全文获取类型
收费全文 | 1761篇 |
免费 | 183篇 |
国内免费 | 512篇 |
专业分类
安全科学 | 34篇 |
废物处理 | 11篇 |
环保管理 | 194篇 |
综合类 | 771篇 |
基础理论 | 1089篇 |
污染及防治 | 161篇 |
评价与监测 | 68篇 |
社会与环境 | 124篇 |
灾害及防治 | 4篇 |
出版年
2024年 | 3篇 |
2023年 | 43篇 |
2022年 | 69篇 |
2021年 | 76篇 |
2020年 | 94篇 |
2019年 | 65篇 |
2018年 | 64篇 |
2017年 | 87篇 |
2016年 | 86篇 |
2015年 | 103篇 |
2014年 | 104篇 |
2013年 | 144篇 |
2012年 | 122篇 |
2011年 | 172篇 |
2010年 | 126篇 |
2009年 | 127篇 |
2008年 | 136篇 |
2007年 | 157篇 |
2006年 | 100篇 |
2005年 | 108篇 |
2004年 | 80篇 |
2003年 | 71篇 |
2002年 | 45篇 |
2001年 | 32篇 |
2000年 | 43篇 |
1999年 | 28篇 |
1998年 | 25篇 |
1997年 | 21篇 |
1996年 | 28篇 |
1995年 | 19篇 |
1994年 | 16篇 |
1993年 | 15篇 |
1992年 | 11篇 |
1991年 | 5篇 |
1990年 | 6篇 |
1989年 | 4篇 |
1988年 | 3篇 |
1987年 | 5篇 |
1986年 | 4篇 |
1984年 | 4篇 |
1982年 | 1篇 |
1981年 | 2篇 |
1973年 | 1篇 |
1972年 | 1篇 |
排序方式: 共有2456条查询结果,搜索用时 78 毫秒
81.
The hydrolysis/precipitation behaviors of Al3+, Al13 and Al30 under conditions typical for flocculation in water treatment were investigated by studying the particulates' size development, charge characteristics, chemical species and speciation transformation of coagulant hydrolysis precipitates. The optimal pH conditions for hydrolysis precipitates formation for AlCl3, PACAl13 and PACAl30 were 6.5–7.5, 8.5–9.5, and 7.5–9.5, respectively. The precipitates' formation rate increased with the increase in dosage, and the relative rates were AlCl3 ? PACAl30 > PACAl13. The precipitates' size increased when the dosage increased from 50 μM to 200 μM, but it decreased when the dosage increased to 800 μM. The Zeta potential of coagulant hydrolysis precipitates decreased with the increase in pH for the three coagulants. The iso-electric points of the freshly formed precipitates for AlCl3, PACAl13 and PACAl30 were 7.3, 9.6 and 9.2, respectively. The Zeta potentials of AlCl3 hydrolysis precipitates were lower than those of PACAl13 and PACAl30 when pH > 5.0. The Zeta potential of PACAl30 hydrolysis precipitates was higher than that of PACAl13 at the acidic side, but lower at the alkaline side. The dosage had no obvious effect on the Zeta potential of hydrolysis precipitates under fixed pH conditions. The increase in Zeta potential with the increase in dosage under uncontrolled pH conditions was due to the pH depression caused by coagulant addition. Al–Ferron research indicated that the hydrolysis precipitates of AlCl3 were composed of amorphous Al(OH)3 precipitates, but those of PACAl13 and PACAl30 were composed of aggregates of Al13 and Al30, respectively. Al3+ was the most un-stable species in coagulants, and its hydrolysis was remarkably influenced by solution pH. Al13 and Al30 species were very stable, and solution pH and aging had little effect on the chemical species of their hydrolysis products. The research method involving coagulant hydrolysis precipitates based on Al–Ferron reaction kinetics was studied in detail. The Al species classification based on complex reaction kinetic of hydrolysis precipitates and Ferron reagent was different from that measured in a conventional coagulant assay using the Al–Ferron method. The chemical composition of Ala, Alb and Alc depended on coagulant and solution pH. The Alb measured in the current case was different from Keggin Al13, and the high Alb content in the AlCl3 hydrolysis precipitates could not used as testimony that most of the Al3+ was converted to highly charged Al13 species during AlCl3 coagulation. 相似文献
82.
Baer SG Engle DM Knops JM Langeland KA Maxwell BD Menalled FD Symstad AJ 《Environmental management》2009,43(2):189-196
Vast areas of arable land have been retired from crop production and “rehabilitated” to improved system states through landowner
incentive programs in the United States (e.g., Conservation and Wetland Reserve Programs), as well as Europe (i.e., Agri-Environment
Schemes). Our review of studies conducted on invasion of rehabilitated agricultural production systems by nontarget species
elucidates several factors that may increase the vulnerability of these systems to invasion. These systems often exist in
highly fragmented and agriculturally dominated landscapes, where propagule sources of target species for colonization may
be limited, and are established under conditions where legacies of past disturbance persist and prevent target species from
persisting. Furthermore, rehabilitation approaches often do not include or successfully attain all target species or historical
ecological processes (e.g., hydrology, grazing, and/or fire cycles) key to resisting invasion. Uncertainty surrounds ways
in which nontarget species may compromise long term goals of improving biodiversity and ecosystem services through rehabilitation
efforts on former agricultural production lands. This review demonstrates that more studies are needed on the extent and ecological
impacts of nontarget species as related to the goals of rehabilitation efforts to secure current and future environmental
benefits arising from this widespread conservation practice. 相似文献
83.
Kerry A. Brown J. Carter Ingram Dan F. B. Flynn Rova Razafindrazaka Vololoniaina Jeannoda 《Environmental management》2009,44(1):136-148
Despite their prevalence in both developed and developing countries, there have been surprisingly few field assessments of
the ecological effectiveness of protected areas. This study aimed to assess the effectiveness of a key protected area in eastern
Madagascar, Ranomafana National Park (RNP). We established paired 100 × 4-m vegetation transects (400 m2) within RNP and in remnant forests in the park’s peripheral zone. In each 400-m2 plot, all woody stems >1.5 cm in diameter at breast height were measured and identified to species. All species were also
identified as native or non-native. We identified utilitarian species within all transects and they were sorted into use category.
We calculated plot-level taxonomic biodiversity and functional diversity of utilitarian species; the latter was calculated
by clustering the multivariate distances between species based on their utilitarian traits, and all metrics were tested using
paired t-tests. Our results showed that there was significantly higher biodiversity inside RNP than in remnant forests and this pattern
was consistent across all diversity metrics examined. Forests not located within the park’s boundary had significantly higher
non-native species than within RNP. There was no statistically significant difference in functional diversity of utilitarian
species inside RNP vs. remnant forests; however, the overall trend was toward higher diversity inside park boundaries. These
findings suggested that RNP has been effective at maintaining taxonomic diversity relative to surrounding unprotected areas
and restricting the spread of non-native plants. The results also suggested that low functional redundancy of forests outside
of RNP might be of concern, because residents in surrounding villages may have few other substitutes for the services provided
by species that are of critical importance to their livelihoods. This study highlights the challenges of trying to reconcile
biodiversity conservation with human use of natural resources in economically poor, remote areas. 相似文献
84.
生物入侵中入侵种与土著种的相互作用 总被引:3,自引:0,他引:3
在全球范围内,生物入侵已经成为一个非常严重的环境问题,并产生了生态问题和经济问题。本文阐述了生物入侵中入侵种自身的变化及对土著种的影响,并讨论了生物入侵过程中入侵种与土著种的快速进化问题。 相似文献
85.
This article analyzes and carries out an econometric test of the explanatory power of economic and attitude variables for
occurrences of the nonnative signal crayfish in Swedish waters. Signal crayfish are a carrier of plague which threatens the
native noble crayfish with extinction. Crayfish are associated with recreational and cultural traditions in Sweden, which
may run against environmental preferences for preserving native species. Econometric analysis is carried out using panel data
at the municipality level with economic factors and attitudes as explanatory variables, which are derived from a simple dynamic
harvesting model. A log-normal model is used for the regression analysis, and the results indicate significant impacts on
occurrences of waters with signal crayfish of changes in both economic and attitude variables. Variables reflecting environmental
and recreational preferences have unexpected signs, where the former variable has a positive and the latter a negative impact
on occurrences of waters with signal crayfish. These effects are, however, counteracted by their respective interaction effect
with income. 相似文献
86.
Robert Kase Peter D. Hansen Birgit Fischer Werner Manz Peter Heininger Georg Reifferscheid 《Environmental science and pollution research international》2009,16(1):54-64
Background, aim, and scope The enzyme-linked receptor assay (ELRA) detects estrogenic and anti-estrogenic effects at the molecular level of receptor
binding and is a useful tool for the integrative assessment of ecotoxicological potentials caused by hormonally active agents
(HAA) and endocrine disrupting compounds (EDC). The main advantage of the ELRA is its high sample throughput and its robustness
against cytotoxicity and microbial contamination. After a methodological adaptation to salinity of the ELRA, according to
the first part of this study, which increased its salinity tolerance and sensitivity for 17-β-estradiol, the optimised ELRA
was used to investigate 13 native sediments characterised by different levels of salinity and chemical contamination. The
applicability of the ELRA for routine analysis in environmental assessment was evaluated. Salinity is often a critical factor
for bioassays in ecotoxicological sediment assessment. Therefore, salinity of the samples was additionally adjusted to different
levels to characterise its influence on elution and binding processes of receptor-binding substances.
Materials and methods The ELRA was carried out with the human estrogen receptor α (ER) in a 96-well microplate format using the experimental setup
known from the competitive immunoassay based on ligand–protein interaction. It is an important improvement that a physiologically
relevant receptor was used as a linking protein instead of an antibody. The microplates were coated with a 17-β-estradiol-BSA
conjugate, and dilution series of estradiol and of native sediment samples were added and incubated with the ER. After a washing
step, a biotinylated mouse anti-ER antibody was added to each well. Receptor binding to estradiol, agonistic and antagonistic
receptor binding, were determined by a streptavidin-POD-biotin complex with subsequent measurement of the peroxidase activity
at the wavelength of 450 nm using a commercial ELISA multiplate reader. The sediment elutriates and pore water samples of
sediments were tested in a dilution series to evaluate at which dilution step the receptor-binding potential ends. In the
elution process (see Section 2.1 to 2.2), a method was developed to adjust the salinity to the levels of the reference testings, which offers an appropriate option
to adjust the salinity in both directions. Statistical evaluation was made with a combination of the Mann–Whitney U test and the pT-method.
Results This part of the study characterised the environmental factor ‘salinity’ for prospective applications of the ELRA. Using reference
substances such as 17-β-estradiol, the ELRA showed sigmoid concentration-effect relations over a broad range from 0.05 μg/l
to 100 μg/l under physiological conditions. After methodological optimisation, both sensitivity and tolerance of the assay
against salinity could be significantly raised, and the ELRA became applicable under salinity conditions up to concentrations
of 20.5‰. The mean relative inter-test error (n = 3) was around 11% with reference substances and below 5% for single sediments elutriates in three replicates each. For
sediment testings, the pore water and different salinity-adjusted elutriates of 13 sediments were used. A clear differentiation
of the receptor-binding potential could be reached by application of the pT-method. Thereby, pT-values from one to six could
be assigned to the sediments, and the deviation caused by the different salinity conditions was one pT-value. The mean standard
deviation in the salinity adaptation procedure of the elutriates was below 5%.
Discussion Although the ELRA has already been used for assessments of wastewater, sludge and soil, its applicability for samples to different
salinity levels has not been investigated so far. Even if the ELRA is not as sensitive as the E-screen or the YES-assay, with
regard to reference substances like 17-β-estradiol, it is a very useful tool for pre-screening, because it is able to integrate
both estrogenic as well as anti-estrogenic receptor-binding effects. According to the results of sediment testing, and given
the integrative power to detect different directions of effects, the ELRA shows sufficient sensitivity and salinity tolerance
to discriminate receptor-binding potentials in environmental samples.
Conclusions The optimised ELRA assay is a fast, cost-effective, reliable and highly reproducible tool that can be used for high-throughput
screening in a microplate format in detecting both estrogenic and anti-estrogenic effects. Additionally, the ELRA is robust
against microbial contaminations, and is not susceptible towards cytotoxic interferences like the common cell-culture methods.
The general applicability and sufficient sensitivity of the ELRA was shown in freshwater environments. Marine and brackish
samples can be measured up to salinity levels of 20.5‰.
Recommendations and perspectives In view of the proven sensitivity, functionality and the fastness of the ELRA, it is recommendable to standardise the test
method. At the moment, no adequate in vitro test procedure exists which is standardised to DIN or ISO levels. The E-screen
and the yeast estrogen/androgen screens (YES/YAS) sometimes underlie strong cytotoxic effects, as reported in the first part
of this study. Further development of an ELRA assay using human androgen receptors appears to be very promising to gain information
about androgenic and anti-androgenic effects, too. This would offer a possibility to use the ELRA as a fast and reliable pre-screening
tool for the detection of endocrine potentials, thus minimising time and cost-expensive animal experiments. 相似文献
87.
Typologically identical (dwarf birch-herb-dwarf shrub-moss) open and closed larch forests growing on the same altitudinal transect have proved to differ in the structural-functional organization of lower vegetation layers. Coverage, general species composition, and species richness of the herb-dwarf shrub layer are higher in the open forest than in the closed forest. Correlations between individual species of vascular plants weaken upon transition from the open to the closed forest. Conversely, the coverage of the lichen-moss layer increases in the closed forest, which contributes to its role as a factor of selection of vascular plant species against the background of the prevailing influence of the tree layer. 相似文献
88.
The results of studies on postfire succession in larch forests of the permafrost zone are discussed. The main directions of successional processes in burned-out areas of different ages are described. It has been shown that secondary pyrogenic successions in larch forests follow the scheme of rapid regeneration without tree species replacement and the model of succession tolerance. Groups of plant species with different life strategies and indicator species characterizing different stages of the overgrowing of burned-out areas have been identified. 相似文献
89.
Species composition of fishes was studied in rivers (capture sites) inhabited by the riffle minnow. In some localities, this species proved to occupy a leading position in the ichthyofauna, being obviously dominant. In small rivers, 16 species were caught together with it, including seven species regularly occurring in catches. The relative abundance of riffle minnow showed a moderate positive correlation with that of the gudgeon (0.568) and a nonsignificant negative correlation (?0.399) with that of the bleak. It is probable that the population dynamics of riffle minnow are determined mainly by natural intraspecific mechanisms rather than by water quality, which has changed only slightly in the rivers studied. 相似文献
90.
Using Multi-Scale Sampling and Spatial Cross-Correlation to Investigate Patterns of Plant Species Richness 总被引:8,自引:0,他引:8
Land managers need better techniques to assess exoticplant invasions. We used the cross-correlationstatistic, I
YZ, to test for the presence ofspatial cross-correlation between pair-wisecombinations of soil characteristics, topographicvariables, plant species richness, and cover ofvascular plants in a 754 ha study site in RockyMountain National Park, Colorado, U.S.A. Using 25 largeplots (1000 m2) in five vegetation types, 8 of 12variables showed significant spatial cross-correlationwith at least one other variable, while 6 of 12variables showed significant spatial auto-correlation. Elevation and slope showed significant spatialcross-correlation with all variables except percentcover of native and exotic species. Percent cover ofnative species had significant spatialcross-correlations with soil variables, but not withexotic species. This was probably because of thepatchy distributions of vegetation types in the studyarea. At a finer resolution, using data from ten1 m2 subplots within each of the 1000 m2 plots, allvariables showed significant spatial auto- andcross-correlation. Large-plot sampling was moreaffected by topographic factors than speciesdistribution patterns, while with finer resolutionsampling, the opposite was true. However, thestatistically and biologically significant spatialcorrelation of native and exotic species could only bedetected with finer resolution sampling. We foundexotic plant species invading areas with high nativeplant richness and cover, and in fertile soils high innitrogen, silt, and clay. Spatial auto- andcross-correlation statistics, along with theintegration of remotely sensed data and geographicinformation systems, are powerful new tools forevaluating the patterns and distribution of native andexotic plant species in relation to landscape structure. 相似文献