聚氨酯泡沫材料阴燃发展过程的特性分析

分析对比了相同加热条件下的聚氨酯泡沫材料在有氧和无氧气氛下的升温过程,并对不同加热条件下的聚氨酯泡沫材料的阴燃传播速度进行研究.结果表明:沿着反应进行的方向,分离点的温度越来越低,不同热流条件下的温度分离曲线斜率在实验稳定发展段的变化规律表现得很相似,并在分离点出现后,有氧气氛中的该位置温度在短时间内急剧上升;在阴燃不稳定传播阶段时,热解前锋的速度小于氧化前锋的速度,在稳定传播阶段时,热解前锋速度与氧化前锋速度近乎相等.     

成都市城镇体系空间结构研究

成都市位于四川盆地的成都平原上,是我国为数不多的较典型的同心圆城市之一。目前,成都市的城市发展已经进入了工业化与城市化中期阶段。从空间结构理论入手,对成都市城镇体系的空间结构进行分析,结果显示：行政辖区内的14个郊县（区）呈现具有黄金分割特征的五边形结构,并可划分为5个五边形。它们分别是：龙泉驿-新都-郫县-温江-双流5个近郊县、区构成的卫星城镇环;大邑-崇州-邛崃-蒲江-新津5个郊县构成的远郊城镇环;以都江堰为共同顶点,由近郊卫星城镇与远郊县、区构成的2个五边形城镇环（郫县-新都-青白江-彭州-都江堰、郫县-温江-崇州-大邑-都江堰）,以及成都主城区东、南部尚待形成的五边形城镇体系结构。在理论上论证了成都市向东、向南发展的客观性、必然性。     

长江经济带城市对外服务能力时空演变分析

基于城市流强度模型测算2000年以来长江经济带126个地级以上城市在全国范围内的对外服务能力,进而采用改良锡尔系数、马尔可夫链和ESDA方法对城市对外服务能力的时空演变特征进行探讨。结果表明:研究时段内长江经济带各市城市流强度都有显著提升,但区域间的非均衡现象明显,城市对外服务能力呈现出由东部向西部的梯度递减;省内差异对城市对外服务能力的差异贡献率最高,是空间尺度差异的主要来源;对外服务能力存在明显的俱乐部趋同现象和空间自相关性,对外服务能力相似的区域聚集分布,东、中、西部分别形成长三角、武汉-长沙、成渝等对外服务区域中心;时空演变表现出阶段性特征,经历由极化向均衡的转变。最后指出多中心发展和寻找新增长点应成为长江经济带城市对外服务能力提升的方向。     

基于生态足迹的武汉城市圈生态承载力评价和生态补偿研究

在推进新型城镇化和生态建设的背景下,客观定量评价区域生态环境状态,是当前我国生态建设重要而紧迫的任务之一。高密度的人类活动会对自然生态系统产生超负荷的压力,通过生态承载力的分析能够定量测度这种状况,为区域可持续发展提供借鉴意义。基于生态足迹模型,计算了2008年和2013年武汉城市圈各县域单元的生态足迹/承载力,并进行了时空变化分析。研究发现武汉城市圈各县域单元的生态足迹和生态承载力在空间上存在显著的差异性,生态足迹逐年增加,生态承载力的变化相对较小,出现两级分化的现象。根据生态足迹/承载力进行跨区县生态补偿测算,得到2008年和2013年武汉城市圈48个县域的转移支付情况,表明如果运用财政转移支付的手段,整个区域能够达到生态系统供给和需求动态平衡的目标,缓解武汉城市圈的生态压力,实现武汉城市圈的可持续发展。     

武汉城市圈空间结构演化及影响研究

武汉城市圈是我国资源节约型、环境友好型社会建设的重点示范区,是中部崛起战略实施的重要支点。但就现阶段的发展情况来看,武汉城市圈在空间结构方面存在一些问题,制约了城市圈的总体发展。采用两方面的方法对武汉城市圈的空间结构展开研究。一方面,利用数理分析确定武汉城市圈的城市职能等级体系;另一方面,利用针对历史建成区的图面分析和方格网分析确定城市圈空间结构的演化历程。结合两方面的研究结论,将武汉城市圈的空间结构确定为单核模式,即由一个较大的核心城市和若干个组团城市结合而成的空间结构模式。单核模式有利于培育强有力的核心城市,突出核心城市的辐射带动作用,但不利于组团城市的扩张和城市圈的总体长远发展。在此基础上,提出了优化武汉城市圈空间结构的初步设想,包括联合一些组团城市建设发展中心,突出一些组团城市特色功能等     

基于ARCGIS的长株潭城市群核心区环境容量评价

区域环境容量评价与分析是区域合理开发和布局的重要依据。在ARCGIS技术的支持下,首先对长株潭城市群核心区大气、水和土壤环境容量分别进行评价与分析,形成等级图,然后,进行各因素空间叠加,经综合分析与评价,将核心区划分为5个区域：优良区、合理区、饱和区、超饱和区、过度饱和区,并且还提出了相应的建议与对策。其主旨是为促进该区域空间科学开发与布局、生态环境的合理保护,对规范长株潭城市群“两型社会”建设理性发展具有非常重要的意义,并提供参考依据     

基于DEA的城市群环境投入产出效率测度研究

随着产业集群、人口城镇化的发展,我国城市群逐渐形成,城市群的环境污染治理问题也成为影响城镇居民生产生活的重要社会问题.目前,城市群的资金投入与环境污染治理的效率,投入产出中的环境变量对环境污染治理的影响,城市群环境污染治理的效果等问题是我们亟需认知的.基于这些思考,以我国十大城市群环境污染与资金投入的统计数据为实例,采用三阶段数据包络分析(DEA)模型,运用DEA模型的计算软件,基于传统的DEA模型、相似SFA模型和调整后的DEA模型三个步骤进行了探讨.从投入产出的角度对我国十大城市群环境污染治理的技术效率、纯技术效率和规模效率进行了实证分析.结果表明:十大城市群在环境投资与污染治理效率方面存在差异性,以京津冀、长三角、珠三角和山东半岛为代表的东部沿海城市群在投入产出效率上高于其他几个城市群,同时也显示我国十大城市群在环境污染治理效率上还有一定的提升空间.最后,提出了十大城市群在环境投资与污染治理方面的思考.     

Linking Nitrogen Export to Landscape Heterogeneity: The Role of Infrastructure and Storm Flows in a Mediterranean Urban System

Urban ecosystems are often sources of nonpoint source (NPS) nitrogen (N) pollution to aquatic ecosystems. However, N export from urban watersheds is highly variable. Examples of densely urbanized watersheds are not well studied, and these may have comparatively low export rates. Commonly used metrics of landscape heterogeneity may obscure our ability to discern relationships among landscape characteristics that can explain these lower export rates. We expected that differences not often captured by these metrics in the relative cover of vegetation, structures, and impervious surfaces would better explain observed variation in N export. We examined these relationships during storms in residential watersheds. Contrary to expectations, land cover did not directly predict variation in N or water export. Instead, N export was strongly linked to drainage infrastructure density. Our research highlights the role of fine‐scaled landscape attributes, mainly infrastructure, in explaining patterns of N export from densely urbanized watersheds. Changes to hydrologic flow paths by infrastructure explained more variation in N export than land cover. Our findings support further development of landscape ecological models of urban N export that focus on hydrologic modification by infrastructure rather than traditional landscape measures such as land use, as indicators for evaluating patterns of NPS nitrogen pollution in densely urbanized watersheds.     

Coupling of the Water Cycle with Patterns of Urban Growth in the Baltimore Metropolitan Region,United States

Regional municipal water plans typically do not recognize complex coupling patterns or that increased withdrawals in one location can result in changes in water availability in others. We investigated the interaction between urban growth and water availability in the Baltimore metropolitan region where urban growth has occurred beyond the reaches of municipal water systems into areas that rely on wells in low‐productivity Piedmont aquifers. We used the urban growth model SLEUTH and the hydrologic model ParFlow.CLM to evaluate this interaction with urban growth scenarios in 2007 and 2030. We found decreasing groundwater availability outside of the municipal water service area. Within the municipal service area we found zones of increasing storage resulting from increased urban growth, where reduced vegetation cover dominated the effect of urbanization on the hydrologic cycle. We also found areas of decreasing storage, where expanding impervious surfaces played a larger role. Although the magnitude of urban growth and change in water availability for the simulation period were generally small, there was considerable spatial heterogeneity of changes in subsurface storage. This suggests that there are locally concentrated areas of groundwater sensitivity to urban growth where water shortages could occur or where drying up of headwater streams would be more likely. The simulation approach presented here could be used to identify early warning indicators of future risk.     

Mitigating urban sprawl effects: a collaborative tree and shade intervention in Phoenix,Arizona, USA

Communities in Phoenix are confronted with numerous challenges that adversely affect human health and safety, with disproportionate impacts on low-income communities. While some challenges are being addressed at the city level, new alliances at the neighbourhood level are initiating community development programmes and projects. This article reports on an intervention study carried out in collaboration with community representatives, city staff, and non-profit organisations to mitigate adverse effects of urban sprawl in the Sky Harbour Neighbourhood in Phoenix. Participatory research was conducted to design and test a tree and shade intervention. Challenges associated with navigating community desires and broader principles of sustainable development are discussed. The study offers a replicable and adaptable intervention research design aimed at empowering communities to meet urban challenges.