理想加压溶气过程模型 ,在此基础上推导出新的理论溶气量计算公式 ,并与现有的计算公式进行了比较。     

建立我国生态环境标准体系的初步构想

我国的生态环境标准极其薄弱,建立生态环境标准体系是我国生态环境保护的迫切需要。借鉴我国目前针对污染防治的环境标准体系,提出了我国生态环境标准体系的基本框架,以及生态环境标准制订的原则和重点。     

Improving protected area effectiveness through consideration of different human-pressure baselines

Previous assessments of the effectiveness of protected areas (PAs) focused primarily on changes in human pressure over time and did not consider the different human-pressure baselines of PAs, thereby potentially over- or underestimating PA effectiveness. We developed a framework that considers both human-pressure baseline and change in human pressure over time and assessed the effectiveness of 338 PAs in China from 2010 to 2020. The initial state of human pressure on PAs was taken as the baseline, and changes in human pressure index (HPI) were further analyzed under different baselines. We used the random forest models to identify the management measures that most improved effectiveness in resisting human pressure for the PAs with different baselines. Finally, the relationships between the changes in the HPI and the changes in natural ecosystems in PAs were analyzed with different baselines. Of PAs with low HPI baselines, medium HPI baselines, and high HPI baselines, 76.92% (n=150), 11.11% (n=12), and 22.86% (n=8) , respectively, showed positive effects in resisting human pressure. Overall, ignoring human-pressure baselines somewhat underestimated the positive effects of PAs, especially for those with low initial human pressure. For PAs with different initial human pressures, different management measures should be taken to improve effectiveness and reduce threats to natural ecosystems. We believe our framework is useful for assessing the effectiveness of PAs globally, and we recommend it be included in the Convention on Biological Diversity Post-2020 Strategy.