生产工艺条件对菌粉爆炸特征参数的影响

利用扫描电镜及激光粒度分析仪,探究了不同生产工艺条件下医药中间体菌粉A和菌粉B的表面形状及粒径分布,并进行了热解分析,证实上述特征参数存在一定差别。在此基础上进行了爆炸特性参数研究。研究结果表明,上述两种菌粉爆炸下限处于70~90 g/m3,最大爆炸压力峰值0.4~0.5 MPa之间,爆炸性相对较弱,但也必须引起足够的重视。与菌粉B相比,菌粉A相对安全,因此条件许可时优先采用菌粉A生产工艺流程。     

生物质气化火灾爆炸事故BN-LOPA分析

提出一种基于BN-LOPA的生物质气化火灾爆炸事故评价方法。绘制出生物质气化火灾爆炸故障树并转换为贝叶斯网络,计算出的事故发生概率为2.600×10-3,根据风险矩阵得出对应风险等级为10级,因此需要在计划内采取安全措施降低风险。采用贝叶斯网络的向后推导计算基本事件后验概率,找出失效后易导致事故发生的节点,对这些节点设置独立防护层并计算设置后基本事件及顶事件的发生概率。最后得出在设置独立防护层后,生物质气化火灾爆炸事故的发生概率降低至8.068×10-6,对应风险等级从10级降至5级,可满足安全生产的要求。     

炮烟中毒事故致因机理研究及预防技术

炮烟中毒事故属于矿山事故类型之一。炮烟中的有毒气体是导致井下作业人员中毒的根源。通过理论分析得出,炸药的爆炸反应偏离零氧平衡、炸药组分混合不均匀导致爆炸反应不完全、炸药爆炸时周围岩石成分及环境因素是有毒气体生成量增多的主要原因。利用轨迹交叉事故理论模型探究了炮烟中毒事故发展过程,揭示事故发生为人的不安全行为和物的不安全状态在同一时间空间的交叉,消除人的不安全行为或物的不安全状态是避免事故发生的途径。针对防治炮烟中毒,提出了预防炮烟中有毒气体超标和炮烟中毒的实用技术,对矿山炮烟中毒预防工作具有指导意义。     

爆炸应力波在层状节理岩体中的传播规律试验研究

为了研究爆炸应力波在岩体中的传播规律,基于相似理论,开展了爆炸应力波在层状节理岩体中衰减的实验研究。研究表明,节理阻碍 应力波的传播且存在各向异性;对于垂直或小角度入射节理的应力波,在垂直方向和纵向的衰减很明显并且幅度较大,在横向衰减不明显;对 于斜入射节理的应力波,横向和垂直方向没有明显的衰减,纵向的衰减很明显并且幅度较大;应力波的合成峰值速度与炮孔密集度之间的关系 密切,当炮孔间距超过一定距离时,实际测得的速度时程为最近药包爆破产生的应力波,并非总药量产生的应力波的叠加。     

Validation of a new formula for predicting the lower flammability limit of hybrid mixtures

A correlation of the lower flammability limit for hybrid mixtures was recently proposed by us. The experimental conditions including ignition energy and turbulence which play a primary role in a gas or dust explosion were at fixed values. The sensitivity of such experimental conditions to the accuracy of the proposed formula was not thoroughly discussed in the previous work. Therefore, this work studied the effect of varying the ignition energy and turbulence intensity to the formula proposed in our previous paper. For ignition energy effect, results from methane/niacin mixture demonstrated that the MEC and LFL will not be affected by changing ignition energy. There is no distinguishable difference among gas explosion index (K_G) and dust explosion index (K_St) derived from tests with every ignition energy (2.5 kJ, 5 kJ and 10 kJ) in a 36 L vessel. The proposed formula is independent of ignition energy. For turbulence effect, the proposed formula can have a good prediction of the explosion and non-explosion zone if the ignition delay time is within a certain range. The formula prediction is good as the ignition delay time increases up to 100 ms in this work. Propane/niacin and propane/cornstarch mixtures are also tested to validate the proposed formula. It has been confirmed that the proposed formula predicts the explosion and non-explosion zone boundary of such mixtures.     

Explosion behaviour of metallic nano powders

This paper describes experiences and results of experiments with several metallic dusts within the nanometer range. The nano dusts (aluminium, iron, zinc, titanium and copper) were tested in a modified experimental setup for the test apparatus 20 L-sphere (also known as 20-L Siwek Chamber), that enables the test samples to be kept under inert atmospheric conditions nearly until ignition. This setup was already introduced in earlier papers by the authors. It was designed to allow the determination of safety characteristics of nano powders under most critical circumstances (e.g. minimisation of the influence of oxidation before the test itself). Furthermore the influence of passivation on explosion behaviour is investigated and additional tests with deposited dust were carried out to describe the burning behaviour of all dusts. For a better characterisation all samples were tested with a simultaneous thermal analysis (STA). To minimise the influence of oxidation all samples were handled at inert conditions until shortly before ignition or start of the test respectively.     

On the explosion and flammability behavior of mixtures of combustible dusts

In the work presented in this paper, the explosion and flammability behavior of combustible dust mixtures was studied. Lycopodium, Nicotinic acid and Ascorbic acid were used as sample dusts.In the case of mixtures of two dusts, the minimum explosive concentration is reproduced well by a Le Chatelier's rule-like formula, whereas the minimum ignition energy is a linear combination of the ignition energies of the pure dusts.An unexpected behavior has been found in relation to the explosion behavior and the reactivity. When mixing Lycopodium and Nicotinic acid or Ascorbic acid, the rate of pressure rise of the mixture is much higher than the rate of pressure rise obtained by linearly averaging the values of the pure dusts (according to their weight proportions), thus suggesting that strong synergistic effects arise; but it is comparable to that of the most reactive dust in the mixture.The observed behavior seems to be linked to the presence of minerals in the Lycopodium particles which catalyze oxidation reactions of Nicotinic acid and Ascorbic acid, as suggested by TG analysis.In the case of mixtures of three dusts, a similar behavior is observed when the concentration of Lycopodium is twice that of the other two dusts.     

粉尘爆炸泄压面积计算及影响因素分析

随着涉粉行业各类企业数量的增长,以及粉尘爆炸产生的巨大危害,企业对粉尘泄爆、防爆越来越重视。在粉尘泄爆方面,泄爆装置的泄放面积影响最大泄爆压力,国内外不同标准的计算方法也有区别,因此针对不同标准的计算方法做出了比较并举例计算说明,为泄爆装置尺寸的选择提供理论依据。     

基于多事故模式的有毒易燃气体道路运输泄漏事故应急疏散范围研究

为确定有毒易燃气体道路运输泄漏事故应急救援的应急疏散范围,降低人员伤亡程度,在对泄漏事故及后续次生灾害演化模式分析的基础上,提出了基于多事故模式的应急疏散范围综合确定方法,分析了多事故模式后果预测的相关理论,明确了应急疏散区域综合确定的步骤和流程。以道路运输氨气泄漏事故为例,采用MATLAB软件对不同时间下的中毒和蒸气云爆炸事故伤害范围分别进行了数值模拟研究。结果表明：相较于单一事故模式,基于多事故模式的应急疏散范围综合确定方法更为科学、合理和准确,能为有毒易燃气体道路运输泄漏事故的应急疏散提供更加精确和可靠的决策依据。