排序方式: 共有4条查询结果,搜索用时 0 毫秒
1
1.
负载型固体超强酸催化剂上的烷基化反应 总被引:3,自引:0,他引:3
本文利用Pt/SO^2-4/ZrO2,Pt/WO3/ZrO2负载于大比表面Al2O3固体强酸催化剂,进行异丁烷和丁烯的烷基化反应。 相似文献
2.
Eight tertiary nonanols were synthesized via Grignard reaction and coupled by Friedel–Crafts alkylation with phenol to the corresponding nonylphenols. Six branched para-nonylphenols (NP) were obtained: 4-(3′-methyl-3′-octyl)phenol (33NP), 4-(2′-methyl-2′-octyl)phenol (22NP), 4-(2′,5′-dimethyl-2′-heptyl)phenol (252NP), 4-(2′,5′,5′-trimethyl-2′-hexyl)phenol (2552NP), 4-(2′,4′-dimethyl-2′-heptyl)phenol (242NP) and 4-(4′-ethyl-2′-methyl-2′-hexyl)phenol (4E22NP). Their structures were confirmed by GC–MS and NMR spectroscopy. These six isomers as well as the earlier synthesized 4-(3′,5′-dimethyl-3′-heptyl)phenol (353NP), 4-(3′,6′-dimethyl-3′-heptyl)phenol (363NP) and 4-(2′,6′-dimethyl-2′-heptyl)phenol (262NP) were compared with commercial NP mixtures purchased from Acros and Fluka by GC–MS (equipped with a 100 m polysiloxane column). The analyses revealed that all obtained isomers are occurring in different quantities in both commercial NP mixtures. 相似文献
3.
陈科 《湖南环境生物职业技术学院学报》2008,14(2):18-21
介绍苯和苯甲醇在环境友好型催化剂硫酸亚铈的催化下合成二苯甲烷,研究了催化剂用量、反应时间对该傅克反应的影响.实验结果表明,该催化剂具有良好的催化活性,实验过程简单,无腐蚀,无废水污染.表1,参4. 相似文献
4.
本项研究是以雪貂(Ferret)和旱獭(Woodchuck)作为实验动物模型,由于这两种动物的某些器官特征在解剖学上和生理学上与人类有其相似之处,试图通过雪貂和旱獭体内生物合成亚硝胺,说明人类暴露于化学致场物亚硝胺的另外一个来源是生物体内合成。同时,用烷基化学致癌物二甲基亚硝胺对旱獭进行DNA烷基化的研究,发现由于被旱獭肝炎病毒(WHV,WoodchuckHepatitisVirus)感染的旱獭,不仅体内易于合成亚硝胺,而且其肝脏组织DNA烷基化的水平高于对照组。以DNA烷基化反应产生的烷化核酸碱基作为生物标志(Riomarkers),对于胃癌高发区人群尿中的烷化核酸碱基进行定量测定,并与低发区相对照,显示两者之间有差异性。本项研究为从动物实验外推到人群的设想提供了启示,还提出了以生物标志作为建立分子流行病学的依据。 相似文献
1