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511.
Jörg Luster Manoj Menon Sandra Hermle Rainer Schulin Madeleine S. Günthardt-Goerg Bernd Nowack 《Water, Air, & Soil Pollution: Focus》2008,8(2):163-176
Soil translocation for recultivation of soil removed from construction sites and for the preparation of refilled lysimeters
inevitably involves disturbance of soil structure, and, if intermediate storage is included, also drying and rewetting of
the soil. We report on an experiment with model forest ecosystems, where uncontaminated forest subsoils were covered with
non-contaminated or freshly heavy metal (mainly Zn and Cu) contaminated topsoil in large lysimeters. Monitoring of the chemical
composition of the drainage water revealed two distinct soil conditioning phases. During an initial phase of about a year
strongly elevated nitrate and sulfate concentrations occurred that were attributed to a mineralisation flush caused by the
increased accessability of mineralisable nitrogen and sulfur in destroyed aggregates. These effects were significantly larger
in lysimeters with calcareous subsoil than in those with acidic subsoil. The second phase was characterised by a gradual decrease
in dissolved organic carbon and sulfate concentrations, in particular in the acidic subsoil. This decrease may be attributed
to the depletion of pools made accessible during aggregate destruction or the formation of new aggregates. These chemical
changes had only little effects on the concentrations of copper and zinc in the drainage water. Based on our results, it can
be concluded that large refilled lysimeters can be used for many purposes without risk of compromised results, if a conditioning
phase of about 1 year with sufficiently moist soil conditions is respected. Nevertheless, gradual changes in soil chemical
characteristics still occur after this initial phase. Implications for the recultivation of sites using relocated soils are
discussed. 相似文献
512.
A. A. Olajire E. T. Ayodele F. E. Imeokparia 《Environmental monitoring and assessment》1999,57(2):183-194
Samples of compost-amended soil from waste dumping sites in Lagos Metropolis were extracted with dichloromethane (3 × 20 cm3) and the extract was evaporated at 35 °>C. The residue was extracted with 2,2,4-trimethylpentane, and portions of the solution were applied to a column containing silica gel from which aliphatic and aromatic hydrocarbons were eluted with n-hexane and toluene respectively. Analysis of the n-hexane fraction using gas chromatography showed the presence of a mixture of aliphatic hydrocarbons, ranging from C9 to C25, while ultraviolet analysis of the toluene fraction suggested 1,2-benzanthracene; 2,3-benzphenanthrene, chrysene and pyrene as polyaromatic compounds present in samples analyzed. The crude extracts were highly coloured and viscous. Total extractable organic residues in the 2,2,4-trimethylpentane extracts ranged from 36 to 89 mg g-1 of soil. 相似文献
513.
514.
Jasmonic acid treatment and mammalian herbivory differentially affect chemical defenses and growth of wild mustard (Brassica kaber) 总被引:2,自引:0,他引:2
Summary. Jasmonic acid (JA) is a wound-related hormone found in most plants that, when applied exogenously, can induce increases in
levels of chemical defenses in patterns similar to those induced by mechanical damage or insect feeding. Relative to responses
to insect and pathogen attack, chemical responses of herbaceous plants to mammalian herbivore attack have been little studied.
In a field experiment, we compared the effects of JA treatment and naturally occurring mammalian herbivory on the expression
of trypsin inhibitors, glucosinolates, peroxidase activity and growth of wild mustard (Brassica kaber). Exogenous JA significantly increased trypsin inhibitor activity and glucosinolate concentration, and moderately increased
peroxidase activity in the eighth true leaves of five-week-old plants, relative to untreated controls. In contrast, levels
of these chemical defenses in the eighth true leaves or in regrowth foliage of plants that had ∼80% of their leaf area removed
by groundhogs (Marmota monax) did not differ from that in undamaged and untreated controls. Although exogenous JA significantly elevated levels of chemical
defenses, it did not affect height of plants through the season and only slightly reduced time to first flower. Groundhog
herbivory significantly reduced height and delayed or abolished flowering, but these effects were not substantial unless coupled
with apical meristem removal. We hypothesize that the lack of effect of groundhog herbivory on chemical defenses may be due
in part to the speed and pattern of leaf area removal by groundhogs, or physiological constraints caused by leaf area loss.
Despite having no effect on chemical defense production, leaf area loss by groundhogs was more costly to growth and fitness
than the effects of JA application in this study, but only substantially so if coupled with apical meristem removal. We suggest
that in general, costs of defense production in plants are likely to be minimal when compared to the risk of losing large
amounts of leaf area or primary meristematic tissue. Thus, if they are effective at deterring herbivory, the benefits of inducible
defense production likely outweigh the costs in most cases.
Received 20 December 2000; accepted 3 May 2001 相似文献
515.
通过把起相转移作用的聚乙二醇链固载在硅胶上(SiO2-PEG600),再将聚乙稀吡咯烷酮(PVP)络合双金属Pd-Cu(PVP-PdCl2-CuCl2)后负载其中,制成一种新型双负载双金属水相脱卤催化剂PVP-PdCl2-CuCl2/SiO2-PEG600。以甲酸钠为氢转移试制,在水相中催化有机卤化物脱卤,研究结果表明:反应温度为800℃,Pd∶Cu=2∶1(摩尔比),反应介质pH≈11.7左右时,该催化剂对芳香氯化物及α-氯代酮、酯具有良好的催化脱氯和重复使用性能。 相似文献
516.
一个新的拓扑指数用于芳烃化合物溶解度、分配系数及生物毒性的研究 总被引:19,自引:0,他引:19
在分子拓扑理论的基础上,提出了一个新的拓扑指数Yx,并用Yx研究了芳烃化合物的溶解度、分配系数及生物毒(活)性,给出了相关方程。结果表明,新方法计算方便,物理意义明确,预测值与相应的实验值较吻合。 相似文献
517.
518.
Summary. Chemical defense against herbivores has rarely been investigated for freshwater plants, possibly due to the common misconception
that herbivory on aquatic macrophytes is low and would not select for chemical defenses. In previous work, the freshwater
angiosperm Saururus cernuus was shown to be a low preference food for omnivorous crayfish despite its high nutrient value and relatively soft texture.
We used feeding by the crayfish Procambarus clarkii to guide fractionation of the deterrent lipid-soluble extract of this plant, leading to the identification of seven deterrent
lignoid metabolites, (–)-licarin A, (+)-saucernetin, (–)-dihydroguaiaretic acid, (–)-sauriols A and B, (–)-saucerneol, and
(–)-saucerneol methyl ether. Lignans have been implicated in terrestrial plant chemical defenses as insect growth inhibitors,
insect toxins, nematocides, antibacterial, and antifungal agents. However, these activities have rarely been demonstrated
using ecologically relevant methodologies in terrestrial systems, and never before in freshwater systems. The widespread nature
of lignans amongst very distantly related plants, along with their rich diversity of molecular structure, suggests that they
could play a large role in mediating plant-herbivore interactions. In addition to the lignoid compounds we identified, there
were other compounds present in low concentration or unstable compounds that were deterrent, that did not appear to be lignans,
but that we were unable to identify. This plant thus appears to be defended by a complex mixture of natural products.
Received 6 June 2000; revised 23 August 2000; accepted 2 September 2000 相似文献
519.
鸭绿江(丹东段)江水中未知有机污染物分析鉴定与有毒有机物名录筛选 总被引:7,自引:0,他引:7
刘绮 《城市环境与城市生态》2001,14(2):41-43
采用美国惠普公司MC/GS联用仪,对鸭绿江(丹东段)江水中有机污染物种类、组成进行了分析鉴定,进而采用高压液相色谱法对多环芳烃类进行定量测定与评价,进行了该江段有毒有机物名录筛选,提出由27种有毒有机污染物组成的名单。 相似文献
520.
接种Glomus versiforme对红三叶草利用有机磷的影响 总被引:1,自引:1,他引:0
以红三叶草为材料,利用三室隔网培养方法,研究接种菌根真菌Glmous versiforme对土壤有机磷及外加有机磷化合物植酸钠(Na-Phytate)、核糖核酸(RNA)和卵磷脂(Lecithin)的利用效率,植株生长7wk后收获测定植标干物重、含磷量和根系菌根侵染率,结果表明:接种菌根真菌能明显增加植株干物重、含磷量和吸磷总量,与各有机磷处理相比,无机磷(KH2PO4)处理生长效应最好,施用有机磷化合物各处理与CK相比均明显促进了植株生长,但不同有机磷处理之间没有显著差异,在植株吸磷量上,各接种处理均为相应CK处理的2倍以上,其中磷酸二氢钾处理吸磷量最高,菌根对照植物的根外菌丝虽然被限制在有限的空间内,但其吸磷量也达到不施磷的CK-M处理的2倍多,这说明由于菌根的形成植物能利用土壤因有的有机磷来满足自身生长的需要,表3参10 相似文献