全文获取类型
收费全文 | 139篇 |
免费 | 19篇 |
国内免费 | 76篇 |
专业分类
安全科学 | 15篇 |
废物处理 | 3篇 |
环保管理 | 3篇 |
综合类 | 118篇 |
基础理论 | 59篇 |
污染及防治 | 25篇 |
评价与监测 | 8篇 |
社会与环境 | 1篇 |
灾害及防治 | 2篇 |
出版年
2023年 | 2篇 |
2022年 | 2篇 |
2021年 | 3篇 |
2020年 | 4篇 |
2019年 | 4篇 |
2018年 | 3篇 |
2017年 | 4篇 |
2016年 | 8篇 |
2015年 | 8篇 |
2014年 | 6篇 |
2013年 | 25篇 |
2012年 | 18篇 |
2011年 | 8篇 |
2010年 | 9篇 |
2009年 | 14篇 |
2008年 | 6篇 |
2007年 | 9篇 |
2006年 | 12篇 |
2005年 | 5篇 |
2004年 | 7篇 |
2003年 | 7篇 |
2002年 | 7篇 |
2001年 | 8篇 |
2000年 | 6篇 |
1999年 | 7篇 |
1998年 | 9篇 |
1997年 | 3篇 |
1995年 | 5篇 |
1994年 | 5篇 |
1993年 | 5篇 |
1992年 | 4篇 |
1991年 | 3篇 |
1990年 | 1篇 |
1989年 | 2篇 |
1988年 | 1篇 |
1987年 | 2篇 |
1986年 | 2篇 |
排序方式: 共有234条查询结果,搜索用时 31 毫秒
12.
13.
The octanol–air partition coefficients (KOA) for PBB15, PBB26, PBB31, PBB49, PBB103 and PBB153 were determined as a function of temperature using a gas chromatographic retention time technique with 1,1,1-trichloro-2,2-bis (4-chlorophenyl) ethane (p,p′-DDT) as a reference substance. The internal energies of phase change from octanol to air (ΔOAU) were calculated for the six compounds and were in the range from 74 to 116 kJ mol−1. Simple regression equations of log KOA versus relative retention times (RRTs) on gas chromatography (GC), and log KOA versus molecular connectivity indexes (MCI) were obtained, for which the correlation coefficients (r2) were greater than 0.985 at 283.15 K and 298.15 K. Thus the KOA values of the remaining PBBs can be predicted by using their RRTs and MCI according to these relationships. 相似文献
14.
一个新的拓扑指数用于芳烃化合物溶解度、分配系数及生物毒性的研究 总被引:19,自引:0,他引:19
在分子拓扑理论的基础上,提出了一个新的拓扑指数Yx,并用Yx研究了芳烃化合物的溶解度、分配系数及生物毒(活)性,给出了相关方程。结果表明,新方法计算方便,物理意义明确,预测值与相应的实验值较吻合。 相似文献
15.
水体中的微塑料会吸附其中的有机污染物,影响有机污染物和微塑料的环境归趋和生态毒性。研究微塑料对有机污染物的吸附行为,对于评价有机污染物和微塑料的环境赋存、迁移及生物有效性有重要意义。污染物在微塑料与水之间的平衡分配系数(Kd),是表征微塑料对有机污染物吸附能力的重要参数。实验方法难以逐个测定众多有机污染物的Kd值,有必要发展其预测模型。本研究搜集了有机污染物的线性溶解能关系(LSER)参数及Kd值,构建了可预测有机污染物在聚丙烯微塑料与海水、聚乙烯微塑料与海水、聚乙烯微塑料与淡水之间Kd值的LSER模型。模型具有良好的拟合优度(R2adj介于0.794~0.903)、稳健性(Q2LOO和Q2BOOT分别介于0.763~0.863和0.720~0.804)和预测能力(R2ext和Q2ext分别介于0.886~0.971和0.825~0.954),能够用于预测多氯联苯、多环芳烃、六氯环已烷和氯苯类有机污染物的Kd值。 相似文献
16.
Francisco Torrens Gloria Castellano 《Journal of environmental science and health. Part. B》2013,48(6):400-407
The high‐performance liquid‐chromatographic retentions of red‐wine pesticide residues are modeled by structure–property relationships. The effect of different types of features is analyzed: geometric, lipophilic, etc. The properties are fractal dimensions, partition coefficient, etc., in linear and nonlinear correlation models. Biological plastic evolution is an evolutionary perspective conjugating the effect of acquired characters and relations that emerge among the principles of evolutionary indeterminacy, morphological determination and natural selection. It is applied to design the co‐ordination index that is used to characterize pesticide retentions. The parameters used to calculate the co‐ordination index are the molar formation enthalpy, molecular weight and surface area. The morphological and co‐ordination indices barely improve the correlations. The fractal dimension averaged for non?buried atoms, partition coefficient, etc. distinguishes the pesticide molecular structures. The structural and constituent classification is based on nonplanarity, and the number of cycles, and O, S, N and Cl atoms. Different behavior depends on the number of cycles. 相似文献
17.
Bioaccumulation models take various elimination and uptake processes into account, estimating rates from chemical lipophilicity, expressed as the octanol-water partition ratio (Kow). Here, we focussed on metabolism, which transforms parent compounds into usually more polar metabolites, thus enhancing elimination. The aim of this study was to quantify the change in lipophilicity of relevant organic pollutants undergoing various biotransformation reactions in mammals. We considered oxidation reactions catalyzed by three enzyme groups: cytochrome P450 (CYP), alcohol dehydrogenase (ADH), and aldehyde dehydrogenase (ALDH). Estimated log Kow values of a selected dataset of parent compounds were compared with the log Kow of their first metabolites. The log Kow decreased by a factor that varies between 0 and −2, depending on the metabolic pathway. For reactions mediated by CYP, the decrease in Kow was one order of magnitude for hydroxylated and epoxidated compounds and two orders of magnitude for dihydroxylated and sulphoxidated xenobiotics. On the other hand, no significant change in lipophilicity was observed for compounds N-hydroxylated by CYP and for alcohols and aldehydes metabolized by ADH and ALDH. These trends could be anticipated by the calculus method of log Kow. Yet, they were validated using experimental log Kow values, when available. These relationships estimate the extent to which the elimination of pollutants is increased by biotransformation. Thus, the quantification of the Kow reduction can be considered as a first necessary step in an alternative approach to anticipate biotransformation rates, which are hard to estimate with existing methods. 相似文献
18.
Salting-out phenomenon and 1-octanol/water partition coefficient of metalaxyl pesticide 总被引:1,自引:0,他引:1
In this paper, we present the effect of inorganic cations such as Na+, K+, Ca2+, Mg2+ on the salting-out phenomenon of metalaxyl from pure water to aqueous salt solutions. Moreover the 1-octanol/water partition coefficient in pure water is presented. To accomplish this, aqueous solubility of metalaxyl was determined in pure water, in different salt solution (NaCl, KCl, CaCl2 and MgCl2), and at different concentration level ranging from 0.01 to 1.5 M. The 1-octanol/water partition coefficient was determined using the static shake-flask method. Solubility was determined using dynamic saturation method for pure water in the range of 298.15-325.15 K and at 298.15 K for different salt solutions. The solubility value in pure water for studied interval was found constant (m = 3.118 × 10−2 mol kg−1).Solubility values were used to calculate the standard molar Gibbs free energy of dissolution (ΔsolG°) and transfer (ΔtrG°) at 298.15 K. The values of ΔtrG° from pure to all studied aqueous salt solutions did not exceed 2 kJ mol−1, the value of ΔsolG° of dissolution is 18.5 ±0.72 kJ mol−1. The 1-octanol/water partition coefficient in pure water log Ko/w is equal to 1.69. The obtained results confirm the classification of the neutral metalaxyl as a slightly hydrophobic molecule. 相似文献
19.
20.
通过将分区疏散转化为分配问题(Allocation Problem),并采用启发式的A*优化算法,对人员位置固定的公共场所分区疏散进行研究。进一步利用基于元胞自动机模型的大型公共场所人员疏散行为模拟仿真系统,在充分考虑公共场所中每个人员的状态、人员之间以及人员与周围环境的相互作用的前提下,对疏散分区的效果进行模拟;通过与未分区的模拟结果相比较,可以认为,分区疏散有助于人员快速疏散,大大缩短整体避难时间,而且基于移动路径搜索的分区更加切合实际。 相似文献