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91.
人工甜味剂环境行为研究进展 总被引:2,自引:0,他引:2
人工甜味剂是一类人工合成或半合成的蔗糖取代物,由于人们对饮食健康的关注而被越来越广泛地应用于食品和饮料中.但是大多数人工甜味剂在人体内几乎不被代谢就随尿液和粪便直接排到生活污水中.近年,几种典型的甜味剂在水体中广泛被检出且浓度较高,同时研究发现部分甜味剂难以降解,因此人工甜味剂已被视为新型有机污染物而得到关注.本文就人工甜味剂在水处理设施中的行为及其在环境来源和分布的相关研究进行了综述,总结了水处理设施和水环境中甜味剂的污染特征规律,并对今后的研究进行了展望. 相似文献
92.
凋落叶作为森林凋落物的主要组成部分,其溶出的大量有机质也是森林土壤可溶性有机质(DOM)的主要来源之一。研究森林凋落叶溶出DOM对PAHs增溶作用的影响有利于合理预测及评价森林土壤中PAHs的环境行为和生态风险。本研究采集了南亚热带常绿阔叶人工林的4种常见树种--尾叶桉(Eucalyptus urophylla)、木荷(Schima superba)、大叶相思(Acacia auriculiformis)和湿地松(Pinus elliottii)的新近凋落叶为试验材料,研究其DOM含量、组成与性质,对比分析了不同凋落叶DOM对菲的増溶作用及其与DOM性质的相关关系。结果表明,4种凋落叶的可溶性有机碳(DOC)质量分数在C 11.61~36.25 mg·g-1之间,其中尾叶桉的含量最大,湿地松最小。尾叶桉和木荷DOM的主要组分是可溶性糖(SS)和可溶性酚(SP),两者总C量占DOC的比例超过47%,而大叶相思和湿地松中SS和SP两者总量所占比例均低于30%。另外,4种凋落叶DOM的质量分数(以C计)与其电导率的线性关系图中有明显转折点,说明它们均具有表面活性剂的性质。凋落叶DOM在临界胶束浓度(CMC)之上对菲具有不同程度的増溶作用,其与菲的结合系数(logKDOC)的大小顺序为尾叶桉(3.05 L·kg-1)>木荷(3.02 L·kg-1)>大叶相思(2.79 L·kg-1)>湿地松(2.54 L·kg-1),这表明尾叶桉和木荷DOM的增溶作用明显高于大叶相思和湿地松DOM。经分析表明,logKDOC与各DOM在254、280 nm处的特征紫外吸光度值(SUV-A254、SUV-A280)及其SS、SP的相对含量均呈显著正相关(p<0.01),与A240/A420、A254/A400比值呈显著负相关(p<0.01),说明DOM的芳香化程度越高,分子量越大, SS与SP所占比例越高,其对菲的増溶效果越明显。 相似文献
93.
Soils from two typical tidal salt marshes with varied salinity in the Yellow River Delta wetland were analysed to determine possible effects of salinity on soil carbon sequestration through changes in soil microbiology. The mean soil respiration (SR) of the salt water–fresh water mixing zone (MZ) was 2.89 times higher than that of the coastal zone (CZ) (4.73 and 1.63?μmol?m?2?s?1, respectively, p?.05), and soil dehydrogenase activity was the main microbial factor influencing SR. In addition to the higher soil microbial biomass, the MZ had more β-Proteobacteria than the CZ, as well as some specific bacteria with strong heterotrophic metabolic activity such as Pseudomonas sp. and Limnobacter sp. that might have led to its higher dehydrogenase activity and respiratory rates. Additionally, the CZ possessed more Halobacteria and Thaumarchaeota with the ability to fix CO2 than the MZ. Significantly lower soil salinity in MZ (4.25?g?kg?1) was suitable for β-Proteobacteria, but detrimental for Halobacteria compared with CZ (7.09?g?kg?1, p?.01), which might lead to the lower microbial decomposition capacity of soils in CZ. As a result, the CZ has a higher soil organic carbon content than the MZ. 相似文献
94.
Hydrophobic acid organic matter (HpoA) extracted from treated effluent has been known to improve the rejection of steroid hormone estrone by reverse osmosis (RO) and nanofiltration (NF) membranes. In this study, the effects of solution chemistry (solution pH and ionic strength) on the estrone rejection by NF membrane with the presence of HpoA were systematically investigated. Crossflow nanofiltration experiments show that the presence of HpoA significantly improved estrone rejection at all pH and ionic strength levels investigated. It is consistently shown that the “enhancement effect” of HpoA on estrone rejection at neutral and alkaline pH is attributed to the binding of estrone by HpoA macromolecules via hydrogen bonding between phenolic functional groups in feed solutions, which leads to an increase in molecular weight and appearance of negative charge. The membrane exhibited the best performance in terms of estrone rejection at pH 10.4 (compared to pH 4 and pH 7) as a result of strengthening the electrostatic repulsion between estrone and membrane with the presence of HpoA. At neutral pH level, the ability of HpoA macromolecules to promote estrone rejection became stronger with increasing ionic strength due to their more extended conformation, which created more chances for the association between estrone and HpoA. The important conclusion of this study is that increasing solution pH and salinity can greatly intensify the “enhancement effect” of HpoA. These results can be important for NF application in direct/indirect potable water reuse. 相似文献
95.
96.
An overview of the methods used in the characterisation of natural organic matter (NOM) in relation to drinking water treatment 总被引:9,自引:0,他引:9
Matilainen A Gjessing ET Lahtinen T Hed L Bhatnagar A Sillanpää M 《Chemosphere》2011,83(11):1431-1442
Natural organic matter (NOM) is found in all surface, ground and soil waters. During recent decades, reports worldwide show a continuing increase in the color and NOM of the surface water, which has an adverse affect on drinking water purification. For several practical and hygienic reasons, the presence of NOM is undesirable in drinking water. Various technologies have been proposed for NOM removal with varying degrees of success. The properties and amount of NOM, however, can significantly affect the process efficiency. In order to improve and optimise these processes, the characterisation and quantification of NOM at different purification and treatment processes stages is important. It is also important to be able to understand and predict the reactivity of NOM or its fractions in different steps of the treatment. Methods used in the characterisation of NOM include resin adsorption, size exclusion chromatography (SEC), nuclear magnetic resonance (NMR) spectroscopy, and fluorescence spectroscopy. The amount of NOM in water has been predicted with parameters including UV-Vis, total organic carbon (TOC), and specific UV-absorbance (SUVA). Recently, methods by which NOM structures can be more precisely determined have been developed; pyrolysis gas chromatography-mass spectrometry (Py-GC-MS), multidimensional NMR techniques, and Fourier transform ion cyclotron resonance mass spectrometry (FTICR-MS). The present review focuses on the methods used for characterisation and quantification of NOM in relation to drinking water treatment. 相似文献
97.
98.
基于目前国家建立环境污染责任保险制度的规划需求和河南省当前新发展形势需要,选择以河南省典型高污染、高风险行业(即煤化工行业)为研究对象.在对相关理论进行分析的基础上,识别影响河南省煤化工行业的环境风险因子,并确定指标的评估标准(权重及评分结果).遵照指标体系的建立原则,采用层次分析法,从内在性和外在性两方面因素构建煤化工行业环境风险等级划分指标体系,进一步将评分结果与环境风险等级比对,最终将煤化工行业的环境风险等级划分为5个等级,为河南省环境污染责任保险制度的建立奠定基础. 相似文献
99.
100.