Cr(Ⅵ)在Fe(Ⅲ)-柠檬酸盐体系中紫外光还原研究

研究了在紫外光照射下,Fe(Ⅲ)-柠檬酸盐溶液对Cr(Ⅵ)的光还原反应.同时,考察了溶液pH值、Fe(Ⅲ)浓度、柠檬酸盐浓度、Cr(Ⅵ)初始浓度对光还原效率的影响,并分析了光还原反应的动力学.研究结果表明,Fe(Ⅲ)-柠檬酸盐体系能光还原Cr(Ⅵ),在pH为2.0～6.0的范围内,Cr(Ⅵ)的还原率随着溶液初始pH值的降低而增大.当pH值为2.0、Fe(Ⅲ)浓度为10μmol·L-1、柠檬酸盐浓度为250μmol·L-1及Cr(Ⅵ)初始浓度为19.2μmol·L-1时,光照反应8min后Cr(Ⅵ)的最大还原率达到100%,但当pH值增加到6.0时,Cr(Ⅵ)的最大还原率下降到19%;当Cr(Ⅵ)的初始浓度在9.6～96.0μmol·L-1的范围内时,Cr(Ⅵ)光还原反应的初始速率随着Fe(Ⅲ)、柠檬酸盐(cit3)、Cr(Ⅵ)初始-浓度的增加而增加.表观动力学方程为:-dCCr(Ⅵ)/dt=0.1019[Cr(Ⅵ)]0.[Fe(Ⅲ)]0.[cit3]0..536-25     

Comparison of dynamic adsorption/desorption characteristics of toluene on different porous materials

Four different types of adsorbents, SBA-15, MCM-41, NaY and SiO₂, were used to study the dynamic adsorption/desorption of toluene. To further investigate the influence of pore structure on its adsorption performance, two SBA-15 samples with different microspores were also selected. It is shown that microporous material NaY has the largest adsorption capacity of 0.2873 mL/g, and the amorphous SiO₂ exhibits the least capacity of 0.1003 mL/g. MCM-41 also shows a lower break through capacity in spite of the relatively small pore diameter, because it can not provide the necessary small geometric confinement for the tiny adsorbates. However, the mesoporous SBA-15 silica with certain micropore volume shows relatively higher adsorption capacity than that of MCM-41 silica. The presence of micropores directly leads to an increase in the dynamic adsorption capacity of toluene. Although NaY has the highest adsorption capacity for toluene, its complete desorption temperature for toluene is high (>350℃), which limits its wide application. On the contrary, mesoporous silica materials exhibits a good desorption performance for volatile organic compounds at lower temperatures. Among these materials mesoporous SBA-15 samples, with a larger amount micropores and a lower desorption temperature, are a potentially interesting adsorbent for the removal of volatile organic compounds. This behavior should been related with the best synergetic effect of mesopores and micropores.     

HPLC-ICPMS对环境样品中Cr(Ⅲ)和Cr(Ⅵ)分析研究

采用动态反应池(Dynamic Reaction Cell,DRC)消除环境样品中碳和氯对铬ICP-MS测定的干扰,实验结果表明O2比CH4能更加有效地消除基体干扰,52Cr更适宜作为铬形态分析的同位素。在优化的DRC条件下2.284μg/L、4.886μg/L和10.579μg/L 3个加标浓度下均具有理想的回收率。进一步采用Pecosphere C8分析柱(3×3),深入研究了流动相组成、pH值及流速对铬形态分离的影响,在1.0 mmol/L四丁基氢氧化铵(TBAH)+0.5 mmol/L乙二胺四乙酸二钠(EDTA)+1%甲醇流动相组成,pH 6.9和流速1.2 mL/min的色谱条件下可以得到最为理想的分离效果,在10～100μg/L标准浓度范围内,Cr(Ⅲ)和Cr(Ⅵ)的线性相关系数均大于0.999 7,建立的方法对Cr(Ⅲ)和Cr(Ⅵ)具有较好的重复性。最后尝试性地对模拟填埋场和地下水环境下市政污泥在脱水、干化和热解过程中铬形态的环境迁移性进行了研究,为更加准确评价铬元素对生态环境的潜在危害提供参考依据。     

A new multiple-risk map approach to solve process plant layout considering safety and economic aspects

Mathematical models used to optimize the process plant layout (PPL) with risk reduction have four primary objectives, which are related to the minimization of land, pumping (pipe system), protection system devices, and risk costs. Moreover, these models are of two types: continuous plane models (CPM) and grid-based models (GBM); however, the nonconvexity of the CPM models makes difficult to achieve the global optimum, because it is formulated as Mixed-Integer Nonlinear Programming (MINLP). Thus, the risk map approach has been implemented with the grid-based models to solve problems of process plant layout focused on finding the best possible solution. However, these risk map formulations present important limitations, mainly related with the use of protection devices and the occupied area. Therefore, a new GBM-MILP formulation is proposed to optimize the selection of protection devices and minimize the occupied area. The risk is reduced through the investment on safety devices instead of considering the increase of separation distances. The proposed model was used to solve the layout problem of an ethylene oxide process, and the results was compared with a process layout reported in the literature. The results show that the model can provide the best possible solution; however, the time spent in the calculation is considerably greater than that reported for continuous plane models. Finally, the model can be used by decision-makers to evaluate different layout options for several explosion scenarios, during the early stages of the plant design.     

矿井主风机不停风倒机系统最优控制研究

为解决矿井停机切换主要通风机过程中引起的井下风量波动很大,易造成瓦斯积聚等引发的安全问题,提出1种基于智能控制的主通风机稳风切换系统.建立动态风机倒机数学模型,提出基于改进粒子群算法优化的模糊自适应PID的控制方法,并应用MATLAB进行仿真实验,结果表明:控制方法控制效果明显,在系统运行的120 s内,井下风量波动始...     

基于SD的装配式建筑施工安全监管演化博弈研究

为了有效减少装配式建筑工程施工安全事故,考虑政府监管部门与施工单位之间存在信息不对称,基于有限理性条件下双方互动关系构建装配式建筑施工安全动态监管演化博弈模型,并分析其稳定策略.采用系统动力学(SD)方法仿真分析在动态监管策略及外部变量调整条件下的演化博弈过程.研究结果表明:政府强弱监管的成本差、施工单位加强安全管理的...     

人体动力特性振动台试验研究

随着社会发展和经济水平的提高,人们对于生产、生活的环境质量要求也不断提升,因而环境振动已越来越多的引起了社会的关注,为了研究环境振动对人体的影响,需要了解人体动力特性和在振动环境下的响应。对20名受试者以站、坐、躺姿进行了水平两向输入白噪声的振动台试验,测得人体头、肩、腹、上肢、下肢五个部位的振动响应,通过对人体各部分振动频率与身高、体重、年龄的关系分析,给出了人体频率分布规律。     

拟动力试验方法的发展与展望

结构抗震试验是模拟地震作用、分析掌握地震机制及结构抗震性能的有效方法。对拟动力试验技术的研究现状和进展进行了概括总结,分析探讨了拟动力试验特别是基于子结构技术试验的逐步积分方法、加载控制方式、误差分析、拟动力子结构试验、实时子结构试验、远程协同拟动力试验、混合子结构拟动力试验等关键技术,对比分析了拟动力试验技术与其他试验方法的差异,以及拟动力试验技术中基于子结构技术各试验方法间的区别和特点,并进一步阐述了各种拟动力试验的现存问题、应用前景,指出了需要进一步研究的方向。     

地震作用下地铁车站结构的动力变形响应研究

研究地铁车站结构在地震作用下的变形,对地铁的建设和安全运营有着重要的现实意义。本文进行了北京地区土层中典型地铁车站结构的振动台试验,并使用FLAC2D对试验进行模拟分析,得到了在地震作用下地铁车站结构的变形响应规律。结果表明:地铁结构的变形峰值随地震强度的增加而增加;结构中柱的峰值应变和峰值挠度曲线曲率,两端大、中间小;侧墙峰值挠度曲线的各点曲率为常数,这是因为侧墙与顶底板组成的箱形结构整体刚度大,难以发生破坏;中柱底端应变呈正负循环变化,侧墙的应变曲线与受冲击荷载的变形曲线相似。     

均质土坝非平稳随机地震反应分析

考虑地震荷载的随机性及强度、频率的非平稳性,基于作者提出的适用于非平稳随机过程的一般随机地震动模型,采用虚拟激励法,建立了非平稳随机地震反应分析方法,并将其应用于某实际均质土坝动力分析中。土石坝及坝基体系采用整体有限元离散,坝体和坝基材料的动力非线性性能以等效线性化方法考虑。首先,基于目标加速度时程的强度和能量信息,确定了作为输入的加速度时—频演变功率谱密度;其次,比较了确定性时程动力分析和非平稳随机分析的结果,探讨了频率非平稳随机地震激励下的土石坝地震反应特性;最后,比较了2种不同坝基条件下的土石坝非平稳随机地震反应,探讨了频率非平稳随机激励下的土石—坝基动力相互作用。分析结果表明:地震动的频率非平稳性对土石坝动力反应有一定影响;坝体—坝基动力相互作用在地震过程中的不同阶段表现有所不同,主震阶段的相互作用显著。