Role of the reduction site in the fluorinated or sulfated TiO2 photocatalytic process

In this article,the effects of TiO_2 surface fluorination and sulfation,on the active oxygen species formed at the reduction site in the photocatalytic process,namely O_2~(?) and H_2O_2,were investigated from a new perspective.The superoxide radical,(O_2~(?)),was determined by colorimetry of nitroblue tetrazolium,a prominent O_2~(?) scavenger.Hydrogen peroxide (H_2O_2) was estimated by using the iodide-starch method.In the naked TiO_2 photocatalysis,O_2~(?) though less reactive,was a very important intermediate.When the TiO_2 surface was fluorinated,more O_2~(?) and H_2O_2 were produced,which indicated that the surface modification could greatly reduce the recombination of photogenerated electrons and holes,thus enhancing the photocatalytic rate.In the sulfated system,photocatalysis proceeded with a more complicated mechanism.These results added support to the view of fluoride-induced enhancement and sulfide's nonappreciable inhibition effect.     

Nitrate leaching under vegetable field above a shallow aquifer in Slovenia

In the search for new technologies that would ensure optimum yield and environmental sustainability, various irrigation, nitrogen and cropping system management strategies for the production of vegetables with a shorter growing period were assessed at a benchmark site in Slovenia for the years 2006 and 2007. In the studied years four irrigation and fertilization treatments were applied: (1) 50% drip irrigation of plants water requirements ET_crop and the farmer's practice of fertilisation (broadcasting), (2) fertilisation and 100% drip irrigation (fertigation), (3) the farmer's practice of irrigation (sprinkler irrigation using water stored in plastic tanks) and fertilisation, and (4) control (the farmer's practice of irrigation but no fertilisation). An equivalent of 80, 80 and 200 kg ha⁻¹ of nitrogen (N), 50, 50 and 80 kg ha⁻¹ of phosphorous (P) and 120, 120 and 300 kg ha⁻¹ of potassium (K) was added for iceberg lettuce, endive and cabbage, respectively. Nitrogen (N) labelled fertilizer (¹⁵N) was applied to trace the movement of the applied N fertiliser. The tested irrigation and fertilisation techniques for the production of vegetables with a shorter growing period in the Slovenian climate showed that environmentally sustainable practices (split application of nutrients compared to broadcast incorporating fertilisation) should be a practice of choice in water protection zones. The results confirm that fertigation and improved irrigation scheduling can be an effective way of minimizing nitrate leaching, and should be considered for vegetable production in or close to groundwater protection zones.     

棘洪滩水库典型风况分析及其应用研究

棘洪滩水库的源水是水库流场变化的主要动力,风力状况也是影响棘洪滩水库流场况变化的重要因素,当水库处于非调水期,风力状况的作用尤为明显。本论文整理了棘洪滩水库1989-2008年20年间气象资料,统计得出水库年际和四个季度的风向、风力变化情况。结果表明,棘洪滩水库常年盛行风向是南风和西北风。春季和冬季以西北风为主,夏季和秋季以东风和东南风为主。通过sMs软件建立的水质模型可以验证,不同的风向与风力大小对水库流场的变化有着显著的影响。     

钢铁行业技术减排措施硫、氮、碳协同控制效应评价研究

随着我国污染减排形势的日趋严峻,在高污染行业采用协同控制措施实现多种污染物控制目标不仅十分必要而且非常迫切,而合理评价减排措施的协同控制效应是实施协同控制的基础.基于此,本研究从环境-经济-技术角度系统地提出了钢铁行业技术减排措施对硫、氮、碳的协同控制效应评价方法,包括:协同控制效应坐标系分析、污染物减排量交叉弹性(Elsa/b)分析和单位污染物减排成本评价,3种评价方法相互配合,可以从多角度检验不同减排措施的协同控制效应.协同控制效应坐标系和污染物减排量交叉弹性分析的结果表明,末端治理措施不具有协同控制效应或协同控制效应不佳,而绝大多数过程控制措施都具有较好的协同控制效应.单位污染物减排成本评价的结果表明,末端治理措施优先度排序靠后,而过程控制措施排序靠前,且针对不同污染物的排序结果有所不同.在进行钢铁行业协同减排方案设计和规划时,应根据决策需要选择适宜的评价方法,参考评价结果选择最为成本有效的措施.     

临近空间环境及环境试验

从热力学结构、大气成分特征、大气电磁特性等方面介绍了临近空间环境参数,按照临近空间飞行器的平均密度、飞行速度、飞行高度介绍了临近空间飞行器的分类及特点。阐述了临近空间环境试验的方法,并对临近空间环境试验技术的发展提出了初步建议。     

我国湖泊富营养化效应区域差异性分析

通过分析我国湖泊富营养化相关指标的区域差异性,发现在相同营养物质条件下,浮游藻类生物量却有所差异,说明不同区域浮游藻类对营养物质总氮（TN）和总磷（TP）的利用效率存在显著的区域差异性.利用SPSS中的曲线估计功能,分析我国不同湖泊区域lg Chl-a分别与lg TN和lg TP的线性方程,通过比较线性方程的斜率分析不同湖泊区域浮游藻类对营养物质TN和TP的利用效率,蒙新高原、云贵高原、东北平原-山地、长江中下游平原及华北平原,lg Chl-a与lg TP线性方程的斜率由高到低依次为1.002、0.817、0.761、0.545、0.250.lg Chl-a与lg TN线性方程的斜率由高到低依次为1.401、1.058、0.447、0.239、0.099,分别为长江中下游平原、云贵高原、华北平原、东北平原-山地及蒙新高原.由此可见,东北平原-山地和蒙新高原TP对浮游藻类生长的影响大于TN,而在华北平原、长江中下游平原和云贵高原,TN对浮游藻类生长的影响大于TP.另一方面,通过分析浮游藻类生物量与水体透明度之间的相关性,阐明藻类生长繁殖对不同区域湖泊水体透明度影响的区域差异性,结果表明,湖泊中浮游藻类生长繁殖对水体透明度影响最大的是云贵高原,其次是东北平原-山地、蒙新高原和华北平原,长江中下游平原水体透明度与浮游藻类生物量之间没有显著相关性.     

A Spatiotemporal Analysis of Urban Growth: A Case Study for Jinan Municipality,China

Abstract

China is experiencing a process of rapid industrialization and urbanization at the cost of agricultural land and environment, particularly in the costal areas. This study takes Jinan as a case presenting a time-series analysis of urban land expansion from 313 to 2003. The results show that the urban expansion of Jinan city mainly took place in the last 100 years, especially after the economic reform in 1978. Social development and economic growth, urban population growth and migration policies were factors driving the urban land expansion. Urban sprawl resulted in a disappearance of wetlands and a great loss of agricultural land, and over-pumping of ground water that led to disappearance of the city's feature, namely “the city of springs”.     

Figuring Out #Fukushima: An Initial Look at Functions and Content of US Twitter Commentary About Nuclear Risk

This study takes an exploratory look at Twitter content in the USA about the emergency at Japan's Fukushima-Daiichi nuclear power station. In particular, I focus on the concepts of the “atrophy of vigilance” from the risk communication literature and the message functions fulfilled for social media users. Two important results emerge from this analysis. First, Twitter content in the USA reflected a cautious approach, mainly suggesting an informative versus interpretive function and rarely mentioning risk or hazard outright. Second, this informative emphasis on risk dominated the content of tweets in the few days following the emergency but decreased substantially within 2 weeks afterwards; it was then overtaken by an interpretive risk emphasis. In addition, toward the end of this period, tweets were more likely to include hyperlinks to websites of traditional news outlets. Implications for the empirical study of social media and risk communication are discussed.     

中国三大海洋经济圈海洋经济发展区域差异与分布动态及影响因素

考察中国海洋三大经济圈海洋经济发展区域差异,探究其分布动态演进规律,识别其空间非均衡的影响因素及空间溢出效应,为“十四五”期间优化海洋经济发展空间布局、推动区域海洋经济协同均衡发展提供决策参考。利用Dagum基尼系数及其分解方法考察三大海洋经济圈海洋经济发展区域相对差异的程度、来源及演变态势,在此基础上,进一步应用Kernel密度估计方法刻画其绝对差异的分布动态演进过程,并将空间效应纳入研究框架,应用空间计量分析方法识别海洋经济发展空间非均衡的影响因素及空间溢出效应。研究发现：三大海洋经济圈海洋经济发展均呈现稳定上升态势,但三者之间存在显著的分级现象;三大海洋经济圈空间非均衡程度显著,超变密度是造成三大海洋经济圈整体区域差异的主要来源;三大海洋经济圈海洋经济发展水平“极化效应”显著,呈现不同极化特征和分布延展性;三大海洋经济圈海洋经济发展存在显著的空间依赖性,总体表现为空间正相关。     

北京市园林植物吸附PM_(10)与SO_2总量及其健康效益

PM10和SO2是目前城市主要的大气污染物,严重危害居民健康。城市园林植物通过叶片和枝干表面能有效吸附大气污染物。采用大气污染物干沉降通量模型和暴露-反应关系模型定量评估了2003年北京市园林植物吸附PM10与SO2总量及其健康效益。北京市园林植物2003年吸附PM1030,415,563～38,019,454kg和SO23,057,173～3,821,466kg,导致减少死亡312～390人,呼吸系统入院286～357.5人,折合经济价值约为280,265,180～350,331,475元,约占国民生产总值的0.7‰～1.0‰。