氨气敏电极法和纳氏试剂分光光度法对地表水中氨氮的比对测试

采用不同质量浓度的氨氮标准样品和实际样品,用氨气敏电极法和纳氏试剂分光光度法进行同步测试。结果表明,2种分析方法在水样氨氮质量浓度在0. 159～2. 81 mg/L范围内具有良好的可比性、精密性和准确性。氨气敏电极法的检出限为0. 03 mg/L,平行6次测定样品的相对标准偏差为0. 4%～4. 2%,加标回收率为85. 0%～110%;纳氏试剂分光光度法的检出限为0. 025 mg/L,平行6次测定样品的相对标准偏差为0. 5%～6. 4%,加标回收率为93. 0%～99. 8%。同时氨气敏电极法在样品预处理、试剂配制和分析时间上要优于纳氏试剂分光光度法。氨气敏电极法能够满足地表水自动监测在线比对实际工作的需求,该方法具有良好的适用性。     

遥感技术在水生态环境管理的应用与前景

随着遥感数据源的不断丰富,遥感技术不断提高,可以解决越来越多的水环境问题。指出了当前水生态环境管理方面的主要需求,结合目前遥感技术的发展,对国内外的水环境遥感研究进展进行综述。以湖泊富营养化监测与评估、核电站温排水遥感监测及城市黑臭水体遥感监测为案例,具体阐述遥感在水环境管理中的应用方法及成效。未来水生态环境管理发展趋势将以水污染防治为主向水污染防治和水生态修复与保护并重发展。基于此趋势,提出遥感在水生态修复的应用潜力,利于更多地方部门积极有效应用遥感技术,解决水生态环境问题。     

Thinking inside the basin: scale in transboundary water management

While transboundary waters are widely advocated to be best managed at the basin level, practical experience in transboundary waters at the basin vis‐à‐vis other scales has not been systematically examined. To understand past experiences in transboundary water management at alternate scales, this paper: (i) determines the relative abundance of water treaties at different scales and (ii) elucidates how transboundary water law varies according to the scale to which it applies. The paper developed a scale typology with six groups, and systematically applied it to stratify transboundary water treaties. Treaty contents were then compared across scales according to the following set of parameters: primary issue area, temporal development, and important water management attributes. Results of this work reveal: (i) treaties tend to focus on hydropower and flood control at smaller scales, and organizations and policies at larger scales; (ii) a temporal trend toward treaties concluded at larger scales; and (iii) a higher proportion of treaties is at larger scales in Africa and Asia than in Europe and the Americas. These findings suggest that smaller scale cooperation may constitute a more constructive scale in which to achieve development‐oriented cooperation. Further, scope may exist to complement basin scale cooperation with cooperation at smaller scales, in order to optimize transboundary water management. In the context of basin‐wide management frameworks, Africa and Asia may benefit from greater emphasis on small‐scale transboundary water cooperation.     

Implementing the European flood risk management plan

In response to the extreme flood events of recent decades, the European Union has released the Floods Directive (2007/60/EC), which requires the creation of flood risk management plans. These plans do not yet exist in practice, as water management agencies have until 2015 to put them into action. This contribution will discuss two questions regarding the European flood risk management plan: First, how is the new instrument integrated into the various member states, particularly with respect to the scenario approach? Second, how prepared are the institutions for the collaborative planning paradigm of the flood risk management plan, particularly with respect to the river basin districts approach? Citing examples from France, Germany, the Netherlands, and Great Britain, this paper offers both a pessimistic and an optimistic perspective on the implementation of the new flood risk management instrument.     

Infrastructure development through PPPs in India: criteria for sustainability assessment

Public private partnerships (PPPs) allow the Indian Government to leverage private capital for meeting the widening demand-supply gap in the provision of infrastructure services. The private sector, however, prefers to limit the participation to financially attractive projects only, thereby resulting in patterns of infrastructure creation impeding the progress towards sustainable development. In order to promote sustainable development, the PPP procurement process should focus on incentivising the private sector for sustainable infrastructure development rather than concentrating on ensuring financial sustainability only. This paper discusses the principles-based PPP-specific framework that has been developed to facilitate assessment of PPP projects' progress towards sustainable development. The framework development was based on a holistic approach to sustainability assessment and subsequently validated through questionnaire survey with key stakeholders in the Indian PPP programme. This framework will provide the decision makers with appropriate decision aid for integration of sustainable development principles in the PPP procurement process.     

Application of environmental risk assessment for strategic decision-making in coastal areas: case studies in China

Environmental risk assessment (ERA) is a powerful technical tool for analyzing potential and extreme adverse environmental impacts, and has found wide application in supporting decision-making processes over the last two decades. However, to date there has been no interrelated application of ERA to support the processes of strategic decision-making (SDM), especially in coastal areas.

In this paper, we attempt to verify the feasibility of the proposed integrated ERA–SDM approach and its methodology by applying it to two case studies (in Xiamen Bay and Luoyuan Bay) of the principal coastal functional zoning (PCFZ, a kind of SDM and similar to the coastal and marine spatial planning in western). The results show that the integrated ERA–SDM approach could integrate ERA into the entire SDM process, directly support the PCFZ, and avoid or mitigate dire environmental risk that can be introduced by SDM processes.     

Result-oriented approaches to the management of drinking water catchments in agricultural landscapes

Management of water quality in drinking water catchments is of ongoing, high importance as nitrate concentrations are often still very high. We analysed the Augsburg catchment in Germany, a unique example where a result-oriented approach has been implemented. We investigated the historical evolution of the water protection programme, the result-oriented payment contracts with farmers, and farmer satisfaction with the contracts, based on interviews with the water utility and farmers as well as an analysis of the literature. Today, the water protection programme has been successfully implemented, and a significant reduction of nitrate concentration was achieved due to the following factors: (1) investment of non-negligible amounts of money for high compensation and remuneration payments, (2) different contract options, (3) farmers’ participation in the negotiation process for result-oriented payment contracts, (4) involvement of “outside” people and institutions in negotiation processes, (5) anticipation of starting a programme when nitrate levels were still far below legislative thresholds, and (6) a political and legislative framework allowing direct decisions by a water supplier.     

Environmental health in the complex city: a co-evolutionary approach

While public health and urban planning were closely linked in the past, today both domains are institutionally separate. In most cases, health intersects with spatial planning processes only through obligatory evaluations, such as environmental impact assessments, or restrictive environmental legislation. This institutionalisation of health criteria in most western countries has difficulty in dealing with recent environmental health challenges, leading to continual distrust and conflict between citizens and the government. This impasse has recently been discussed by academics who acknowledge the complexity of both city and health issues. It seems, however, that the full extent of the issue has not been covered yet, leading to recommendations and frameworks that are useful but fixed and retrospective. This paper moves beyond those fixed frameworks to develop a better understanding of the complexity of the current disconnect and explores ideas for a future planning approach, grounded on new ideas of co-evolutionary and adaptive planning.     

钙钛矿型La_(0.8)Ce_(0.2)Fe_(1-x)Co_xO_3催化剂的制备及其三效催化活性

采用自燃烧法制备了一组钙钛矿型复合氧化物La_(0.8)Ce_(0.2)Fe_(1-x)Co_xO_3(x=0.9,0.7,0.5,0.3,0.1),并考察了其对CO、C_3H_6和NO的三效催化活性。XRD和SEM表征结果显示,La_(0.8)Ce_(0.2)Fe_(1-x)Co_xO_3具有良好的钙钛矿型晶体结构,晶粒大小为纳米级并自组装成片状结构。催化剂的比表面积为14.73~22.43 m~2/g,含有微孔和介孔结构。催化活性评价结果表明:La_(0.8)Ce_(0.2)Fe_(0.1)Co_(0.9)O_3具有很好的三效催化活性,在理论空燃比的条件下,CO、C_3H_6和NO的起燃温度分别为195℃、264℃和290℃,完全转化温度分别为239℃、418℃和415℃,低温三效催化活性良好;Fe和Co的掺杂量同时影响着La_(0.8)Ce_(0.2)Fe_(1-x)Co_xO_3的催化效果。     

Preliminary studies on potential remediation of acid mine drainage‐impacted soils by amendment with drinking‐water treatment residuals

Mining operations result in a wide range of environmental impacts: acid mine drainage (AMD) and acid sulfate soils being among the most common. Due to their acidic pH and high soluble metal concentrations, both AMD and acid sulfate soils can severely damage the local ecosystems. Proper post‐mining management practices are necessary to control AMD‐related environmental issues. Current AMD‐impacted soil treatment technologies are rather expensive and typically not environmentally sustainable. We conducted a 60‐day bench‐scale study to evaluate the potential of a cost‐effective and environment‐friendly technology in treating AMD‐impacted soils. The metal binding and acid‐neutralizing capacity of an industrial by‐product, drinking water treatment residuals (WTRs) were used for AMD remediation. Two types of locally generated WTRs, an aluminum‐based WTR (Al‐WTR) and a lime‐based WTR (Ca‐WTR) were used. Highly acidic AMD‐impacted soil containing very high concentrations of metals and metalloids, such as iron, nickel, and arsenic, was collected from the Tab‐Simco coal mine in Carbondale, Illinois. Soil amendment using a 1:1 Al‐ and Ca‐WTR mix, applied at 5 and 10 percent rates significantly lowered the soluble and exchangeable fractions of metals in the AMD‐impacted soil, thus lowering potential metal toxicity. Soil pH increased from an extremely acidic 2.69 to a near‐neutral 6.86 standard units over the 60‐day study period. Results from this preliminary study suggest the possibility of a successful scale‐up of this innovative, cost‐effective, and environmentally sustainable technology for remediating AMD‐impacted acid sulfate soils.