铝阳极电凝聚处理活性红241动力学分析

在一个序批式反应器中,以铝作阳极、不锈钢作阴极,考察了电流密度、初始pH值、电解质浓度及种类、温度、染料浓度因素对电凝聚处理活性红241动力学过程的影响。结果表明,电凝聚处理活性红241遵循均一级动力学方程;电流强度、染料浓度、电解液初始pH值、氯化钠电解质浓度、温度对染料溶液脱色速率常数的影响显著,而硫酸钠电解质浓度则影响不明显;在电凝聚处理过程中,主要作用机理是以铝离子的单核水解产物与染料络合作用占主导地位。     

The role of off-path glances: A quantitative analysis of rear-end conflicts involving Chinese professional truck drivers as the striking partners

Introduction: Rear-end crashes are one of the most frequent crash types in China, leading to significant economic and societal losses. The development of active safety systems – such as Automatic Emergency Braking System (AEBS) – could avoid or mitigate the consequences of these crashes in Chinese traffic situations. However, a clear understanding of the crash causation mechanisms is necessary for the design of these systems. Method: Manually coded variables were extracted from a naturalistic driving study conducted with commercial vehicles in Shanghai. Quantitative analyses of rear-end crashes and near crashes (CNC) were conducted to assess the prevalence, duration, and location of drivers’ off-path glances, the influence of lead vehicle brake lights on drivers’ last off-path glance, and driver brake onset, and the influence of off-path glances and kinematic criticality on drivers’ response to conflicts. Results: The results indicate that the Chinese truck drivers in our study rarely engage in distracting activities involving a phone or other handheld objects while driving. Instead, they direct their off-path glances mainly toward the mirrors, and the duration of off-path glances leading to critical situations are shorter compared to earlier analyses performed in Western countries. The drivers also often keep small margins. Conclusions: Overall, the combination of short time headway with off-path glances directed toward the mirror originates visual mismatches which, associated to a rapid change in the kinematic situation, cause the occurrence of rear-end CNC. When drivers look back toward the road after an off-path glance, a fast response seems to be triggered by lower values of looming compared to previous studies, possibly because of the short time headways. Practical Application: The results have practical implications for the development of driver models, for the design of active safety systems and automated driving, and for the design of campaigns promoting safe driving.     

紫外光度法测定硝酸盐氮有关问题的探讨

试验了水样预处理过程中所加氢氧化铝悬浮液的数量,以加１ｍｌ,并作了以活性炭代替树酯的试验,结果表明对测定结果的精密度和准确度均无影响。简化了操作手续,节省了时间。     

土壤中活性铝的流动注射分析

研究了ECR-CTMAB体系测定土壤中活性铝的流动注射分析。结果表明,该方法具有快速、灵敏的特点,进样频率为60个样/时,检出限为0.05μg/ml。用不同提取液提取各地区土壤中活性铝并进行了测定。     

A new coal pillars design method in order to enhance safety of the retreat mining in room and pillar mines

Most of the proposed methods for coal pillar design determine pillar dimensions using pillar load estimation only through the tributary area theory. Designing pillar based on these methods is not appropriate in room and pillar mines with pillar recovery because retreat mining and gob creation generate abutment loads. Neglecting abutment loads in design stage may lead to pillar failure and destructive effects during retreat mining. Thus proper pillar design has a remarkable effect on mining safety. In this paper, a step-by-step method is presented to design pillars with square shape in room and pillar mines with regard to existing pillars in the active mining zone (AMZ) and estimating abutment loads according to experimental equations. A decrease in pillar failure risk during retreat mining is the most significant benefit of this method. This method has been applied to determine optimum pillar dimensions in the main panel of Tabas Central Mine (TCM), located in the mid-eastern part of Iran. Obtained results show the abutment loads account for 27% of the total loads applied on pillars in AMZ in this panel. Pillar width, based on this method, is also obtained 11.6 m.     

变光焊接护目镜光电响应特性研究

为促进变光焊接护目镜新技术新产品的应用和发展 ,为制定该产品专业标准提供依据 ,通过对焊接弧光特性、可见光特性、焊工盲目引弧过程、焊工闪光盲、变光护目镜响应时间和保持时间等的分析和研究 ,提出了变光焊接护目镜响应时间和保持时间应该根据焊工引弧时眼睛最大允许照射量和允许闪光盲时间来确定 ,并进一步提出了变光焊接护目镜响应时间和保持时间的定义、指标值 ,以及测试系统设计要求     

活性艳红水溶液的光助还原脱色反应机理研究

基于紫外辐照/硼氢化钾/亚硫酸氢钠(UV/KBH4/NaHSO)3体系下对活性艳红X-3B进行还原脱色反应,重点探讨了该体系下还原降解活性艳红X-3B的反应机理,考察了硼氢化钾和亚硫酸氢钠的摩尔比(B/S)、辐射光强对其反应机理的影响。结果发现,UV/KBH4/NaHSO3处理染液具有明显协同作用,初步推测光助硼氢化钾和亚硫酸氢钠还原活性艳红X-3B的脱色反应是SO2-参与的自由基反应;脱色反应的B/S最佳摩尔比为1:30;增加辐射光的强度对染液的还原脱色反应过程具有明显的促进作用。     

One-pot synthesis of Fe/Cu-SSZ-13 catalyst and its highly efficient performance for the selective catalytic reduction of nitrogen oxide with ammonia

Series of Fe/Cu-SSZ-13 catalysts with different Fe loading content were synthesized by simple one-pot strategy. The obtained catalysts were subjected to selective catalytic reduction (SCR) of NO_x with NH₃ and were characterized by various techniques. The results show that Fe_0.63/Cu_1.50-SSZ-13 catalyst with proper Fe content exhibits excellent catalytic activity with widest operation temperature window from 160 to 580°C, excellent hydrothermal stability as well as good resistance to sulfur poisoning when compared with Cu-SSZ-13, signifying its great potential for practical applications. Further characterizations reveal that the synthesized Fe/Cu-SSZ-13 catalysts present typical chabazite (CHA) structure with good crystallinity, while isolated Cu²⁺ and monomeric Fe³⁺ are revealed as the predominant copper and iron species. At low temperatures, isolated Cu²⁺ species act as primary active sites for SCR reaction, while monomeric Fe³⁺ species provide sufficient active sites for sustain the SCR activity at high temperature. Moreover, Fe over doping would lead to the damage of zeolite structure, destruction of isolated Cu²⁺ site, as well as the formation of highly oxidizing Fe₂O₃, thus causing deterioration of catalytic performances.     

Active moss biomonitoring of trace elements with Sphagnum girgensohnii moss bags in relation to atmospheric bulk deposition in Belgrade, Serbia

Active biomonitoring with wet and dry moss bags was used to examine trace element atmospheric deposition in the urban area of Belgrade. The element accumulation capability of Sphagnum girgensohnii Russow was tested in relation to atmospheric bulk deposition. Moss bags were mounted for five 3-month periods (July 2005-October 2006) at three representative urban sites. For the same period monthly bulk atmospheric deposition samples were collected. The concentrations of Al, V, Cr, Mn, Fe, Ni, Cu, Zn, As, Cd, and Pb were determined by instrumental neutron activation analyses and atomic absorption spectrometry. Significant accumulation of most elements occurred in the exposed moss bags compared with the initial moss content. High correlations between the elements in moss and bulk deposits were found for V, Cu, As, and Ni. The enrichment factors of the elements for both types of monitor followed the same pattern at the corresponding sites.     

活性炭负载TiO2光催化杀菌研究

研究了溶胶-凝胶法制备活性炭颗粒负载TiO2的光催化杀菌作用,探讨了光催化剂的最佳制备条件。实验结果表明,光催化杀菌效果明显好于单独紫外光的杀菌效果,当钛酸丁脂与无水乙醇比例为1:8制备TiO2溶胶,活性炭颗粒浸涂凝胶一次、在450℃煅烧2h,20min的杀菌率可达88%,在溶胶中掺杂Fe3+的杀菌率可达到95%,提高了活性炭负载TiO2的光催化活性。