电气自动化系统在烟气脱硫工程中的应用

结合国电宣威发电有限责任公司七期(2×300 MW)机组烟气脱硫工程电气自动化系统(ECS)实施的经验,从应用的角度出发,分析了火电厂ECS通过硬接线、硬接线 通信、全通信3种方式接入DCS的优缺点和需要解决的问题,提出全通信的组网方式,展望了ECS最终实现全通信的前景和目标.     

嘉兴电厂2×300MW机组脱硝方案的对比分析

根据嘉兴电厂的实际情况，在对6种主流脱硝工艺进行技术经济分析的基础上，结合电厂近期和远期的NOx控制目标，对各种脱硝工艺的组合进行研究，推荐了可行的脱硝方案，为工程的实施提供了可靠的技术依据。     

某厂化学装置爆炸对设备房结构的损坏——调查与模拟分析

在对某厂化学爆炸所作的现场调查的基础上，对设备房钢筋混凝土框架结构构件的受损状况进行了分类描述，采用有限元方法对框架结构在静力和爆炸冲击荷载下的反应进行了模拟分析，分析结果与现场调查情况基本一致，给出了一些有意义的结论。     

低瓦斯矿井瓦斯爆炸事故的主要原因及防治对策

从理论和实际两方面分析了近期发生在一些低瓦斯矿井的瓦斯爆炸事故,结合对福建煤矿曾经发生的瓦斯爆炸事故的分析和研讨,认为发生瓦斯爆炸事故的主要原因有:对瓦斯防治重视不够、未能准确地确定瓦斯的爆炸下限浓度及瓦斯混合气体在强点火能下会降低瓦斯爆炸浓度下限等主观上的原因,还有因采深加大致使瓦斯涌出量增加、瓦斯监测系统不到位等客观上的原因。着重从大量的试验证明了在强点火能下瓦斯混合气体爆炸浓度下限大幅降低的事实,并提出了相关的防治对策。研究成果对瓦斯防治具有重要的实际意义。     

复合无机防火涂料优配研究

以市售无机膨胀型AB牌防火涂料为研究基础,复合了膨胀阻燃剂(APP-MEL-PER阻燃体系)、抑烟剂和助剂,进行了新型防火涂料的制备,当膨胀阻燃体系(APP-MEL-PER阻燃体系)以17∶6∶6的配比混合于该涂料中,其所占质量百分比为19%的时,防火性能最好。测试表明,该新型防火涂料烟密度等级6.77,指数下降了10,接近于国家标准1级。在248℃~400℃期间失重仅为12%,在390℃,有强烈的吸收峰,也表现了优异的阻燃性能。实现了APP-MEL-PER膨胀阻燃剂和AB牌涂料优配的目的。     

天然气钻井井口安全距离研究分析

分析天然气钻井井场可能发生的事故类型及事故的破坏程度,选择适合的事故后果模型,对天然气井井喷失控后可能发生的蒸气云爆炸及硫化氢扩散的后果进行量化分析,根据超压-冲量准则、热剂量准则和硫化氢扩散行为规律,计算出爆炸波、爆炸火球及硫化氢扩散的危害范围。笔者建立了天然气钻井井口安全距离的计算模型,并提出一种确定安全距离的方法。通过计算给出不同无阻流量、不同硫化氢体积含量的20种条件下的天然气钻井井口安全距离,并应用该模型对某含硫气井井口安全距离进行了计算。实例表明,该方法具备实用性,值得在天然气井选址规划中推广和使用。     

Modeling of n-butane ignition, combustion, and preflame oxidation in the 20-l vessel

The objective of the study reported herein is to simulate various physical and chemical phenomena accompanying fuel-rich n-butane–oxygen mixture preparation, ignition, preflame oxidation, and combustion in the standard 20-l explosion vessel, by applying mathematical models. Based on the computational fluid dynamics (CFD) simulations of the mixing process and natural convection of the ignition kernel, as well as on the analysis of the detailed reaction mechanism of n-butane oxidation, laminar flame propagation, and self-ignition, possible explanations for the phenomena observed experimentally have been suggested. The results of the study indicate that seemingly inflammable mixtures can become hazardous depending on the mixture preparation procedure and forced ignition timing.     

Post-explosion observations of experimental mine and laboratory coal dust explosions

The Pittsburgh Research Laboratory (PRL) of the National Institute for Occupational Safety and Health (NIOSH) and the Mine Safety and Health Administration (MSHA) conducted joint research on dust explosions by studying post-explosion dust samples. The samples were collected after full-scale explosions at the PRL Lake Lynn Experimental Mine (LLEM), and after laboratory explosions in the PRL 20-L chamber and the Fike 1 m³ chamber. The dusts studied included both high- and low-volatile bituminous coals. Low temperature ashing for 24 h at 515 °C was used to measure the incombustible content of the dust before and after the explosions. The data showed that the post-explosion incombustible content was always as high as, or higher than the initial incombustible content. The MSHA alcohol coking test was used to determine the amount of coked dust in the post-explosion samples. The results showed that almost all coal dust that was suspended within the explosion flame produced significant amounts of coke. Measurements of floor dust concentrations after LLEM explosions were compared with the initial dust loadings to determine the transport distance of dust during an explosion. All these data will be useful in future forensic investigations of accidental dust explosions in coal mines, or elsewhere.     

Determination of turbulent burning velocities of dust air mixtures with the open tube method

Correlating turbulent burning velocity to turbulence intensity and basic flame parameters-like laminar burning velocity for dust air mixtures is not only a scientific challenge but also of practical importance for the modelling of dust flame propagation in industrial facilities and choice of adequate safety strategy. The open tube method has been implemented to measure laminar and turbulent burning velocities at laboratory scale for turbulence intensities in the range of a few m/s. Special care has been given to the experimental technique so that a direct access to the desired parameters was possible minimising interpretation difficulties. In particular, the flame is propagating freely, the flame velocity is directly accessible by visualisation and the turbulence intensity is measured at the flame front during flame propagation with special aerodynamic probes. In the present paper, those achievements are briefly recalled. In addition, a complete set of experiments for diametrically opposed dusts, starch and aluminium, has been performed and is presented hereafter. The experimental data, measured for potato dust air mixtures seem to be in accordance with the Bray Gülder model in the range of 1.5 m/s<u′<3.5 m/s. For a further confirmation, the measurement range has been extended to lower levels of turbulence of u′<1.5 m/s. This could be achieved by changing the mode of preparation of the dust air mixture. In former tests, the particles have been injected into the tube from a pressurised dust reservoir; for the lower turbulence range, the particles have been inserted into the tube from above by means of a sieve–riddler system, and the turbulence generated from the pressurised gas reservoir as before. For higher levels of turbulence, aluminium air mixtures have been investigated using the particle injection mode with pressurised dust reservoir. Due to high burning rates much higher flame speeds than for potato dusts of up to 23 m/s have been obtained.     

“Vybuchovy trojuhelnik”: A software tool for evaluation of explosibility of coal mine atmosphere

Rescue operations during mine fires or methane explosions are highly dangerous for rescue workers. The knowledge of the composition of the coal mine atmosphere and the calculations of its explosibility may help to increase the safety of the rescuers. In the Czech Republic, a system called “Mine Gas Laboratory” (DPL) has been used for these purposes. The DPL allows measurement of the composition of the mine atmosphere and transmits the data necessary for evaluation to the surface. Up to now the explosibility evaluation of the coal mine atmosphere has depended either on the rescuers’ experience or on software code calculation. The code called “Vybuchovy trojuhelnik” (explosion triangle) is a graphical computing system intended for fast assessment of explosibility of fuel–air mixture. This article introduces the code and describes two simple methods of explosibility evaluation. The first method is “explosion triangle analysis”—a graphical method based on empirical graphs transformed into equations. The second method uses thermodynamic calculation based on chemical balance dynamics and Gibbs and Helmholtz energy. According to the requirements of the Czech Bureau of Mining (CBU) and Central Mine Rescue Service (HBZS), the code solves the problems of explosion triangle for both standard and non-standard coal mine atmosphere compositions. Unfortunately, the atmosphere composition must be introduced manually due to the unknown format of the data transmitted from the old DPL model. On 1 September 2005, a project started to develop a new system for on-line monitoring and atmosphere explosibility evaluation. The system should be able to measure CO₂, O₂, CH₄, H₂ and CO concentrations as well as the wind speed, temperature and humidity. The “Vybuchovy trojuhelnik” code will be used as a basis for explosibility evaluation, and an on-line connection with the new model of DPL will be established.