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1.
以水为萃取剂,萃取分离乙醇和环己烷,得到乙醇水溶液和粗环己烷。粗环己煊经精馏提纯,得到纯度为99.91%的纯品;乙醇水溶液经分馏,CaO脱水后得无水乙醇,纯度达99.74%。 相似文献
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Portable Fuel Containers (PFCs) made for consumer use can, under unusual circumstances, develop a flammable atmosphere in the container headspace. In order to prevent an inadvertent ignition from causing flame propagation into this headspace and a subsequent explosion or flame jetting, PFC manufacturers are developing prototype Flame Mitigation Devices (FMDs) for installation in the PFC. A test method is described in this paper to determine if the installed FMD will indeed prevent flame entry into the PFC in a high-challenge flame propagation scenario. The method entails the use of a butane-air mixture ignited in a 5 cm diameter, 12 cm long tube attached to either the container neck or a spout on the container neck. Two concept FMD designs have successfully prevented repeated attempts at flame propagation into the PFC and have also produced encouraging results in tests for fuel flow restriction, duel dispensing nozzle friction, and prolonged fuel exposure. Versions of these tests are currently being promulgated in a draft ASTM standard on PFC FMDs. 相似文献
4.
污水处理厂消毒技术对抗生素抗性菌的强化去除 总被引:1,自引:1,他引:0
基于消毒技术对污水处理厂出水中总异养菌(total heterotrophic bacteria,HPC)及5种抗生素抗性菌(antibiotic resistant bacteria,ARB):氨苄霉素抗性菌(AMP)、红霉素抗性菌(ERY)、四环素抗性菌(TET)、卡那霉素抗性菌(KAN)、环丙沙星抗性菌(CIP)的去除情况研究,分析消毒技术对ARB的强化去除效果.结果表明,实际污水处理厂的紫外消毒对ARB去除率仅为18.2%~40.9%,且AMP含量最高;另外,消毒技术对ERY有选择性去除效果,对其他4种ARB无明显选择性去除效果(P0.05);最后结合次氯酸钠、臭氧、紫外消毒处理对COD、NH_4~+-N的去除效果,确定强化去除ARB的消毒方式中臭氧,次氯酸钠和紫外的最佳浓度和剂量依次为5.0 mg·L~(-1)、25.0 mg·L~(-1)和45.0 m J·cm~(-2),ARB去除率依次为45.5%~74.5%、66.1%~85.5%、68.6%~85.5%,另外次氯酸钠耦合紫外消毒强化去除ARB的效果更佳. 相似文献
5.
Organic flammable liquids and their mixtures, which possess high risk of combustion and explosion, are widely used as raw materials and solvents in chemical and pharmaceutical industries. Lower flammability limits (LFL) is one of the most important parameters to characterize the combustion and explosion hazards of combustible gases and liquid vapors. The LFL of various ternary organic mixtures consist of ketone (acetone and butanone), ester (ethyl acetate) and alcohol (ethanol and isopropanol) were tested at 25 °C and atmospheric pressure. The results showed that resulted LFL values of the experiment were always lower than those calculated by volume fraction weighting method when the volume fraction of alcohol was less than 20 vol% but more than 10 vol%. The co-existence of alcohol and ethyl acetate had synergistic effect on reducing the LFL values of ternary organic mixtures and thus increased their explosive risk. The mechanism of synergistic effect was analyzed, and the results showed that the OH· and H· radicals produced by the oxidation decomposition of alcohols and esters accelerated the oxidation process of ternary organic mixtures, which led to the decrease of experimental LFL values and thus corresponding increased of their explosive risk. This study would be expected to provide some guidance for designing or choosing safer and more suitable ternary organic mixtures prior to their applications for engineering. 相似文献
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WU Yu-qiong WANG Chong-gang WANG Yun ZHAO Yang CHEN Yi-xin ZUO Zheng-hong 《环境科学学报(英文版)》2007,19(9):1129-1135
It has been reported that there is an interaction between Benzo[a]pyrene (BaP), a widespread carcinogenic polycyclic aromatic hydrocarbon, and tributyltin (TBT), an organometal used as an antifouling biocide. This study was therefore designed to examine the potential in vivo influence of BaP, TBT and their mixture on splenic antioxidant defense systems of Sebastiscus marmoratus. The fish were exposed to water containing environmentally relevant concentrations of BaP, TBT and their mixture. Spleens were collected for biochemical analysis after exposure for 7, 25, 50 d and after recovery for 7, 20 d. Cotreatment with BaP and TBT for 7 d potentiated the induction of glutathione peroxidase (GPx) activity by BaP or TBT alone. The cotreatment for 25 and 50 d resulted in inhibition of GPx activity, which was similar to the effect of TBT. Splenic glutathione S-transferase (GST) activities were significantly elevated in S. marmoratus exposed to BaP starting from 7 d and remained high up to 25 d. However, no further activity change was found with prolonged exposure. Cotreatment of BaP and TBT primarily inhibited the GST activity, which was similar to the effect of TBT. Cotreatment with BaP and TBT for 25 or 50 d potentiated the depletion of GSH (glutathione) by BaP or TBT alone. MDA (malondialdehyde) contents in spleen of S. marmoratus were not significantly altered compared with the control during the test period. Spleen, as an immune organ, is sensitive to exposure of BaP or TBT. It should have an effective mechanism to counteract oxidative damage. Antioxidative defense systems in spleen of S. marmoratus should be considered as potential biomarkers. Short-term exposure of BaP or TBT could result in induction of antioxidant defense system. A significant decrease of these indices, such as GSH, GST, GPx might indicate more severe contamination. 相似文献
8.
Jan Bernd Barhorst Roland Kubiak 《Environmental science and pollution research international》2009,16(5):582-589
Background, aim and scope The use of sodium hypochlorite (HYP) in viticulture results in effluents which are contaminated with halogenated substances.
These disinfection by-products (DBPs) can be quantified as group parameter ‘adsorbable organic halogens’ (AOX) and have not
been determined in effluents of viticulture yet. The substances that are detected as AOX are unknown. The AOX can be composed
of harmless substances, but even toxic contaminants. Thus, it is impossible to assess ecological impacts. The aim of this
study is to determine the quantification of AOX and DBPs after the use of HYP. This will be helpful to reduce environmental
pollution by AOX.
Materials and methods The potential of HYP to generate AOX was determined in laboratory-scale experiments. Different model solutions were treated
with HYP according to disinfection processes in viticulture and conditions of AOX formation in effluents were simulated. AOX
were quantified using the flask-shaking method and identified DBPs were investigated by gas chromatography–mass spectrometry.
Results Treatment with HYP resulted in the formation of AOX. The percentage conversion of HYP to AOX was up to 11%. Most important
identified DBPs in viticulture are chloroform, dichloroacetic acid and trichloroacetaldehyde. In addition, the formation of
carbon tetrachloride (CT), 1,1,1-trichloropropanone, 2,4-dichlorobenzoic acid and 2-chloro-/2,4-dichlorophenylacetic acid
was investigated. It was demonstrated that reaction temperature, concentration of HYP and type of organic matter have important
influence on the formation of chlorinated DBPs.
Discussion The percentage conversion of HYP to AOX was similar to other published studies. Although a correlation of single compounds
and AOX is difficult, chloroform was the predominant AOX. Generation of the volatile chloroform should be avoided due to possible
adverse effects. The generation of dichloroacetic acid is of minor importance on account of biodegradation. Trichloroacetaldehyde
and 1,1,1-trichloropropanone are weak mutagens and their formation should be avoided.
Conclusions The generation of AOX and chlorinated DBPs can be minimised by reducing the concentrations of the organic materials in the
effluents. The removal of organic matter before disinfection results in a decreased formation of AOX. HYP is an effective
disinfectant; therefore, it should be used at low temperatures and concentrations to reduce the amount of AOX. If possible,
disinfection should be accomplished by the use of no chlorine-containing agents. By this means, negative influences of HYP
on the quality of wine can also be avoided.
Recommendations and perspectives Our results indicate that HYP has a high potential to form AOX in effluents of viticulture. The predominant by-products are
chloroform, dichloroacetic acid and trichloroacetaldehyde. In further research, wastewaters from a winery and the in- and
outflows of two sewage treatment plants were sampled during vintage and analysed. These results will be discussed in a following
paper. 相似文献
9.
F. Boukhoubza A. Jail F. Korchi L. Loukili Idrissi H. Hannache J.C. Duarte L. Hassani A. Nejmeddine 《Journal of environmental management》2009,91(1):124-132
The application of hypochlorite for the removal of soluble COD, phenolic and polyphenolic like compounds, and other organic compounds responsible for the olive mill wastewater (OOWW) colour has been experimentally studied. After the OOWW filtration on a sand column, the effluent was subjected to a fast liming under optimal conditions. Lime application reduced polyphenols, COD and SS contents to half of their initial values but an important blackening of the treated OOWW was observed, especially when adding high concentrations of lime (10% (W/V) and 15% (W/V)).A second stage of treatment was applied using calcium hypochlorite. In this stage, removal of the studied compounds reached as much as 95% at higher concentrations, and particularly the colouring of OOWW which is generally difficult to eliminate was greatly reduced. The OOWW hypochloration acted through coagulation–flocculation and a rapid oxidation of the organic matter proceeded from the first 5 min. The kinetic study of the degradation of the waste polluting compounds from liming showed that Ca(ClO)2 reacts similarly in the elimination of organic compounds, polyphenols, SS and colouration. The analysis of the organochloride compounds generated by the reaction between hypochlorite and the organic compounds showed that DDD, DDT and the heptachlor contents exceeded the values recommended by the International and European drinking water standards. 相似文献
10.