Vapour pressures, aqueous solubility, Henry's law constants and air/water partition coefficients of 1,8-dichlorooctane and 1,8-dibromooctane

New data on the vapour pressures and aqueous solubility of 1,8-dichlorooctane and 1,8-dibromooctane are reported as a function of temperature between 20 °C and 80 °C and 1 °C and 40 °C, respectively. For the vapour pressures, a static method was used during the measurements which have an estimated uncertainty between 3% and 5%. The aqueous solubilities were determined using a dynamic saturation column method and the values are accurate to within ±10%. 1,8-Dichlorooctane is more volatile than 1,8-dibromooctane in the temperature range covered (p_sat varies from 3 to 250 Pa and from 0.53 to 62 Pa, respectively) and is also approximately three times more soluble in water (mole fraction solubilities at 25 °C of 5.95 × 10⁻⁷ and 1.92 × 10⁻⁷, respectively). A combination of the two sets of data allowed the calculation of the Henry’s law constants and the air water partition coefficients. A simple group contribution concept was used to rationalize the data obtained.     

低压下聚乙烯绝缘层导线火蔓延熔融滴落实验分析

低压导线火蔓延的研究对于飞机和航天器的防火安全具有重要意义。针对镍铬合金线芯、聚乙烯(PE)绝缘层导线火蔓延过程中的熔融滴落现象,在低压舱内开展了不同气压、不同氧气浓度的大量实验研究,获得了导线熔融滴落频率、质量和火蔓延速度,以及不同氧浓度熔融滴落的上下限。结果表明:(1)在熔融滴落过程中,由于滴落会产生向上的动量,从而使火焰在滴落后发生突然的"跳动"现象,火焰高度先增加后降低;(2)滴落上限和滴落下限随着氧浓度的增加而降低,并且可以划分为3个不同的区域:火蔓延仅存区;滴落和火蔓延共存区;无滴落无火蔓延区。滴落上限和滴落下限下降曲线在50%氧浓度、5kPa压力发生会合,此后只有火蔓延而不存在滴落现象。(3)当压力降低时,由于线芯温度增加,线芯传导热量增加,导致绝缘层熔融速率加快,从而使得滴落频率增加,同时液滴的表面张力随着压力的降低而增加,使得低压下液滴的质量变大。     

Pipeline leakage detection and isolation: An integrated approach of statistical and wavelet feature extraction with multi-layer perceptron neural network (MLPNN)

Leakage diagnosis of hydrocarbon pipelines can prevent environmental and financial losses. This work proposes a novel method that not only detects the occurrence of a leakage fault, but also suggests its location and severity. The OLGA software is employed to provide the pipeline inlet pressure and outlet flow rates as the training data for the Fault Detection and Isolation (FDI) system. The FDI system is comprised of a Multi-Layer Perceptron Neural Network (MLPNN) classifier with various feature extraction methods including the statistical techniques, wavelet transform, and a fusion of both methods. Once different leakage scenarios are considered and the preprocessing methods are done, the proposed FDI system is applied to a 20-km pipeline in southern Iran (Goldkari-Binak pipeline) and a promising severity and location detectability (a correct classification rate of 92%) and a low False Alarm Rate (FAR) were achieved.     

爆炸波在饱和土介质中传播时压力变化规律的试验研究

介绍了在Φ900平面波加载器中进行的饱和土爆炸波传播试验,通过试验比较系统地研究了爆炸波在饱和土自由场中的传播规律及其在刚性边界上的反射问题。试验表明饱和土中的气体含量是控制波传播规律的主要因素,在深度方向上自由场应力峰值可能随深度增加,而在刚性边界上荷载反射系数可能>2。对饱和土与非饱和土中波传播规律的区别,在确定饱和土中结构的设计荷载时必须给予极大的关注。     

Theoretical equation of gas desorption of particle coal under the non-uniform pressure condition and its analytical solution

Based on the second Fick’s law, the theoretical equation of gas desorption of particle coal under the non-uniform pressure condition was developed in this paper. The analytical solution of the theoretical equation and the method of gas desorption quantity of particle coal under non-uniform pressure condition were obtained.     

油品真实蒸汽压多元非线性回归

油品蒸气压是从事油品蒸发损耗研究、计算油品蒸发损耗量的重要参数,但是仅有美国石油学会给出的诺模图,给利用计算机来计算储罐蒸发损耗带来了很大困难.为了利用计算机来计算储罐的蒸发损耗,运用Excel中的回归功能,对原始数据进行必要的转换,进行了真实蒸气压的多元非线性回归,回归出了油品真实蒸气压计算公式.结果显示,回归的方程具有很高的精度,利用回归方程编制了计算软件,为储罐蒸发损耗计算提供帮助.     

基于电荷监测技术预测矿山动力灾害试验研究

为提高矿山动力灾害预测准确率,应用自主研制的电荷传感器,将标准煤样置于三轴压力室内进行应力-电荷试验。分析围压对煤样压缩破坏过程中电荷信号的影响。结合现场测试,揭示工作面开挖过程中煤体应力与煤壁表面感应电荷的时间和空间变化规律。试验结果表明,煤体压缩过程中电荷信号的变化与煤体所处的应力水平关系密切,处于应力集中区域和应力松弛区域的煤体有明显脉冲状电荷信号,原始应力区电荷信号平稳,电荷信号的变化超前于煤体应力的变化,围压对电荷信号有延缓、强化的作用。     

气-固复合粉体在高原地区灭火性能的试验研究

为满足高原地区低压低氧环境对火灾防治的特殊需求,在拉萨进行模拟试验,研究由溴氟丙烯和13X沸石所组成的气-固复合粉体灭火剂对汽油火的灭火性能,并与平原地区的合肥的灭火效果进行对比。试验结果表明,在拉萨低压低氧的环境下,复合粉体灭火剂对汽油火具有很好的灭火性能。在同样的试验条件下,其灭火时间和灭火剂用量比合肥减少20%以上,说明该复合粉体灭火剂在高原地区有很好的适用性。     

煤与瓦斯突出冲击波及瓦斯气流所致伤害研究

为揭示煤与瓦斯突出过程中冲击波及瓦斯气流传播特性,针对这种突出做功随瓦斯压力、煤的普氏系数和煤的放散初速度变化的特征,运用气体动力学理论,建立冲击波超压、冲击瓦斯流速度与传播距离以及煤层瓦斯压力等参数的关系,计算不同超压下瓦斯气流传播伤害的范围。理论计算与现场测试结果表明,突出冲击波属惰性弱冲击波;波阵面上的超压传播伤害距离与突出时瓦斯膨胀的强度、巷道断面及巷道壁面的摩擦力和局部阻力等因素有关;冲击产生的高压瓦斯气流是造成巷道内大量人员窒息伤亡的主要诱因;突出能量瞬间释放没有补给,冲击波及瓦斯气流会在巷道阻力等因素作用下迅速衰减。     

油污染土壤气体抽排去污模型及影响因素

为了开展适合我国实际情况的有机污染土壤气体抽排净化技术研究,在对油污染土壤的通风去污过程机理进行分析的基础上,建立了一个简化机理模拟模型.以华北地区典型土壤为实验土样,油污染物为例,通过一维土柱实验,研究了抽排气体流速、土壤含水率和土质对去污过程的影响.实验表明抽排气体流速存在最佳值,土壤含水率对不同土质土壤净化时间影响不同,对粉砂土,含水率升高,净化效率增强;而对粘质土壤,结果正好相反.对模型预测结果进行实验验证表明,本文建立的模拟模型在实验限定条件范围内是准确和适用的.