烟气中SO2/NOx同时吸收催化脱除的研究

根据同时脱硫脱硝的要求,对以ＣＵＯ为主要活性组分催化剂的制备和反应过程进行研究,活性测试的结果表明,催化剂的最佳活化温度和活化时间分别为４５０℃和２ｈ。当反应温度为４００℃,空间速度为２×１０＾４ｈ＾－１以及ＣｕＳＯ４／ＣｕＯ摩尔比和Ｃｕ／Ｓ分别保持在１．４６和０．８３以上时,ＳＯ２和ＮＯｘ的脱除率可达９０％以上。     

锅炉烟气脱硫技术发展综述

在调查研究的基础上，论述国内外烟道气脱硫技术的发展与前景，提出开发生产适合我国国情的烟气脱硫技术势在必行。还简要介绍了最为普遍的石灰／石灰石法脱硫基本原理。     

我国废铅蓄电池产生量与再生铅产能的讨论

废铅蓄电池是再生铅主要原料,铅蓄电池产量、进出口量、社会消费保有量,以及铅蓄电池消费使用领域与废铅蓄电池产生量有关。预测2015年废铅蓄电池产生量,并讨论我国再生铅产能规模,供再生铅产业结构调整与区域布局调整作参考。     

流化催化裂化装置湿法脱硫烟气中颗粒物现场监测的问题分析、对策及优化建议

针对流化催化裂化(FCC)装置湿法脱硫烟气中颗粒物浓度现场监测数据高于在线监测数据的问题,从颗粒物的定义和分类、监测标准及方法等角度分析了现场手工采样时滤筒法和滤膜法存在的问题.指出造成颗粒物现场监测数据高于在线监测数据的原因为:玻璃纤维滤筒被雾滴润湿后雾滴中的可溶性盐及烟气中的铵盐气溶胶均被截留;石英滤膜吸水后可有效...     

Reaction mechanism and metal ion transformation in photocatalytic ozonation of phenol and oxalic acid with Ag+/TiO2

Photocatalytic ozonation of phenol and oxalic acid （OA） was conducted with a Ag^＋/TiO2 catalyst and different pathways were found for the degradation of different compounds. Ag^＋ greatly promoted the photocatalytic degradation of contaminants due to its role as an electron scavenger. It also accelerated the removal rate of OA in ozonation and the simultaneous process for its complex reaction with oxalate. Phenol could be degraded both in direct ozonation and photolysis, but the TOC removal rates were much higher in the simultaneous processes due to the oxidation of hydroxyl radicals resulting from synergetic effects. The sequence of photo-illumination and ozone exposure in the combined process showed quite different effects in phenol degradation and TOC removal. The synergetic effects in different combined processes were found to be highly related to the properties of the target pollutants. The color change of the solution and TEM result confirmed that Ag＋ was easily reduced and deposited on the surface of Tit2 under photo-illumination, and dissolved again into solution in the presence of ozone. This simple cycle of enrichment and distribution of Ag^＋ can greatly benefit the design of advanced oxidation processes, in which the sequences of ozone and photo-illumination can be varied according to the needs for catalyst recycling and the different properties of pollutants.     

百万千瓦燃煤机组超低排放改造方案的研究

为确定国内某电厂1 000 MW燃煤机组超低排放的改造方案,对脱硝、脱硫及除尘系统传统改造技术路线进行研究。结合烟气脱硫、除尘一体化技术(SPC-3D)原理,给出该机组改造方案。研究结果表明:脱硝系统采用备用层增加催化剂,脱硫、除尘系统采用SPC-3D改造方案可达到超低排放的目标;与传统脱硫、除尘改造方案相比,SPC-3D技术具有改造工期短、投资及运行费用低等特点。     

UV-catalytic treatment of spent caustic from ethene plant with hydrogen peroxide and ozone oxidation

The performance of UV/H2O2, UV/O3 and UV/H2O2/O3 oxidation systems for treating spent caustic from an ethylene plant was investigated, in UV/H2O2 system, with the increase of H202 dosage, removal efficiencies of COD and the ratio of biochemical oxygen demand(BOD) to chemical oxygen demand(COD) of the effluent were increased and a better performance was obtained than the H2O2 system alone. In UV/H2O2 system, removal efficiency of COD reach 68% under the optimum condition, and BOD/COD ratio was significantly increased from 0.22 to 0.52. In UV/O3 system, with the increase of O3 dosage, removal efficiency of COD and BOD/COD ratio were increased, and a better performance was obtained than the O3 system alone. Under the optimum condition, removal efficiency of COD was 54%, and BOD/COD ratio was significantly increased from 0.22 to 0.48. In UV/H2O2/O3 system, COD removal efficiency was found to be 22.0% higher than UV/O3 system.     

燃煤锅炉的选择性催化还原烟气脱硝技术探讨

烟气脱硝是目前世界上最为常见的减少NO_x排放的方法,而燃煤锅炉的选择性催化还原烟气脱硝技术(SCR)的应用更为广泛。本文就从催化剂设计、喷氨量控制、实际应用案例三个方面入手,针对燃煤锅炉的选择性催化还原烟气脱硝技术展开实际的探讨。     

燃煤电厂锅炉烟气脱硫脱硝技术及展望

随着社会经济的发展,环境污染的情况日益严重,众所周知,在电厂燃煤中所排放的硫化物等都是造成大气污染的主要成分之一。中国是一个以煤炭为主要能源的国家,如何有效的控制燃煤电厂排放的SO2与NO3变得尤为重要。本文对燃煤电厂锅炉烟气脱硫脱硝技术的特点以及原理加以分析,并指出这项技术应用前景。