固相微萃取-毛细管气相色谱法快速同步分析水中有机氯及有机磷农药

固相微萃取是一种快速、简便,集萃取浓缩进样于一体的样品前处理技术,具有分析时间短、灵敏度高、无需有机溶剂的优点.用固相微萃取富集水中8种有机氯及7种有机磷农药,毛细管气相色谱ECD检测器分离分析,整个分析过程只需26min,检出限可达0.002～1μg/L,已用于地表水中有机氯及有机磷农药含量的测定.     

膜、柱串联固相萃取-高效液相色谱法测定水中多环芳烃(PAHs)的研究

建立了用膜-柱串联固相萃取(SPE)技术,甲醇和水作为流动相进行梯度洗脱,紫外和荧光检测器串联的高效液相色谱法(HPLC)分析水中EPA优先监控的16种PAHs的方法.     

微波高压络合消解石墨炉原子吸收分光光度法测定环境空气中锑

用有机滤膜采集空气中颗粒物样品,用微波高压络合消解后制成样品溶液。用石墨炉原子吸收分光光度法可确定样品溶液中锑的浓度。该方法具有对有机滤膜和样品消解完全,省时,无损失,灵敏度高,准确度、精密度好等特点。     

Biotreatability and kinetics of UASB reactor to mixtures of chlorophenol pollutants

In most natural ecosystems heterotrophic microorganisms encountercomplex mixtures of carbon sources, each of which is present at aconcentration of few micrograms per litre. This study examined the biotreatability and kinetics of an upflow anaerobic sludge blanket (UASB) reactor to complex mixtures of chlorophenols encountered in environmental conditions using on-line and off-line experimental studies. Results indicate that (1) steady-state concentration was quite lower (98.3 mg L^-1) with complex mixture of chlorophenols than steady-state concentration achieved when only 2.4 dichlorophenol (124 mg L^-1) was studied alone on the same reactor; (2) that toxiceffects of chlorophenols increase with increasing concentrationsof toxicant. (Onset of the inhibitory effect occurred at a lowerconcentration in multi-substrate than in single substrate utilization); (3) addition of alternative utilizable substrate can mitigate toxic effects and enhance degradation; (4) the relative concentration of substrate was critical in determiningutilization patterns. HPLC analysis of off-line experimental samples resulted in a steady-state treatment efficiency of68% for COD, 36% for 2-hlorophenol, 40.5% for 4-chlorophenol, 70.7% for 2,4-dichlorophenol, 53.2% for 2,4,6-trichlorophenol and 42% for pentachlorophenol in presence of glucose. Kinetic constant in terms of V _max and K _s were determined. K _s for the five chlorophenols ranged between 0.016 and 0.117 kg m^-3 day^-1 while V _max ranged between 0.056 and 0.244 kg m^-3 day^-1.     

Biodegradability: An assessment of commercial polymers according to the Canadian method for anaerobic conditions

The degradation of several biodegradable polymers was measured as a result of exposure to an anaerobic medium. The polymers investigated included materials based upon polylactic acid, polylactone, and poly(hydroxy butyrate/valerate) as well as those incorporating starch-based materials. The degradation was monitored by methane and carbon dioxide evolution. In addition, the physical and chemical changes were noted as a result of exposure. These measurements included changes in mass, dimension, and molecular weight. FTIR, UV-vis, proton, and¹³C NMR spectra were also recorded prior to and after exposure. The results clearly indicated that several biological and chemical degradation processes were occurring with the biodegradable polymers studied.Paper presented at the Bio/Environmentally Degradable Polymer Society—Second National Meeting, August 19–21, 1993, Chicago, Illinois.Issued as NRCC No. 37549.     

石灰石-石灰乳二段中和法处理矿山酸性废水

分析了处理含重金属离子矿山酸性废水的处理工艺。通过实例说明石灰石-石灰乳二段中和法与传统的石灰乳中和工艺相比，有较大的优越性，可以降低处理成本和减少沉渣的产生量。     

生活垃圾生物处理的研究与展望

综述了国内外生活垃圾生物处理的研究进展和目前生活垃圾微生物研究水平，以及生活垃圾处理发展趋势与新动向，在此基础上提出了生活垃圾处理的建议和展望。     

厌氧处理原理及其在低浓度有机废水处理中的应用现状

介绍了厌氧处理原理，并对厌氧处理低浓度废水的最新进展进行了较全面的综速，高效厌氧反应器及组合工艺为这一发展提供了可能。高效厌氧反应器中以膨胀颗粒污泥床（ECSB）反应器为首选。其结构及远行特性决定了它在处理低浓度虚水方面具有潜在的优势，但中国EC,SB的应用仅处于研究阶段，尚未有生产规模的EGSB；组合工艺对低浓度废水中污染物去除率极高，出水中COD、NH3-N、TP和SS浓度均可达到较高的排放标准，对生活污水、稀释后的工业有机废水等低浓度有机废水处理具有广阔的前景。     

反静电场处理厌氧污泥的影响因素分析

在电场和电解副效应的共同作用下，选定0．5mA、1．0mA、1．5mA和1．95mA四种电流强度作为不同的运行条件，处理时间24h，分别测定反应开始和结束时厌氧污泥上清液COD、NH4^＋-N和VSS，其变化率随电流强度呈抛物线型变化。用反静电处理厌氧污泥时，电场对污泥参数的影响存在着最佳的工作电流强度，在本试验条件下，反静电处理厌氧污泥的最佳工作电流强度为1．5mA。反静电场可提高微生物的活性，使COD与NH4^＋-N得到一定程度的降解，同时，污泥的性质影响反静电场处理污泥的效果。     

水解酸化─厌氧─好氧─混凝─吸附工艺处理洁霉素生产丁提高浓度有机废水

采用水解酸化厌氧好氧混凝吸附工艺处理洁霉素生产丁提高浓度有机废水，工程实践表明，ＣＯＤＣｒ和ＢＯＤ５去除率在９９％以上，所排废水各项指标达到国家排放标准。