Exploring the linkages between river water chemistry and watershed characteristics using GIS-based catchment and locality analyses

A typology of land characteristics for the Humber catchment in central/eastern England is identified in relation to land use, hydrology and demographic, topographic and geological characteristics, using GIS and statistical analyses. Empirical relationships between land characteristics and water quality were examined in relation to the spatial variability in water quality across the Humber catchment. Analyses of relationships between land characteristics and water quality were undertaken at two hierarchical scales: (1) individual catchments and (2) localities of 10 km radius draining to each sampling site. The importance of urban and agricultural sources was identified, together with a hydrological component linked to dilution of point source inputs and mobilisation of specific sediment-associated contaminants in higher-energy (higher-flow) environments. High-solubility (dissolved) chemical determinands (such as B, Cl and SO₄), which undergo conservative transport through the river network, show the strongest linkages with land characteristics at the catchment scale. Cr, Zn and Ca show stronger correlations with land characteristics at the locality rather than the catchment scale, indicating that the concentrations of these determinands are more closely linked to the availability of localised sources. This work provides a starting point for investigating how changes in land use and management of drainage basins might impact river water quality at the regional scale and fluxes to the coastal zone, by providing a mechanism for examining linkages between regional-scale land characteristics and river water quality. The next step requires development of the approach within a more rigorous statistical framework and the extension of the regional analysis within a wider national and international context. Electronic Publication     

Nuclear Wastes in the Arctic Ocean. the Consequences of Past Dumping and Opportunities for Future Prevention

The view is expressed that the assessment of disposal of nuclear waste in the ocean (specifically the Arctic and Kara Seas) is critical to understanding Arctic pollution. Much needs to be done in deciding what we should do, even though many wastes are long-standing and persistent. in 1993, disclosures about Russian dumping of submarine nuclear reactors, nuclear fuel, and other radioactive wastes into the Arctic Ocean brought this region and its problems into the world spotlight and raised public concerns about the resulting health and environmental risks. As a result of this concern, the Congressional Office of Technology Assessment published a 1995 study, Nuclear Wastes in the Arctic (US Congress Office of Technology Assessment, 1995). This paper summarises and updates that study.     

Short-term effects of sucralose on Calanus finmarchicus and Calanus glacialis in Disko Bay,Greenland

The potential effects of sucralose on the Arctic copepods Calanus finmarchicus and Calanus glacialis were studied in Disko Bay, Greenland. Sucralose is a non-calorie sweetener and chlorine derivate of sucrose containing three chlorine atoms. Scandinavian screening studies of sucralose in 2007, revealed sucralose in all effluent samples. To investigate whether sucralose is harmful to the Arctic aquatic ecosystems, possible short-term effects were investigated on egg production, hatching rate, food intake and mortality of two species of Arctic copepods. The copepods were exposed to six different concentrations (0–50,000 ng · L^?1) of sucralose, which spans the range of concentrations found in the screening studies. Exposure led to no mortality among the copepods. Food intake by C. glacialis increased with increasing concentrations of sucralose. In C. finmarchicus, food intake did not differ with increasing concentrations. No effect of sucralose was observed on egg production of C. finmarchicus. Despite increased food intake with increasing concentrations of sucralose, C. glacialis did not increase its egg production. The results show that both species responded weakly to sucralose, but with C. glacialis being possibly slightly more sensitive to sucralose than C. finmarchicus.     

Biological effects of water soluble fraction of crude oil on the Arctic sea ice amphipod Gammarus wilkitzkii

With increasing petroleum related activity in the Barents Sea and the subsequent risk of accidents, there is a demand for knowledge about the effect of oil pollution in Arctic ecosystems. In the present study, the sea ice amphipod Gammarus wilkitzkii was exposed to a water soluble fraction (WSF) of oil in two experiments, using a rock column system. First, three groups of adult females were exposed for 36 days for control (n=9), low dose (n=10) (initial and final oil concentration: 14, 115 and 120 μ g/l) and high dose (n=10) (initial and final oil concentration: 78, 764 and 395 μ g/l). Total oxyradical scavenging capacity (TOSC), malondialdehyde (MDA), catalase activity (CAT), respiration rate and mortality were measured. In the second experiment, moulting rate was measured in immature individuals of two groups, control (n=10) and exposed (n = 20), over 113 days. No mortality was observed in either of the experiments. There was a dose-related significant increase in respiration rate (40.69 (±22.82), 55.63 (±20.98), 94.57 (±22.80)) mg O₂ h^?1g ww^?1 in control, low dose and high dose, respectively. A higher MDA level was detected in the low dose group (25.04 (±6.00) nmol g^?1 of tissue) compared to both control (20.44 (±2.62) nmol g^?1 of tissue) and high dose groups (20.93 (±4.79) nmol g^?1 of tissue). Likewise, the low dose group had the highest value of TOSC towards hydroxyl (727.74 (±475.58), 1157.58 (±278.62), 1067.30 (±369.22) TOSC unit value mg^?1 of protein for control, low and high dose, respectively). Although no difference in the catalase activity between control and exposed groups was detected, higher activity was measured at 0 °C (average: 248 μ mol^?1 min^?1 mg^?1 of protein) than at the standard temperature for catalase measurement of 25 °C (average: 140 μ mol^?1 min^?1 mg^?1 of protein), indicating a need to optimise the standard operational procedure when working with Arctic organisms. No effect of WSF exposure on moulting rate was detected. In conclusion, little mortality was observed during the experiments, indicating some degree of tolerance levels. However, the biomarker results indicated sub-lethal effects in G. wilkitzkii after exposure to WSF.     

Histology of Sculpin spp. in east Greenland. I. Histological measures

There is inadequate morphological nomenclature and definition of organ pathology when using wild fish in biomonitoring of environmental pollution. The aim of this investigation was to provide a guide that assesses histology of Shorthorn (Myoxocephalus scorpius) and Fourhorn (Myoxocephalus quadricornis) sculpins obtained from a study using these two fish species as bioindicator organisms to evaluate environmental impact attributed to a dumpsite located in East Greenland. Specific histopathological lesions were quantified on the basis of Bernet et al. and all lesions were photomicrographed, evaluated, and placed into specific categories of five reaction patterns. These were circulatory disturbances, regressive changes, progressive alterations, inflammation, and tumors based on anatomical location, type, and severity. This method is postulated to enable an objective assessment of the histological integrity of fish gills and liver; thus, making it possible to compare sculpin pathology and reaction patterns at different locations. Data suggest that this updated histological guide might be used for identification and quantification of histological lesions when applying sculpins in biomonitoring programs in Greenland and other Arctic regions.     

Histology of Sculpin spp. in East Greenland. II. Histopathology and trace element concentrations

Abstract

For many years, the sculpin has been utilized as a sentinel monitoring species for anthropogenic impacts on the marine environment. To further develop its potential as a screening model body burden of several trace elements, including cadmium (Cd), copper (Cu), mercury (Hg), lead (Pb) and selenium (Se), were investigated. In addition, histopathology in shorthorn sculpins (Myoxocephalus scorpius; n?=?20) and fourhorn sculpins (Myoxocephalus quadricornis; n?=?10) were examined at three sites around the Scoresby Sound settlement in Central East Greenland. Fourhorn sculpins caught at the most distant site from the settlement, contained significantly higher hepatic Cu and Cd concentrations as well as significantly elevated gill Pb levels compared to the shorthorn sculpins collected at two other sites closer to the settlement. Histological examinations showed that fish with significantly higher concentrations of hepatic Cd and Se exhibited greater nuclear alterations, interstitial hyperplasia/hypertrophy, interstitial mononuclear infiltrations and granulomas. Further, fish with higher Cd and Cu gill tissue levels displayed a significantly higher number of cytoplasmic alterations and lamellar epithelium lifting, hypertrophic and hyperplastic epithelium along with mucus cell hyperplasia. While the presence of liver lesions were not species or sex-specific, the presence of gill lesions decreased in the order female fourhorn sculpins?>?female shorthorn sculpins?>?male fourhorn sculpins?>?male shorthorn sculpins. Hepatic Hg concentrations exceeded known lowest observable effect doses (LOED) for fish (0.1–0.5?μg g^?1 ww) in 27% of fish, while liver Cd residues in 80% exceeded LOED (0.42–1.8?μg g^?1 ww). Based upon these results, data suggest that using the sculpin as a valuable sentinel fish species histopathology may serve as a reliable tool for assessing marine ecosystem exposure to trace metals. However, confounding physiological and ecological factors also need to be considered.     

Resilience in the context of tsunami early warning systems and community disaster preparedness in the Indian Ocean Region

This paper discusses insights from post-tsunami early warning system (EWS) development in Thailand, Sri Lanka and Indonesia by analysing selected elements of resilience, based on the Coastal Community Resilience (CCR) framework, and by distinguishing between the cognitive, normative and procedural dimensions of EWSs. The findings indicate that (1) recent calls to develop participatory and people-centred EWSs as promoted by the Hyogo Framework for Action 2005—2015 have not been sufficiently translated into action in the implementation of national policies and strategies for early warning; (2) policy and guidance places significantly more emphasis on the procedural compared to the normative and cognitive dimensions of EWSs; (3) practitioners engaged in early warning and disaster risk reduction operate in contexts shaped by multiple stakeholder agendas and face considerable challenges in negotiating diverse needs and priorities; and (4) few platforms currently exist that enable stakeholders to coordinate and reconcile agendas, negotiate joint targets, share knowledge and critically reflect on lessons learnt, and to improve the integration of early warning with other priorities such as livelihoods improvement, natural resource management and community development.     

Metals concentration and bioaccumulation in the marine-coastal trophic web from Buenos Aires province southern coast,Argentina

Metals accumulated in the tissues of organisms inhabiting marine ecosystems generally reflect their bioavailable levels within that environment. The aim of this work was to study the presence and concentration of metals (Cd, Cr, Cu, Fe, Ni, Pb and Zn) and its bioaccumulation in liver-ink sac (n?=?12) and muscle (n?=?12) tissues of loliginid squids, Loligo sanpaulensis, in liver (n?=?15) and muscle (n?=?15) tissues of white croakers, Micropogonias furnieri, and in muscle (n?=?12) tissues of franciscana dolphins, Pontoporia blainvillei, as representatives of different trophic levels of an estuarial ecosystem from the southern coast of Buenos Aires. Except for Pb, all metals were detectable in the hepatic tissues. Bioaccumulation was observed for Fe, Cr and Ni in muscle of squids. Zn levels in muscle samples increased with the trophic level of the species analysed. Necochea-Quequén presents relatively high levels of Ni and Cr in the tissue samples of squids and fishes given other locations of southern hemisphere, indicating a possible anthropic enrichment. These outcomes provide the necessary basis for the environmental monitoring of an area with relevance for fishing and high anthropic activity.     

MODELING HYDROLOGIC TIME SERIES FROM THE ARCTIC1

The general intervention model is applied to hydrologic and meteorologjc time series from the Canadian Arctic. The authors show how the model is able to account for environmental interventions, missing observations in the data, changes in data collection procedures, the effects of external inputs, as well as seasonality and autocorrelation. Methods for identifying transfer functions by making use of a physical understanding of the processes involved are demonstrated and sample applications of the general intervention model to Arctic data are shown.     

Biodegradation of Fuel Oil Under Laboratory and Arctic Marine Conditions

The aerobic biodegradation of the components of a fuel oil under Arctic summer conditions follows a pattern that is indistinguishable from that exhibited under temperate conditions. Straight chain alkanes and small aromatics are degraded first, followed by branched alkanes and larger and alkylated aromatics. We present data on the biodegradation of heptadecane as a representative n-alkane, pristane as a representative iso-alkane, and naphthalene, phenanthrene, and chrysene and their alkylated forms as representative two-, three- and four-ring aromatic hydrocarbons. In particular, the pattern of degradation of the alkylated aromatics allows the identification of biodegradation in samples collected from the field and the estimation of the extent of biodegradation that occurred in the In-Situ Treatment of Oiled Sediment Shorelines Field Trials.