Sulfur Metabolism in Polluted Sphagnum Peat Bogs: A Combined 34S–35S–210Pb Study

The size and isotopic behavior of sulfur pools in²¹⁰Pb-dated peat cores were investigated to obtain aninsight into retention mechanisms of pollutant S in twomountain-top peatlands of the Northern Czech Republic, CentralEurope. The bogs were situated 40 km apart in an area whichbetween the years 1985 and 1995 received as much as 130 kg Sha^-1 yr^-1 from the atmosphere. Vertical peataccretion was faster at Pod Jelení horou (JH) than atVelký moál (VM). Organic carbon-bonded S was themost abundant sulfur pool, constituting 77 and 65 wt. % at JHand VM, respectively. At JH both the S concentration maximumand the highest annual S deposition rate were displaceddownward by more than 20 years (from 1987 to the 1960s)indicating that the buried S is vertically mobile. At VM the Sconcentration was the highest in the topmost 2-cm section eventhough atmospheric S deposition peaked in 1987. Differentmechanisms of S isotope redistribution prevailed in thetopmost peat layers at JH, where a negative ³⁴Sshift occurred, and at VM, where a positive ³⁴Sshift occurred. Bacterial sulfate reduction was responsiblefor the negative ³⁴S shift at JH. One possibleexplanation of the positive ³⁴S shift at VM isrelease of ³²S-enriched products of mineralization duringpeat diagenesis. There was a strong positive correlationbetween the abundance of total and pyrite S along the profiles.The presence of pyrite S at VM (526 ± 60 ppm) suggestedthat even at VM bacterial sulfate reduction occurred. Ananaerobic incubation of JH peat indicated sulfate reductionrate of 600 nmol g^-1 day^-1. The turnover times forinorganic S pools were shorter than for the organic S pools.Cumulative S contents in the Czech peat bogs were found to besignificantly lower than in similar sites in the NortheasternU.S., even though the atmospheric S inputs were more thanthree times higher at the Czech sites. Possible causes of suchdiscrepancy are discussed.     

论城市创新的生态思维--推动城市可持续发展的新思维

城市化是人类生产和生活方式转型的必然结果,由于城市建设过程中依照的是传统思维模式,导致各大城市均不同程度存在一定的城市病。因此要加强可持续发展生态思维的观念,以期推动我国城市生态化与可持续城市建设工作的开展。     

公众参与市容环境规划与管理的方法设计--以南京市的实践为例

市容环境是与公众生活联系最为紧密的领域,也是公众参与最容易进行的领域。南京的城市建设要实现“经济发达、环境优美、融古都特色和现代文明于一体的现代化江滨城市”的目标,公众参与市容环境的规划与管理是关键内容之一。论文以“南京市市容环境卫生发展规划”项目工作为基础,分析和阐述公众参与的内涵,提出公众参与市容环境的五大步骤,并针对南京市容环境方面的具体案例,设计出符合南京特色的公众参与市容环境规划与管理的方法框架模型,包括决策模式、制度框架的共管体系。     

Numerical Prediction of Dispersion Characteristics in an Urban Area Based on Grid Refinement and Various Turbulence Models

A detailed simulation of the Goettinger Strasse pollutantdispersion problem is performed using the CFD code CFX-TASCflow for different wind directions. Two turbulencemodels, the k- and the RSM are adopted on three gridrefinement levels. Besides the typical reference gridimplemented by the TRAPOS group, two different gridresolutions are introduced. The first refinement is in thewhole street canyon region on the x-y level, while thesecond one is local in all three directions. Validation ofall involved computational schemes is performed based onrelative available experimental data. The computed velocityfields and concentration contours imply that the typicalreference grid is a suitable choice for the velocityfields, while local grid refinement in all three directionsin a small region containing the receptor is required toupgrade the pollutant concentration results with modestadditional computational effort. Finally the RSM modelresulted in smaller concentration levels. The k-model compared to the RSM seems a more appropriate choiceto solve this particular problem.     

Atmospheric Levels of Nitrogen Oxides at a Greek Oil Refinery Compared with the Urban Measurements in Athens

Oil refining is among the industrial activities that emit considerable amounts of air pollutants into the atmosphere. Nitrogen oxides are important air pollutants that are emitted by oil refineries as products of combustion processes. The ambient air concentrations of nitrogen oxide (NO) and nitrogen dioxide (NO₂) were monitored continuously at a site close to an oil refinery, near the city of Corinth in Greece, during autumn 1997 together with the main meteorological parameters. The contribution of the oil refinery to the measured atmospheric levels of nitrogen oxides was estimated. The ambient air concentration of nitrogen oxides in the area surrounding the oil refinery were generally lower than the ambient air concentrations in the urban area of Athens in Greece, and the NO₂ levels were always below the existing air quality standards. The influence of the refinery emitted NO_x in the photochemical production of ozone seems to be more important in terms of human and vegetation exposure given the high ozone backgrounds measured in the area.     

Lowest Effect Levels of Lead and Mercury on Decomposition of Mor Layer Samples in a Long-Term Experiment

Indications of possible negative effects of lead (Pb) and mercury(Hg) on microbial respiration in Southern Swedish forest humus layers led to experiments on dose-response relationships by additions of metal salts in the laboratory. Respiration rates andweight loss due to decomposition of organic material were measured. For relevance to field situations metal doses were low,the time span was long, 550 days including freeze storage, and microbial activity was kept up by plant litter additions. We looked for effects of Pb and Hg at levels moderately elevated above the Southern Swedish reference, as well as combined effectsof Pb + Hg. A reduction in respiration and decomposition of10% was found at about 225–245 g g^-1 of total Pb, i.e. ata Pb level elevated 3.5 times. Although small effects of Hg werefound even at the lowest dose level, 10% inhibition of microbialactivity appeared temporarily at about 2–3 g g^-1 of total Hg, i. e. at 6–8 times the reference level. There were nolong-term additive effects of Pb and Hg on decomposition. Type of anion had a strong influence on the test, chlorides of Pbbeing more toxic than nitrates. Long-term monitoring and maintenance of microbial activity during the experiment were prerequisites for the occurrence of effects at low metal levels.     

Vertical Distribution of Atmospheric Pollution Lead in Swedish Boreal Forest Soils

In order to understand the fate of anthropogenic lead (Pb)pollution in boreal forest soils, and to predict future trends, it is important to know where in the soil the pollution Pb is accumulated and how large the pollution and natural Pb inventories are in different soil horizons. We combined stable Pb isotope (²⁰⁶Pb/²⁰⁷Pb ratios) and concentration analyses to study Pb in podzol profiles and mor samples from old-growth forest stands at seven sites distributed from southern to northern Sweden. Additional samples were taken from managed forests, and from an agricultural field, to give some idea of the effects of land-use. Pb concentrations are typically 60–100 g g^-1 dry mass in the mor layer in southern Sweden and about 30 g g^-1 in northern Sweden. Pb isotope analyses show that virtually all of this Pb is pollution Pb. The isotope composition also shows that pollution Pb has penetrated downwards between 20–60 cm in the forest soils. The total pollution Pb inventories vary between 0.7–3.0 g m^-2 ground surface, with larger inventories in southern compared to northern Sweden. Although the highest Pb concentrations occur in the mor layer, the largest inventories of pollution Pb are found in the Bs-horizon. The limited investigation of Pb distribution and inventories in soils from managed forests did not point to any major difference compared to the old-growth forests. The agricultural field revealed, however, a completely deviating Pb profile with all pollution Pb evenly distributed in the 20 cm thick top-soil.     

Conservation strategies for effective land management of protected areas using an erosion prediction information system (EPIS)

This research demonstrates the predictive modeling capabilities of a geographic information system (GIS)-based soil erosion potential model to assess the effects of implementing land use change within a tropical watershed. The Revised Universal Soil Loss Equation (RUSLE) was integrated with a GIS to produce an Erosion Prediction Information System (EPIS) and modified to reflect conditions found in the mountainous tropics. Research was conducted in the Zenzontia subcatchment of the Río Ayuquíla, located within the Sierra de Manantlán Biosphere Reserve (SMBR), México. Expanding agricultural activities within this area will accentuate the already high rate of soil erosion and resultant sediment loading occurring in the Río Ayuquíla. Two land-use change scenarios are modeled with the EPIS: (1) implementation of soil conservation practices in erosion prone locations; and (2) selection of sites for agricultural expansion which minimize potential soil loss. Confronted with limited financial resources and the necessity for expedient action, managers of the SMBR can draw upon the predictive capacity of the EPIS to facilitate rapid and informed land-use planning decisions.     

城市灾害学研究及科学建议

无论从哪个角度来看,２０世纪都是历史发展最快,发生事件最多的一个世纪。城市由于是对时代脉搏最敏感空间地域,所以,时时处处反映出时代的特点。城市灾害作为现代及未来灾害的集中反映,越来越成为严峻的话题。无论承认与否,城市化发展进程中将始终伴随着灾情。笔者认为,惟有直面灾情,全面关注城市灾害及其在中国减灾中的地位与作用,才有希望走向未来,并创造城市安全“时空”。