能源富集区市域经济发展水平空间格局演变——基于晋陕蒙甘宁地区

采用熵权TOPSIS法对我国晋陕蒙甘宁这一典型能源富集区各地级以上城市的市域经济发展水平进行综合评价,进而使用马尔可夫转移概率分析方法和ESDA空间分析方法,探索该地区市域经济发展水平时空分异格局的演化特征,结果显示：（1）该地区的市域经济发展差距在波动中下降;（2）各等级城市在不同时期演化规律截然相反,随时间推移,除低等级之外的各等级城市均表现出较高的等级下降风险;（3）该地区城市的市域经济水平曾存在一定空间负相关,到2015年这种关系则不再显著;（4）该地区呈现以局部为核心区的格局,但西部地区明显趋冷;（5）市域经济系统整体处于耦合协调度较低的状态,发展不平衡、不协调的问题较突出。     

腐植酸中不同分子量组分与As(Ⅲ)的络合性能

采用超滤方法将腐植酸（HA）分成5个不同分子量组分,利用平衡透析法研究HA中不同分子量组分与As（III）的络合特征和作用机理,计算络合过程的条件分配系数、表观稳定常数.结果表明,腐植酸组分的分子量对HA与As（III）的络合过程有显著的影响,当分子量小于10kDa时,HA与As（III）络合能力明显强于其他条件.其中羧基和酚羟基在HA与砷络合中起重要作用,为主要络合位点.采用Scatchard分析和双位点配体模型对络合结果进行拟合,发现HA中不同分子量组分和As（III）的络合过程中均存在强和弱2种络合位点.     

Sulphate, Nitrogen and Base Cation Budgets at 21 Forested Catchments in Canada, the United States and Europe

To assess the concern over declining base cation levels in forest soils caused by acid deposition, input-output budgets (1990s average) for sulphate (SO₄), inorganic nitrogen (NO₃-N; NH₄-N), calcium (Ca), magnesium (Mg) and potassium (K) were synthesised for 21 forested catchments from 17 regions in Canada, the United States and Europe. Trend analysis was conducted on monthly ion concentrations in deposition and runoff when more than 9 years of data were available (14 regions, 17 sites). Annual average SO₄ deposition during the 1990s ranged between 7.3 and 28.4 kg ha⁻¹ per year, and inorganic nitrogen (N) deposition was between 2.8 and 13.8 kg ha⁻¹ per year, of which 41–67% was nitrate (NO₃-N). Over the period of record, SO₄ concentration in deposition decreased in 13/14 (13 out of 14 total) regions and SO₄ in runoff decreased at 14/17 catchments. In contrast, NO₃-N concentrations in deposition decreased in only 1/14 regions, while NH₄-N concentration patterns varied; increasing at 3/14 regions and decreasing at 2/14 regions. Nitrate concentrations in runoff decreased at 4/17 catchments and increased at only 1 site, whereas runoff levels of NH₄-N increased at 5/17 catchments. Decreasing trends in deposition were also recorded for Ca, Mg, and K at many of the catchments and on an equivalent basis, accounted for up to 131% (median 22%) of the decrease in acid anion deposition. Base cation concentrations in streams generally declined over time, with significant decreases in Ca, Mg and K occurring at 8, 9 and 7 of 17 sites respectively, which accounted for up to 133% (median 48%) of the decrease in acid anion concentration. Sulphate export exceeded input at 18/21 catchments, likely due to dry deposition and/or internal sources. The majority of N in deposition (31–100%; median 94%) was retained in the catchments, although there was a tendency for greater NO₃-N leaching at sites receiving higher (<7 kg ha^-1 per year) bulk inorganic N deposition. Mass balance calculations show that export of Ca and Mg in runoff exceeds input at all 21 catchments, but K export only exceeds input at 16/21 sites. Estimates of base cation weathering were available for 18 sites. When included in the mass balance calculation, Ca, Mg and K exports exceeded inputs at 14, 10 and 2 sites respectively. Annual Ca and Mg losses represent appreciable proportions of the current exchangeable soil Ca and Mg pools, although losses at some of the sites likely occur from weathering reactions beneath the rooting zone and there is considerable uncertainty associated with mineral weathering estimates. Critical loads for sulphur (S) and N, using a critical base cation to aluminium ratio of 10 in soil solution, are currently exceeded at 7 of the 18 sites with base cation weathering estimates. Despite reductions in SO₄ and H⁺ deposition, mass balance estimates indicate that acid deposition continues to acidify soils in many regions with losses of Ca and Mg of primary concern. The U.S. Government's right to retain a non-exclusive, royalty free licence in and to any copyright is acknowledged. The Canadian Crown reserves the right to retain a non-exclusive, royalty free licence in and to any copyright.     

贵阳地区基本地质环境和主要岩土工程问题综述

本文系笔者对贵阳地区主要地质环境和工程地质特点进行的初步总结,内容为贵阳地区主要岩土构成情况、分布范围及与之相应的岩土工程地质特点和主要的岩土工程地质问题的描述,旨在给同行提供宏观性的了解和方向性的参考。     

阳离子共聚物的反相悬浮聚合

采用反相悬浮聚合方法合成颗粒状的阳离子型高分子絮凝剂。选用丙烯酰胺(Am)和氯化[N,N,N-三甲基乙醇丙烯酸酯]盐(AQ)两种单体,研究反应体系的特征及影响分子量的基本因素,诸如温度、单体浓度、引发剂浓度、分散剂浓度、水相和油相的体积比(Vw/Vo)对分子量的影响。为了选择出最佳原料比,本文对两种单体的原料比进行了研究。实验中还发现亚硫酸钠是一种优良的缩短反应诱导期、加速反应进程的试剂。     

曲面零件在拉深过程中内皱时刻及影响因素

进一步推导了曲面零件悬空区上的应力分布及临界失稳公式。然后通过计算机编程 ,求解了临界失稳方程 ,得到了拉深系数、相对锥顶半径、相对圆角半径、材料相对厚度与临界失稳时刻间的关系曲线 ,并对曲线变化的规律进行了分析。     

基于AHP-MF模型的用户群节水指标体系研究

从分析影响用户群节水的因素及其构成关系入手,根据专家长期节水工作的经验,利用层次分析法对用户群节水指标进行优选,并提出全面的定量化和定性化的层次结构评价模式和总体评价方法.首先构建用户群节水的层次分析结构模型及判断矩阵,应用Matlab6.5计算出各判断矩阵的最大特征值及其特征向量,并检验判断矩阵的一致性,继而确定出各指标的权重;其次,应用Fuzzy统计的方法对陕西2006年度高校用户群的节水情况进行评价,并为节水工作提供建设性意见.     

膜生物反应器膜污染的水力学控制实验研究

叙述了膜污染是影响膜-生物反应器处理技术推广应用的关键因素，采用水动力学方法是控制膜污染的有效方法。在不同污泥浓度条件下。对不同曝气强度下膜污染的发展速率及其形成机理进行了试验研究，研究结果表明：对应于不同污泥浓度均存在一个经济曝气强度，其大小随污泥浓度升高呈线性增加，膜生物反应器在经济曝气强度条件下运行可控制膜污染的发展；并从理论上推导出一个临界污泥浓度，其值为5．15g／L。对应于临界污泥浓度，并且污泥絮体在膜面可形成比较稳定的动态膜，膜过滤压差上升的速率最慢，膜生物反应器在此临界污泥浓度条件下运行膜污染发展最为缓慢。     

城市环境系统的权重分配

本文将多目标二级决策法用于城市环境系统的权重分配，对城中环境系统各要素及各要素的表征参数进行客观自动赋权，克服了环境质量评价中权重分配的主观随意性。该方法物理意义清晰，算法简便，具有较好的应用价值。     

确定不同保证率下的中国酸沉降临界负荷

在进行中国酸沉降临界负荷区划时 ,通常以 1°× 1°(经纬度 )的网格为单位进行计算 ,难以反映网格内不同生态系统对酸沉降敏感性的差异 .为了便于决策者根据临界负荷确定酸沉降控制对策 ,也为了使 1°× 1°的结果更具代表性和实用性 ,本研究确定了 0 1°× 0 1°网格为单位计算的中国酸沉降临界负荷 ,并在此基础上通过引入保证率的概念 ,得到了一系列与一定的经济技术水平相适应的、允许有一定损失的 1°× 1°的中国酸沉降临界负荷图 .利用累积分布函数 ,本研究还确定了不同保证率下的中国酸沉降超临界负荷分布和各省、市、自治区的酸沉降临界负荷 .