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21.
氨氮测定过程中有关问题的探讨 总被引:5,自引:1,他引:5
针对纳氏比色法测定氨氮过程中存在的问题,提出了相应的解决办法。消除了混浊和泡沫干扰问题,降低了空白吸光度,提高了测定的准确度。 相似文献
22.
Using improved neural network model to analyze RSP,NOx and NO2 levels in urban air in Mong Kok,Hong Kong 总被引:4,自引:0,他引:4
As the health impact of air pollutants existing in ambient addresses much attention in recent years, forecasting of airpollutant parameters becomes an important and popular topic inenvironmental science. Airborne pollution is a serious, and willbe a major problem in Hong Kong within the next few years. InHong Kong, Respirable Suspended Particulate (RSP) and NitrogenOxides NOx and NO2 are major air pollutants due to thedominant diesel fuel usage by public transportation and heavyvehicles. Hence, the investigation and prediction of the influence and the tendency of these pollutants are ofsignificance to public and the city image. The multi-layerperceptron (MLP) neural network is regarded as a reliable andcost-effective method to achieve such tasks. The works presentedhere involve developing an improved neural network model, whichcombines the principal component analysis (PCA) technique and theradial basis function (RBF) network, and forecasting thepollutant levels and tendencies based in the recorded data. Inthe study, the PCA is firstly used to reduce and orthogonalizethe original input variables (data), these treated variables arethen used as new input vectors in RBF neural network modelestablished for forecasting the pollutant tendencies. Comparingwith the general neural network models, the proposed modelpossesses simpler network architecture, faster training speed,and more satisfactory predicting performance. This improvedmodel is evaluated by using hourly time series of RSP, NOx and NO2 concentrations collected at Mong Kok Roadside Gaseous Monitory Station in Hong Kong during the year 2000. By comparing the predicted RSP, NOx and NO2 concentrationswith the actual data of these pollutants recorded at the monitorystation, the effectiveness of the proposed model has been proven.Therefore, in authors' opinion, the model presented in the paper is a potential tool in forecasting air quality parameters and hasadvantages over the traditional neural network methods. 相似文献
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A technique was developed to measure the total gaseous phosphorus content in biogas. The amount of air needed for a neutral to oxidising flame was mixed with the biogas. The gas mixture was burnt in a closed quartz burner and the combustion gasses were bubbled through a nitric acid solution. The phosphate content in the bubbling liquid was determined with sector field ICP-MS. The technique was validated in the lab with phosphine. Afterwards the set-up was installed on a landfill. The total gaseous phosphorus content in the landfill gas, measured with the combustive technique, ranged from 1.65 to 4.44 g P/m3. At the same time the phosphine concentration in the landfill gas was determined gas chromatographically (GC). The phosphine (PH3) content measured with GC ranged from 7.6 to 16.7 g PH3-P/m3. Since the phosphine-P content (GC) was consistently higher than the total gaseous phosphorus content (burner/ICP-MS), the hypothesised presence of highly toxic gaseous phosphorus compounds other than phosphine could not be demonstrated. 相似文献
26.
Kimpo metropolitan landfill has received various kinds of wastessince January 1992. The leachate level was measured to be 10.3 m in May 1995 and the level increased to 12.2 m in August 1996. Therefore, to prove the reason for the increasing leachate level, we calibrated hydraulic conductivity of each waste andintermediate layer using the HELP (Hydrologic Evaluation ofLandfill Performance) model. The leachate generation data measured from February 1993 to October 1995 was used in the model calibration. As a result of a model calibration, we obtained anaverage infiltration ratio and used this in analysis of the total water balance to predict elevation of leachate level. Main causes of the elevation of the leachate level were the high water content of the waste and the degradation of the leachate-drainage system caused by the subsidence of a naturalbarrier layer. 相似文献
27.
The article describes the use of Scots pine bark to identifynitrogen sources in eastern Germany, as well as background areas in Russia and Bulgaria, by using natural isotope ratios of total nitrogen (Nt) and individual N compoundssuch as ammonium (NH4
+), nitrate (NO3
-)and amid nitrogen (amide-N). The samples collected were analysed using an elemental analyser in connection with a gas isotope mass spectrometer (EA-IRMS). Natural 15N abundances in pine bark from impact areas suggest that the ammonium accumulated on the surface of the bark is releasedfrom livestock management. Bark of Scots pines growing near agricultural land had highly depleted 15Nt values (between –8 and –12), while bark from background areas (unpolluted areas) displayed slightly negative 15Nt values (mean 15Nt = –3.8). It is assumed that part of the N adsorbed on the bark surface is mainly derived from ammonia(mean 15Nt = –40.3) escaping from livestock housing and during the application of manure. This assumption is confirmed by experiments under controlled conditions in which manure samples were spread on soil. In addition, temporal and spatial variations of 15Nt abundances in pine bark from various locations in eastern Germany as wellas pine stands in Nature Park Dübener Heath are discussed. 相似文献
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During the summers of 1991–1994, the Environmental Monitoringand Assessment Program (EMAP) sampled 344 lakes throughout thenortheastern United States using a proportional stratified sampling design based on lake size. Approximately one-quarter ofthe 344 lakes were sampled each year (4 years) for totalphosphorus to determine the proportion (and associated95% confidence intervals) of the northeast lake population 1ha (11,076 ± 1,699 lakes) that was in oligotrophic,mesotrophic, eutrophic, or heupereutropic (4 classes) conditionaccording to the total phosphorus criteria of the North AmericaLake Manegement Society. Estimates for the second, third, andfourth yr were developed as cumulative of the previous yrsamples and the current yr samples for the northeast as a wholeand for each of its three ecoregions (4 regions). New confidence intervals were computed for each cumulative yrcondition estimate. This produced a total (4 years × 4classes × 4 regions) of 64 cumulative yr tropic conditionestimates. Confidence intervals for 21% of these estimates didnot shorten with increased sample size. This phenomena raisedquestions about the accuracy of estimates based on cumulativesampling procedures. We explain why and how the phenomenon comesabout with both straight random and proportional randomsampling. Further, we present an example of the effects thisphenomenon has on lake tropic state condition estimates in thenortheastern United States. 相似文献
30.
对色泽较深,含杂质量较高的废水加硅油I以抑制测定中蒸馏产生的泡沫.结果表明,在250ml水样中加硅油IO.10~1.25ml,即可收到理想效果.硅油I性质稳定,不随水蒸汽蒸出,对测定无干扰. 相似文献