SMA绞线-叠层橡胶复合支座结构的动力反应

为了改进现有普通叠层橡胶支座的隔震效果，利用形状记忆合金的超弹性，将SMA绞线加入叠层橡胶支座中，形成了SMA绞线-叠层橡胶复合支座。分析了SMA绞线-叠层橡胶复合支座的工作原理，建立了其力学分析模型，并进行了应用SMA绞线-叠层橡胶复合支座的结构动力反应分析，导出了加速度衰减比尺。与位移放大比凡的理论形式，并利用具体算例，研究了频率比和阻尼比对结构隔震效果的影响。结果表明，频率比越大，阻尼比越小，隔震效果越好。     

臭氧氧化-化学吸收净化橡胶恶臭废气的中试研究

以再生胶炼胶车间一生产线产生的恶臭废气为研究对象,通过中试试验考察了化学吸收、臭氧氧化及两者组合工艺对炼胶恶臭废气的净化效果,结果表明:恶臭废气经臭氧氧化预处理后,再经碱液吸收净化,其浓度低于国家排放标准;在臭氧(浓度为19×10-6)氧化时间为1～2 s、碱溶液(10%浓度)吸收时间为2～3 s的试验条件下,净化率达99%;净化系统装机功率小于2 kW/1 000 m3,运行成本小于3.7元/1 000 m3,表现出良好的工程应用前景。     

双台子河橡胶坝对支流绕阳河纳潮的影响

基于Mike11 HD和AD模块建立双台子河口区感潮河段水动力-水质耦合模型,利用实测资料对水动力、水质模型参数进行了率定和验证。利用所建模型,以夏灌期为例分析了在两种水文条件下橡胶坝对支流绕阳河纳潮的影响。结果表明,在两种水文情景下,建橡胶坝后纳潮量分别增加18.3%和16.9%,最大流量分别增加了32.7%和31.2%。盐度分析表明修建橡胶坝对绕阳河纳潮盐度变化影响不大,可满足苇田灌溉对盐度的要求。研究结果可为盘锦双台子河口苇田科学灌溉、促进增产提供技术支持。     

Explosibility and thermal decomposition behavior of nitrile rubber dust in industrial processes

The formation of nitrile rubber (NBR) dust clouds during processing can lead to a potential dust explosion under certain conditions. However, the potential explosion hazard posed by NBR dust is usually overlooked by enterprises. In this paper, the explosive properties of NBR dust are investigated using a Hartmann tube, a G-G furnace, and a 20 L explosion chamber. The results showed that NBR dust could cause explosions severe enough to be classified as St-1. In addition, the thermal decomposition behavior of NBR dust under combustion conditions was investigated using a combination of thermogravimetric analysis coupled with Fourier transform infrared spectroscopy (TGA-FTIR). The results indicated that in the early stage, NBR dust mainly undergoes self-thermal decomposition to produce a large amount of combustible gas, which combines with oxygen to form a mixed gas and cause a gas-phase explosion. In addition, the participation of oxygen could lower the initial temperature of NBR dust thermal decomposition. As a result, decomposition occurred more quickly and a large amount of combustible gas was produced, thus expanding the range of dust explosions. Furthermore, these combustible gases exhibit varying degrees of toxicity, seriously affecting the life and health safety of relevant personnel. This work provides theoretical guidance for the development of safe procedures to prevent and address problems during NBR dust processing in enterprises.     

Rubber sheet strewn with TiO2 particles:Photocatalytic activity and recyclability

A new method for the preparation of rubber sheet strewn with titanium dioxide particles (TiO₂-strewn sheet) is presented. This simple and low cost method is based on the use of TiO₂ powder (Degussa P25) being strewn onto the sheet made from rubber latex (60% HA) through a steel sieve. The characteristic of the TiO₂-strewn sheet was studied by using scanning electron microscopy/energy dispersive X-ray spectrometer (SEM/EDS) and X-ray diffractometer (XRD) techniques. The photocatalytic activity of TiO₂-strewn rubber sheet was evaluated using Indigo Carmine (IC) dye as a model for organic dye pollutant in water. The results showed that the TiO₂-strewn sheet could degrade IC dye solution under UV light irradiation. The effects of pH, initial concentration, and the intensity of UV light on the photodegradation were also investigated. Kinetics of the photocatalytic degradation was of the first-order reaction. The used TiO₂-strewn sheet can be recovered and reused. The recycling uses did not require any cleaning between successive uses and no decline in the photodegradation efficiency was observed compared with freshly prepared TiO₂-strewn sheet.     

三元乙丙橡胶防水卷材热解分析

采用热重-差热联动分析仪对三元乙丙橡胶(EPDM)防水卷材进行了热解特性研究,同时分析了升温速率以及不同气氛对热解行为的影响,并采用Flynn-Wall-Ozawa多升温速率法和Coats-Redfern单升温速率法分别求解了样品在氮气气氛以及空气气氛下的动力学参数,以此作为基础数据开发室外屋面防灭火系统,对减少人员伤亡和经济损失具有重要意义。     

氟醚橡胶在不同介质下的热老化行为与机理研究

目的 对氟醚橡胶FM-2D在空气与飞马Ⅱ号润滑油中的热老化行为与机理进行研究。方法 开展氟醚橡胶高温贮存试验,在热氧、热油的介质环境下,研究氟醚橡胶的力学性能退化规律。试验后对样品的拉伸性能、压缩性能以及硬度进行检测,并且利用傅里叶红外光谱仪、扫描电子显微镜以及X射线电子能谱对试验后样品进行检测。结果 通过热老化试验,发现氟醚橡胶在200℃以下能够长期维持较好的力学性能。试验温度在200℃以上,氟醚橡胶的力学性能出现明显退化趋势,并且在热空气与热油中的老化趋势不同。在220℃的热空气老化31 d后,氟醚橡胶的拉伸强度下降27.0%,断裂伸长率增大89.8%,压缩应力松弛率为34.6%,硬度下降8.7%。在220℃的热油老化31 d后,氟醚橡胶的拉伸强度下降85.9%,断裂伸长率下降83.9%,压缩应力松弛率为-17.5%,硬度上升4.2%。结论 在热空气老化过程中,橡胶分子链受热氧影响发生断裂,使其强度下降;在热油老化过程中,油介质和高温的耦合作用使橡胶的交联网络失效,橡胶发硬变脆。     

橡胶工业废水深度处理回用的研究

采用混凝沉淀－砂滤,活性炭吸附和反渗透处理工艺,对齐鲁石橡胶厂排放的工业废水进行了深度处理后回用的实验研究。混凝沉淀－砂滤主要用于去除悬浮物质去除率约为９３％;活性炭主要去除难生物降解的可溶性有机物质对ＣＯＤ,石油类,挥发酚和色度的去除率分别为６０％,８０％,８０％和７０％;反渗透主要去除无机盐类和一些残余有机物质对ＴＤＳ和无机盐的去除率分别为９３％和８５％。     

橡胶厂污水达标排放改造

通过对橡胶厂污水处理系统各单元运行状况进行检测 ,找出系统不能达标排放的原因 ,提出了改造方案 ,并对系统进行了改造。改造后的结果表明 ,在来水处于正常的情况下 ,即CODCr<80 0mg L ,系统最终出水CODCr<10 0mg L。     

利用废旧橡胶研制管式微孔曝气器

采用废旧橡胶研制的微孔曝气器 ,制造工艺简单 ,机械强度高 ,价格低廉 ;传质效率高 ,曝气充氧性能优良 ,搅拌能力强 ;沿管长具有很好的均匀布气性 ,输气曝气合二为一 ,安装方便 ;拓展了废旧橡胶的综合利用途径 ,以废治废 ,减少了废旧橡胶对环境的污染 ,是固体废气物综合利用的环保型高科技产品。