长期施肥对旱塬麦田土壤大团聚体有机碳组分及冬小麦产量的影响

大团聚体是土壤有机碳固存的主要场所,对土壤肥力提升具有重要意义. 为揭示长期不同施肥措施下大团聚体有机碳的固持机制及产量效应,依托8 a定位试验,设不施肥（CK）、农户施肥（NP）、测控施肥（NPK）、测控+有机肥配施（NPKM）以及测控+生物有机肥配施（NPKB）这5个处理,采用“团聚体-密度”联合分组法,分析了黄土旱塬麦田土壤大团聚体中粗颗粒有机碳（cPOC）、细颗粒有机碳（fPOC）、微团聚体颗粒有机碳（iPOC）、游离态粉+黏颗粒有机碳（s+c_f）和微团聚体粉+黏颗粒有机碳（s+c_m）的变化特征及其与土壤碳投入和产量形成之间的关系. 结果表明,长期有机无机配施（NPKM和NPKB）较单施化肥（NP和NPK）显著提高了大团聚体中有机碳（SOC）含量,提升幅度高于对应处理土壤SOC提升幅度. 长期施肥有提高大团聚中cPOC、fPOC和iPOC含量,降低s+c_f和s+c_m含量趋势,且长期有机无机配施显著提高了大团聚中cPOC、fPOC和iPOC储量占比,显著降低了s+c_f储量占比,而长期单施化肥仅显著提升了大团聚中cPOC储量占比. 相关分析表明,小麦籽粒产量与有机碳组分（cPOC和iPOC）含量、土壤总有机碳含量、 >0.25 mm大团聚体有机碳含量以及土壤有机碳投入量存在极显著正相关性,相关系数为0.645~0.883. 综合来看,黄土旱塬麦区长期施肥尤其是有机无机配施,通过增加土壤碳投入量促进了游离态粉+黏颗粒有机碳（s+c_f）向其它形态有机碳的转化,进而整体提升大团聚体有机碳含量,为作物增产创造了良好土壤环境.     

基于PMF和源示踪物比例法的大气羰基化合物来源解析:以南京市观测为例

大气羰基化合物在对流层大气化学中发挥着重要作用,其受到直接排放和二次生成的共同影响,来源研究面临挑战.本研究基于2017年3月在南京市开展的羰基化合物观测,分别利用源示踪物比例法(STR)和正交矩阵因子模型(PMF)对羰基化合物进行来源解析,并将二者结果进行比较,以探讨导致来源解析不确定性的因素.本研究共检测出11种羰...     

Effect of activated sludge treatment on the formation of Nnitrosamines under different chloramination conditions

Municipal wastewater discharge is considered as one of the main sources of N-nitrosamine precursors which can impact the qualities of downstream source waters and reclaimed wastewaters for potable reuse. NNitrosamine precursors can be removed to various degrees during biological wastewater treatment (e.g., the activated sludge (AS) process). So far, little is known about the impact of the AS process on N-nitrosamine formation under practical disinfection condition (e.g., uniform formation condition (UFC)). In this study, N-nitrosamine UFC from selected model compounds, sewage components (i.e., blackwaters and greywaters) and sewage samples were comprehensively investigated during batch AS treatment tests. NNitrosodimethylamine (NDMA) formation from the tested precursor compounds (i.e., trimethylamine (TMA) and sumatriptan (SMTR)) under UFC chloramination decreased mostly after 6 or 24 hr treatment with different types of AS (i.e., domestic rural AS, domestic urban AS, and textile AS), and the reductions in NDMA UFC were comparable to their NDMA formation potential (FP) reductions. In urine and feces blackwaters, NDMA UFC increased after 6 or 24 hr treatment with the domestic (i.e., rural and urban) AS, while NDMA FP decreased substantially. The increases in NDMA UFC after AS treatment was presumably attributed to the removal of bulk organic matters (e.g., dissolved organic carbon (DOC)) which favored NDMA formation under UFC. On the other hand, in laundry greywaters having relatively abundant DOC, N-nitrosamine UFC was less affected by DOC removal before or after AS treatment, but decreased to similar degrees with N-nitrosamine FP. In sewage samples collected from wastewater treatment plants, N-nitrosamines UFC tended to increase or remain constant during AS treatment, despite the decreases in their FPs. These results suggest that biological wastewater treatment (e.g., the AS process) may not effectively reduce N-nitrosamine formation (e.g., measured under UFC) partially because the concurrent removal of bulk organic matters (e.g., DOC) favored N-nitrosamine formation in s econdary effluents.     

输送、滞留叠加海上回流的长时间沙尘天气影响判断及贡献分析

于2019年10月15日～11月7日对上海大气中颗粒物的质量浓度和PM2.5的化学组分进行了在线连续观测,期间,华东地区遭遇了一次大范围的沙尘过程.根据相关规定,结合沙尘示踪组分和WRF-CMAQ 数值模拟,将观测过程分为4 个阶段:沙尘前、沙尘I(输送和滞留过程)、沙尘Ⅱ(海上回流和清除过程)和沙尘后.基于相关规定、...