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Lee H. Macdonald Donald M. Anderson William E. Dietrich 《Environmental management》1997,21(6):851-863
2 /yr, respectively. Geomorphic evidence indicates that plantation agriculture during the 18th and 19th centuries did not cause
severe erosion. Since about 1950 there has been rapid growth in roads and development due to increasing tourism and second-home
development. Our field investigations identified the approximately 50 km of unpaved roads as the primary source of anthropogenic
sediment. Field measurements of the road network in two catchments led to the development of a vector-based GIS model to predict
road surface erosion and sediment delivery. We estimate that road erosion has caused at least a fourfold increase in island-wide
sediment yields and that current sedimentation rates are unprecedented. Paving the dirt roads and implementing standard sediment
control practices can greatly reduce current sediment yields and possible adverse effects on the marine ecosystems surrounding
St. John. 相似文献
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To overcome the shortcomings of phosphorus-containing compounds (PCCs, not widely used) in fire suppression, the dry water powder containing phosphoric acid was analyzed for a new fire suppressant (SiO2-P). First, the fine conditions (solid-to-liquid ratio, stirring time and stirring speed) were determined to prepare the new powder. The particle size distributions and XPS of SiO2-P powder were analyzed. The TG tests were conducted to study the decomposition of powder, and there was a major decomposition peak. Second, the extinguishing time of SiO2-P powder was tested, which showed that the SiO2-P powder containing phosphorus species could significantly improve the fire suppression ability. In addition, the kinetic parameters of powder decomposition reaction were determined by genetic algorithm based on TG results. Last, based on the decomposition products and kinetic parameters, the burning velocity and mass fraction of free radicals of CH4/air flame with SiO2-P powder addition were studied theoretically. The results indicated that SiO2-P powder had great ability of reducing the burning velocity and scavenging free radicals. Furthermore, the suppression effects were analyzed, which indicated that the cooperation of H2O and P suppression effect dominated the suppression mechanism and resulted in the good suppression efficiency. 相似文献
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Reza Kashiry Fard Reza Azar Afza Reza Teimouri 《Journal of Manufacturing Processes》2013,15(4):483-494
Dry wire electrical discharge machining (WEDM) is an environmentally friendly modification of the oil WEDM process in which liquid dielectric is replaced by a gaseous medium. In the present work, parametric analysis has been fulfilled while dry WEDM of Al–SiC metal matrix composite. Experiments were designed and conducted based on L27 Taguchi's orthogonal array to study the effect of pulse on time, pulse off time, gap voltage, discharge current, wire tension and wire feed on cutting velocity (CV) and surface roughness (SR). Firstly, a series of exploratory experiments has been conducted to identify appropriate gas and wire material based on the values of cutting velocity. After selection of best gas and best wire, they were used for later stage of experiments. Analysis of variances (ANOVA) has been performed to identify significant factors. In order to correlate relationship between process inputs and responses, an adaptive neuro-fuzzy inference system (ANFIS) has been employed to predict the process characteristics based on experimental observation. At the end, an artificial bee colony (ABC) algorithm has been associated with ANFIS models to maximize CV and minimize SR, simultaneously. Then the optimal solutions that obtained through ANFIS-ABC technique have been compared with numbers of confirmatory experiments. Results indicated that oxygen gas and brass wire guarantee superior cutting velocity. Also, according to ANOVA, pulse on time and discharge current were found to have significant effect on CV and SR. In modeling of CV and SR by ANFIS, it was resulted that the proposed method has superiority in prediction of them in the ranges of factors beyond the training condition. Also, association of ANFIS with ABC can find the optimal combination of process parameters accurately according to the confirmatory experiments. 相似文献
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Density functional theory (DFT) has been used to investigate the reaction pathways with steam reforming of glycerol under cold plasma conditions. Total energies, energy barriers, and reaction enthalpies at 298.15 K have been calculated at the GGA/PW91/DNP level. The calculation shows that, with the presence of steam, the energy barrier of glycerol conversion is reduced and the conversion from glycerol to H2 and CO is promoted under cold plasma conditions. The formation of syngas was through a multi-step pathway via the conversion of OHCH2CHOH, CH2OH, CH2O, HCO,·and CH3, while the recombination of H generated extra H2. The synthesis of hydrocarbons are from the recombination of·CH3,·CH2, and·CH, which could be primarily generated through glycerol dissociation. The structure of glycerol anion was also studied in this work, and it was less stable than the neutral molecule. The route for the formation of OHCH2CHOH·and CH2OH·from glycerol anion is thermodynamically favorable. 相似文献
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Observations of Atmospheric Nitrogen and Phosphorus Deposition During the Period of Algal Bloom Formation in Northern Lake Taihu,China 总被引:5,自引:1,他引:4
Cyanobacterial blooms in Lake Taihu occurred at the end of April 2007 and had crucial impacts on the livelihood of millions
of people living there. Excessive nutrients may promote bloom formation. Atmospheric nitrogen (N) and phosphorus (P) deposition
appears to play an important role in algal bloom formation. Bulk deposition and rain water samples were collected respectively
from May 1 to November 30, 2007, the period of optimal algal growth, to measure the bulk atmospheric deposition rate, wet
deposition rate, and dry deposition rate for total nitrogen (TN; i.e., all species of nitrogen), and total phosphorus (TP;
i.e., all species of phosphorus), in northern Lake Taihu, China. The trends of the bulk atmospheric deposition rate for TN
and the wet deposition rate for TN showed double peaks during the observation period and distinct influence with plum rains
and typhoons. Meanwhile, monthly bulk atmospheric deposition rates for TP showed little influence of annual precipitation.
However, excessive rain may lead to high atmospheric N and P deposition rates. In bulk deposition samples, the average percentage
of total dissolved nitrogen accounting for TN was 91.2% and changed little with time. However, the average percentage of total
dissolved phosphorus accounting for TP was 65.6% and changed substantially with time. Annual bulk atmospheric deposition rates
of TN and TP during 2007 in Lake Taihu were estimated to be 2,976 and 84 kg km−2 a−1, respectively. The results showed decreases of 34.4% and 78.7%, respectively, compared to 2002–2003. Annual bulk deposition
load of TN for Lake Taihu was estimated at 6,958 t a−1 in 2007 including 4,642 t a−1 of wet deposition, lower than the values obtained in 2002–2003. This may be due to measures taken to save energy and emission
control regulations in the Yangtze River Delta. Nevertheless, high atmospheric N and P deposition loads helped support cyanobacterial
blooms in northern Lake Taihu during summer and autumn, the period of favorable algal growth. 相似文献