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Kaliannan Durairaj Palanivel Velmurugan Subramaniyan Divyabharathi Dhamodaran Kavitha 《International Journal of Green Energy》2019,16(7):573-582
The present study investigates the thermally activated carbon derived from Nerium oleander flower which was used an adsorbent. Physicochemical properties of Nerium oleander flower carbon (NOFC) were characterized by scanning electron microscopy, X-ray diffraction, and Fourier transform infrared for the removal of DTB (Direct Turquoise Blue) and RR-HE7B (Reactive red–HE7B) dyes from aqueous solution. Adsorption studies were carried out with different pH, adsorbent dose, contact time, and initial concentration dye solution. Optimum conditions for maximum removal of DTB and RR-HE7B was achieved to be pH 2 for both dyes, adsorbent dose of 100 mg and equilibrium time of 35 and 60 min, respectively, for NOFC. The maximum adsorption capacity of NOFC was found to be 33.33 and 19.60 mg g?1, respectively, for the removal of dye solution. The mechanism of adsorption was studied by using different kinetic models and isotherms. The results clearly showed that the NOFC adsorption was fitted to pseudo–first-order for DTB and pseudo–second-order for RR-HE7B. Equilibrium data were well fitted with both isotherm models. According to the results, NOFC can effectively remove DTB and RR-HE7B from aqueous solutions. 相似文献
184.
This, our second reply to Östensson, supplements our earlier more technical analysis with a simple intuitive explanation of how investor demand can be driving commodity prices higher even when investor stocks are falling. 相似文献
185.
Kai Ma;Bowen Chen;Cheng-Xin Li;Venkataraman Thangadurai; 《Advanced Sustainable Systems》2024,8(6):2300656
Garnet-type Li7La3Zr2O12 electrolytes have garnered significant attention as promising solid-state electrolyte candidates in all-solid-state lithium batteries (ASSLBs). However, its susceptibility to forming Li2CO3 upon atmospheric exposure leads to performance degradation, limiting its application. This study introduces a co-doping strategy of Mg and Ta to enhance the properties of garnet electrolytes. Pure cubic Mg and Ta-doped LLZO electrolytes are successfully synthesized using the solid-state reaction method. Experimental results, coupled with density functional theory (DFT) calculation, reveal that Mg2+ doping occurs primarily at the La site (24c). This substitution, given the substantial disparity in ionic radii between Mg2+ and La3+, effectively narrows the transport bottleneck for Li-ions, resulting in a decreased ionic conductivity and an increased activation energy. Li6.6La2.8Mg0.2Zr1.4Ta0.6O12 exhibits a relative density of ≈92.6%, demonstrating outstanding performance with a room temperature ionic conductivity of 4.31 × 10−4 S cm−1 and low electronic conductivity of 2.48 × 10−8 S cm−1. Notably, after 4 months of atmospheric exposure, its ionic conductivity decreased to ≈78% of the initial value, attributable to Li2CO3 formation. Furthermore, the material demonstrated exceptional long-term cycle stability over 1000 h at a current density of 0.1 mA cm−2 at 25 °C, indicating effective suppression of Li dendrite formation. 相似文献
186.
以某电解锰工艺末端铬钝化废水为研究对象,采用氧化、除杂、反应制得成品,污水达标处理及回用的组合工艺,制备达到国家标准的中铬黄产品,以实现铬的回收利用。结果表明:对于H2O2氧化工艺,选用V(水样)/V(30%H2O2)为(600~1000):1;可采取加碱沉淀Mn的工艺去除杂质金属离子;铬酸铅的生成反应适宜温度为55~60℃,硝酸铅投加量为理论值的1.05倍~1.10倍;采取加石灰调pH、投加硫酸铝的方法可去除水样中剩余铅离子,V(上清液)/V(5%硫酸铝溶液)为1000~2000较合适;生产该产品基本上能够做到保本、微利,但具有显著的环境效益和社会效益。 相似文献
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Weihua Su Yuying Wang Dalia Streimikiene Tomas Balezentis Chonghui Zhang 《Sustainable Development》2020,28(4):657-669
The G7 and Brazil, Russia, India, China and South Africa (BRICS) nations have committed to greenhouse gas emission reduction according to targets set out in the Paris Agreement and Copenhagen Accord. The objective of this paper is to develop an index decomposition framework and apply it for comparison of the drivers behind carbon dioxide emission. The impact of economic and technological development on greenhouse gas emissions is assessed by applying the Kaya identity. The index decomposition analysis is carried out by applying the Shapley value. In this paper, we seek to compare the two groups of countries—G7 and BRICS—in regard to the underlying trends in the energy‐related carbon dioxide emission during 1990–2015. The comparison of these two groups for countries draws some light on the pathways of decarbonization of the economies in developing and developed countries. The time period covered spans over the sub‐periods of economic growth and decline. Energy intensity appeared as the major factor pushing the carbon dioxide emissions down in the developed countries (i.e., G7 group). The latter effect was much lower for the developing countries (i.e., BRICS group) and was offset by the affluence effect. Further development of the renewable energy is important for the developing countries in order to start exploiting the carbon factor effect. 相似文献
189.
Inbasekaran Muthuvel Balu Krishnakumar Meenakshisundaram Swaminathan 《环境科学学报(英文版)》2012,24(3):529-535
Fe(Ⅲ) immobilized fire clay (Fe-FC) was prepared using ferric nitrate by solid state dispersion method and this hetero-Fenton catalyst was applied for the degradation of Acid Violet 7 (AV 7) under natural sunlight. The 26% ferric nitrate loaded fire clay was found to be most efficient. The experimental conditions such as solution pH, H2O2 concentration for efficient degradation of AV 7 have been determined. Unlike Fenton catalyst, Fe-FC is photoactive over a wide pH range of 3-7. This catalyst was found to be stable and reusable. The GC-MS analysis of experimental solutions during irradiation revealed the formation of 2,8-diaminonaphthalene-1,3,6-triol, 8-aminonaphthalene-1,2,3,6-tetrol, 2-aminonaphthalene-1,3,6,8-tetrol and 2-aminobenzene-1,3-diol/5-aminonbenzene-1,3-diol/ 2-aminobenzene-1,4-diol as intermediates. The 26% ferric nitrate loaded fire clay was characterized by XRD, ICP-AES, BET surface area, FT-IR, SEM-EDS and UV-DRS studies. 相似文献
190.
Effects of temperature and precipitation on grassland bird nesting success as mediated by patch size
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Grassland birds are declining faster than any other bird guild across North America. Shrinking ranges and population declines are attributed to widespread habitat loss and increasingly fragmented landscapes of agriculture and other land uses that are misaligned with grassland bird conservation. Concurrent with habitat loss and degradation, temperate grasslands have been disproportionally affected by climate change relative to most other terrestrial biomes. Distributions of grassland birds often correlate with gradients in climate, but few researchers have explored the consequences of weather on the demography of grassland birds inhabiting a range of grassland fragments. To do so, we modeled the effects of temperature and precipitation on nesting success rates of 12 grassland bird species inhabiting a range of grassland patches across North America (21,000 nests from 81 individual studies). Higher amounts of precipitation in the preceding year were associated with higher nesting success, but wetter conditions during the active breeding season reduced nesting success. Extremely cold or hot conditions during the early breeding season were associated with lower rates of nesting success. The direct and indirect influence of temperature and precipitation on nesting success was moderated by grassland patch size. The positive effects of precipitation in the preceding year on nesting success were strongest in relatively small grassland patches and had little effect in large patches. Conversely, warm temperatures reduced nesting success in small grassland patches but increased nesting success in large patches. Mechanisms underlying these differences may be patch‐size‐induced variation in microclimates and predator activity. Although the exact cause is unclear, large grassland patches, the most common metric of grassland conservation, appears to moderate the effects of weather on grassland‐bird demography and could be an effective component of climate‐change adaptation. 相似文献