岷江水系河水与沉积物中稀土,稀有元素背景值及其特征初探

报告了岷江水系河水及沉积物中８种稀土元素（Ｌａ，Ｃｅ，Ｎｄ，Ｓｍ，Ｅｕ，Ｔｂ，Ｙｂ，Ｌｕ）及８种稀有元素（Ｒｂ，Ｃｓ，Ｓｒ，Ｂａ，Ｓｂ，Ｔｈ，Ｓｃ，Ｕ）的背景值及其特征，并对元素的排列顺序及元素间的相关关系进行了初步探索，还列出了１６种元素在原水同积物中的相关矩阵及相互间的相关回归方程。     

溶液吸收/分光光度法检测空气中偏二甲肼含量

GJB2373-95采用固体吸附/分光光度法监测空气中偏二甲肼,但是采集空气中偏二甲肼所用的SG-2固体吸附剂和采样管制作繁琐,分析步骤复杂,不适合连续监测。文章以单位自行研制的偏二甲肼动态配气系统配制已知浓度空气样品为测试环境,用标定过的美国Interscan气体检测仪实时监测其浓度为13.4×10-6～13.6×10-6,采用溶液吸收法采样并简化GJB2373-95标准方法的分析步骤。依据两种方法分别做出各自的标准曲线,并采用固体吸附法和溶液吸收法各采集两个平行样,样品采样体积分别为3.28L、3.31L和3.12L、3.14L,对应各自的标准曲线,计算出两组样品偏二甲肼含量分别为10.7×10-6、11.0×10-6和12.1×10-6、12.0×10-6。经传感器实时监测值作为第三方数据比对,结果表明溶液吸收/分光光度法监测结果准确,分析步骤简单、省时。     

Enhanced adsorption of Methylene Blue from aqueous solution by chitosan-g-poly （acrylic acid）/vermiculite hydrogel composites

A series of chitosan-g-poly (acrylic acid)/vermiculite hydrogel composites were synthesized and used as adsorbents for the investigation of the e ect of process parameters such as vermiculite content, pH of dye solution, contact time, initial concentration of dye solution, temperature, ionic strength and concentration of surfactant sodium dodecyl sulfate on the removal of Methylene Blue (MB) from aqueous solution. The results showed that the adsorption capacity for dye increased with increasing pH, contact time and initial dye concentration, but decreased with increasing temperature, ionic strength and sodium dodecyl sulfate concentration in the present of the surfactant. The adsorption kinetics of MB onto the hydrogel composite followed pseudo second-order kinetics and the adsorption equilibrium data obeyed Langmuir isotherm. By introducing 10 wt.% vermiculite into chitosan-g-poly (acrylic acid) polymeric network, the obtaining hydrogel composite showed the highest adsorption capacity for MB, and then could be regarded as a potential adsorbent for cationic dye removal in a wastewater treatment process.     

无铅焊料合金中重金属元素浸出行为的研究

选用Sn.3.5Ag-0.5Cu、Sn-3.5Ag、Sn-0.5Cu无铅焊料合金及它们与Cu的钎焊接头,研究了它们在典型的酸性、碱性和盐溶液中的重金属元素的浸出规律.结果表明,焊料合金中的主要浸出元素Sn在酸性或碱性溶液中的浸出量都不是太多,而在NaCl盐溶液中浸出量增大2个数量级.制备成钎焊接头后,在酸性环境中,Sn-3.5Ag和Sn.0.5Cu钎焊接头中Sn的浸出量增加1个数量级以上,而在NaOH碱性环境中.Sn-3.5Ag-0.5Cu钎焊接头中Sn的浸出量相对较高.该结果对电子垃圾填埋环境选择及相关决策提供了参考.     

Impacts of soil organic matter, pH and exogenous copper on sorption behavior of norfloxacin in three soils

Norfloxacin (Nor) sorption and the factors (soil organic matter (SOM), pH, and exogenous copper (Cu) influencing the sorption were investigated in a black soil (soil B), a fluvo-aquic soil (soil F), and a red soil (soil R). With increasing of Nor concentrations, sorption amount of norfloxacin increased in both the bulk soils and their SOM-removed soils, but the sorption capacity in SOM-removed soils was higher than that of their corresponding bulk soils, indicating that the process of norfloxacin sorption in soil was influenced by the soil properties including SOM. The sorption data in all bulk soils and SOM-removed soils were fitted to Freundlich and Langmuir models. The correlation coefficients suggested that the experimental data fitted better to Freundlich equation than to Langmuir equation. Furthermore, the data from soil F and SOM-removed F could not be described by Langmuir equation. The norfloxacin sorption amount decreased in soil B and soil F, whereas it increased in soil R as solution pH increased. The maximum KD and KOC were achieved in soil R when the equilibrium solution pH was 6. And the norfloxacin sorption was also influenced by the exogenous Cu2+ ions, which depended on the soil types and Cu2+ concentrations. With increasing of Cu2+ concentrations in solution, generally, sorption amount, KD and KOC for norfloxacin in soils increased and were up to a peak at 100 mg/L Cu2+, and then the sorption amount decreased regardless of norfloxacin levels.     

基于空位溶液与DA理论的多组分气体吸附方法及验证*

为准确预测煤层气中多组分气体的吸附性能,将空位溶液与Dubinbin-Astakhov（DA）理论相结合,提出1种适用于煤层气吸附系统的多组分混合吸附模型。在模型中,吸附体系被视为气体与假设的“空位溶质”的多元混合物,吸附体系视为气相和吸附相空位溶质之间的平衡。结果表明:根据单组分气体吸附等温线,采用D-A方程计算分析了生成二元（吸附质+空位）混合物中纯组分气体的活度系数,并优化吸附参数;模型能够根据在单一温度下收集的纯组分吸附数据预测不同温度下的多组分气体吸附;模型计算结果与实测结果吻合良好,误差在10%以内,充分说明模型是切实可靠的。     

Biosorption of cesium（Ⅰ） from aqueous solution by a novel exopolymers secreted from Pseudomonas fluorescens C-2： Equilibrium and kinetic studies

The biosorption characteristics of Cs(I) ions from aqueous solution using exopolymers (PFC02) produced from Pseudomonas fluorescens C-2 were investigated as a function of pH, biosorbent dosage, contact time and initial concentration. pH played a major role in the adsorption process, and the optimum pH for the removal of Cs(I) was 8.0. Langmuir, Freundlich and Dubinin-Radushkevich (D-R) models were applied to describe the biosorption isotherm of the Cs(I) ions by PFC02. The Lagergren first-order, pseudo second-order kinetic and intraparticle diffusion models were used to test the kinetic data. Langmuir model and D-R model fitted the equilibrium data better than the Freundlich isotherm. The monolayer adsorption capacities of PFC02 as obtained from Langmuir isotherm at 25°C was found to be 32.63 mg/g. From the D-R isotherm model, the mean free energy was calculated as 26.73 kJ/mol, indicating that the biosorption of cesium was chemisorption. The biosorption process was rapid, and the kinetic rates were best fitted to the pseudo second-order model, which indicated the biosorption process operated through chemisorption mechanism. FT-IR analysis of PFC02 showed the possible functional groups responsible for cesium adsorption were hydroxyl, carboxyl, carbonyl and sulphonate groups. SEM analysis showed the porous structure of the material while EDX analysis confirmed the adsorption of Cs(I) on PFC02. Cesium adsorbed onto the PFC02 could be desorbed efficiently using 1 mol/L HNO3, and the enrichment factor was 50.0. Furthermore, PFC02 could be reused five times with only about 8.25% regeneration loss. The developed method was successfully utilized for the removal of Cs(I) ions from aqueous solution.     

Material conversion from paper sludge ash in NaOH solution to synthesize adsorbent for removal of Pb^2＋, NH^4＋ and PO4^3- from aqueous solution

Material conversion from paper sludge ash (PSA) in NaOH solution was attempted to synthesize the adsorbent for removal of inorganic pollutants, such as Pb2+, NH4 + and PO4 3?? from aqueous solution. PSA of 0.5 g was added into 10 mL of 3 mol/L NaOH solution, and then heated at 80, 120, and 160°C for 6–48 hr to obtain the product. PSA mainly composed of two crystalline phases, gehlenite (Ca2Al2SiO7) and anorthite (CaAl2Si2O8), and amorphous phase. Hydroxysodalite (Na6Al6Si6O24 8H2O) was formed at 80°C, and anorthite dissolved, whereas gehlenite remained una ected. Katoite (Ca3Al2SiO4(OH)8) was formed over 120°C, and hydroxycancrinite (Na8(OH)2Al6Si6O24 2H2O) was formed at 160°C, due to the dissolution of both gehlenite and anorthite. Specific surface areas of the products were almost same and were higher than that of raw ash. Cation exchange capacities (CECs) of the products were also higher than that of raw ash, and CEC obtained at lower temperature was higher. Removal abilities of products for Pb2+, NH4 +, and PO4 3?? were higher than that of raw ash.With increasing reaction temperature, the removal e ciencies of Pb2+ and NH4 + decreased due to the decrease of CEC of the product, while removal e ciency for PO4 3?? was almost same. The concentrations of Si and Al in the solution and the crystalline phases in the solid during the reaction explain the formation of the product phases at each temperature.     

恒能量同步荧光光谱法测定水体中多环芳烃

建立了胶束溶液中多环芳烃混合物同时测定的恒能量同步荧光分析法,方法简便快速,无需对混合物进行分离,就可实现11种组分的同时鉴别和定量测定,方法的检出限在1.3×10-11～4×10-9g/mL,标准偏差为1.03～1.73,方法应用于分析河水样、污水样中的多环芳烃的效果良好,回收率分别为77.88%～120.13%、6...