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491.
交联壳聚糖-CdS颗粒可见光催化脱色甲基橙研究 总被引:1,自引:0,他引:1
利用壳聚糖对金属离子的配位络合作用和吸附性能,模拟生物矿化仿生制备交联壳聚糖/CdS复合粒子。以甲基橙为处理对象,氙灯模拟可见光,研究了该复合材料对甲基橙的降解脱色性能。用Langmuir-Hinshelwood方程从动力学的角度,考察了不同催化剂浓度、甲基橙的初始浓度、反应体系的pH值、外加无机阴离子等对甲基橙降解脱色的影响。结果表明,该复合材料的吸附性能和光催化活性产生的协同作用能较有效促进甲基橙染料的脱色,在低质量浓度条件下可见光催化过程为假一级反应。光催化剂的最佳用量为1.5g/L,甲基橙降解的最佳pH为4.0。Cl-和Br-均对MO的光催化脱色起抑制作用,而NO3-的添加明显促进MO的光催化速率。 相似文献
492.
含钛高炉渣制光催化剂降解水中2,4-二氯酚的研究 总被引:1,自引:0,他引:1
以攀钢含钛高炉渣为原料制备了光催化剂,并将其用于降解水中2,4-二氯酚,研究了光催化剂投加量、光照强度、反应物浓度、反应时间对2,4-二氯酚降解率的影响。结果表明:高炉渣制光催化剂对2,4-二氯酚具有良好的光催化效果,在催化剂投加量为0.3g/L,光照时间为2h的条件下,浓度为50mg/L的2,4-二氯酚的降解率达到了77.1%。通过反应的动力学分析,确立出高炉渣制光催化剂对水中2,4-二氯酚的降解反应为一级反应。对2,4-二氯酚的光催化降解产物进行分析发现,苯环上的C—Cl键被光催化剂产生的羟自由基·OH氧化断裂,氯取代基成为游离Cl-存在于溶液中,2,4-二氯酚被·OH降解生成中间小分子有机产物,这些小分子有机物再进一步被光催化降解。 相似文献
493.
494.
苯并[a]芘(B[a]P)是国际公认的人类化学致癌物,在自然界中分布极广,卫生学中一般以它作为多环芳烃类致癌物的代表物.详细介绍了B[a]P的来源、理化性质、检测方法、毒性、致毒机理以及降解特性等方面最近的研究进展.展望了B[a]P今后重要的研究方向. 相似文献
495.
本文研究了厌氧方法驯化的活性污泥中筛选出的一株活力苯酚厌氧降解菌降解苯酚的最佳条件。结果为:在基础选择培养基中以1.0g(NH4)2SO4作为氮源并且在1 L培养基中加入1 mL微量元素储备液,调节培养基pH值为6.9-7.2,有利于C. albicans PDY-07降解苯酚。 相似文献
496.
497.
Degradation of chlorpyrifos in laboratory soil and its impact on soil microbial
functional diversity 总被引:2,自引:0,他引:2
Degradation of chlorpyrifos at different concentrations in soil and its impact on soil microbial functional diversity were investigated under laboratory conditions. The degradation half-lives of chlorpyrifos at levels of 4, 8, and 12 mg/kg in soil were calculated to be 14.3, 16.7, and 18.0 d, respectively. The Biolog study showed that average well color development (AWCD) in soils was significantly (P < 0.05) inhibited by chlorpyrifos within the first two weeks and thereafter recovered to the similar level as the control. A similar variation in the diversity indices (Simpson index 1/D and McIntosh index U) in chlorpyrifos-treated soils was observed, no significant difference in the Shannon-Wiener index H' was found in these soils. With increasing chlorpyrifos concentration, the half-lives of chlorpyrifos were significantly (P ≤ 0.05) extended and its inhibitory effects on soil microorganisms were aggravated. It is concluded that chlorpyrifos residues in soil had a temporary or short-term inhibitory effect on soil microbial functional diversity. 相似文献
498.
ITO/CdS/ZnO interface composite films were successfully prepared by subsequent electrodeposition of CdS and ZnO onto indium tin oxide (ITO) glass substrates. The obtained ITO/CdS/ZnO composite films were characterized with X-ray diffraction (XRD), scanning electron microscopy (SEM), and UV-Vis spectroscopy. The photocatalytic activity of ITO/CdS/ZnO composite films were investigated using methyl orange (MO) as a model organic compound under UV light irradiation. The influence of operating parameters on MO degradation including initial concentration of MO, pH value of solution, and inorganic anion species over the composite films were examined. A blue shift of absorption threshold was observed for the ITO/CdS/ZnO film in comparison with ITO/ZnO film. ITO/CdS/ZnO composite films prepared under specific conditions showed a higher photocatalytic activity than that of ITO/ZnO films. It was also found that the photocatalytic degradation of MO on the composite filing followed pseudo-first order kinetics. 相似文献
499.
水解(酸化)工艺预处理难降解有机废水应用技术分析 总被引:1,自引:0,他引:1
本文对水解(酸化)工艺进行了原理分析,论述了该工艺的优缺点,以及对后续工艺的影响.分析论述了该工艺对几种典型的难降解有机废水的降解机理.认为水解(酸化)作为难降解有机废水的预处理工艺具有很高的推广应用价值. 相似文献
500.
The current modified electro-Fenton system was designed to develop a more convenient and e cient undivided system for practical
wastewater treatment. The system adopted a cathode portion that employed magnetic stirring instead of common oxygen gas di usion
or gas sparging to supply oxygen gas for the electrolyte solution. Key factors influencing the cathode fabrication and activity
were investigated. The degradation of acid fuchsine with a self-made graphite-polytetrafluorethylene cathode was studied using a
spectrophotometer. It was found that the cathode generated hydrogen peroxide with high current e ciency and the hydrogen peroxide
yield of the cathode did not decay after 10 times reuse. With the Pt anode at a ferrous ion concentration of 0.5 mmol/L, a pH of 3, and
using magnetic stirring, dye decolorization could be rapidly accomplished but the destruction of benzene rings and intermediates was
fairly di cult. With a Fe anode, dye degradation was more complete. 相似文献