化学品反应危险性分级方法研究与应用

针对化学品反应危险性的评价,介绍利用最大分解热,反应放热功率,绝热反应参数等方法对化学品反应危险性进行分级的几种方法及各自特点。通过分析整合不同分级方法,提出一种基于实测反应放热参数的分级方法,此方法以初始放热温度和反应热组成指标体系,同时配合燃爆曲线实现对化学品反应危险性的分级,得到的结果对于化学品的安全评价有较强的参考价值。考察了6种有机过氧化物的放热性质,诠释了有机过氧化物的反应危险性,应用所提出的反应危险性分级方法对其进行分级,并对分级方法进行了验证。该方法结合了实验结果和多种分级方法的优点,使化学品反应危险性分级方法具有更强的实用性。     

Study of high-frequency electromagnetic field effect on some somatic and neuro-behavioral characteristics in healthy and neurodefective mice

The effect of long-term exposure to high frequency electromagnetic field (HF EMF) on some somatic and neural characteristics was studied in neurodefective Lurcher mutant (+/Lc) and normal wild type mice (+/+). Both newborn and young adult (3 months) animals derived from two strains (C3H, B6CBA) were exposed to HF EMF (870 MHz) from 1st to 21st day or from 91st to 120th day respectively. In animals of both groups and controls we observed the development of body weight. Moreover, in the HF EMF exposed adult B6CBA animals we studied spatial learning ability, motor functions and the CNS excitability. To investigate specific energy absorption rate (SAR) in experimental animals we have done the basic 3D calculations of the electromagnetic energy distribution in the simplified model of the mouse. The HF EMF exposed animals exhibited mild differences of body weight between them and unexposed controls. The long-term exposure to HF EMF did not significantly influence the ability to learn in the Morris water maze. However, significant lower swimming speed was found in the irradiated +/Lc as well as lower motor activity of +/+ in the open field when compared to controls. No significant differences were found between HF EMF irradiated animals and controls in examination of the CNS excitability and motor functions.     

锅炉尾部烟道直接喷水调质技术的研究

对排烟温度低于160 ℃的锅炉尾部烟道内直接喷水调质技术进行了探讨,从实际应用情况来看,此项技术改造规模小,不影响除灰系统正常运行,并且能提高1%～2.5%的除尘效率.     

大型建筑构件在突发性事件中的抗火性能分析

针对地震、恐怖袭击等突发性事件引起的次生火灾对大型建筑的破坏特点,比较了大型建筑与普通建筑在结构抗火性能上的差异;利用轴向非均匀温度应力模型,对大型建筑构件的抗火性能与结构抗火计算进行了分析,疏理归纳出了部分性能特征;提出了一套用于这类火灾特点的构件抗火计算理论方法。     

HP6890色谱柱用于环境空气中微量恶臭硫化物的检测

利用HP6890型气相色谱仪进行环境空气中微量恶臭硫化物分析,实验结果表明:分离效果、峰形都很好,实验采用4种柱箱初始温度及升温程序,分别由初始温度70℃升温至90℃、120℃、130℃及由初始温度150℃,最后升温至190℃,相应分析一个样品的时间依次为:130.515min、63.419min、56.359min及11.116min,样品分析时间大大缩短,可提高分析效率。     

东北地区玉米低温冷害综合指标研究

在以往对低温冷害指标研究的基础上，将低温冷害成分不同的发育阶段进行分析，结合发育期日数和初霜日研究等，讨论分析了东北地区玉米的低温冷害问题，提出一个玉米低温冷害综合指标。该指标生物学和农学意义明确，计算较为方便，便于在预报上的应用。     

黑龙江省暴雪天气分析和预报技术

分析表明，造成黑龙江省暴雪的低压天气系统不仅来自西北、偏西和偏南方向，而且还有在东北和日本海新生成的，其中又以西南和南来的居多；高空影响系统主要是低槽，其次是低涡，但降暴雪时多数是低涡；造成暴雪的锋面系统以暖锋和锢囚锋为最多。另外，从造成降水的成因和水平锋生这两个角度出发，给出了7个暴雪落区的温压场模型。850hPa温度、850hPa温度平流和拔海高度决定了降水（雨、雪）的性质。     

Specificity of Life Conditions for Commercial Invertebrates on Artificial Substrates in the Eutrophicated Amur Bay,the Sea of Japan

The consequences of anthropogenic impact on the water area of Amur Bay (the Sea of Japan) near Vladivostok include the eutrophication of coastal waters and littering with various objects used as artificial substrates, which protect sedentary animals from predators and contribute to the survival of their larvae. An indicator of eutrophication, the diatom Skeletonema costatum accounting for 81–96% of the total abundance of phytoplankton (Stonik and Selina, 1995), is consumed mainly by barnacles and the Pacific oyster. Thus, these animals gain an advantage in the colonization of artificial substrates. The results of the study suggest that eutrophication will lead to changes in the structure of the marine community.     

钢网壳抗火非线性有限元分析

通过两种方式研究钢网壳的抗火性能,其一是对火的分析及单个构件的抗火力学性能分析;其二是对钢网壳结构进行抗火分析,以结构具有一定的抗火时间为标准,通过模拟预测实际火灾特性和结构的非线性有限元分析,求得直到倒塌时的结构抗火全过程响应,从而确定结构的抗火性能及临界温度。并通过一个实际的算例进行了结构的倒塌分析,得到了一些结论,从而对其实际抗火能力有一个理性的了解和认识,为经济、科学的结构综合防火设计提供理论依据。     

围岩散热计算及壁面水分蒸发的处理

笔者采用湿度系数法对壁面水分蒸发进行了处理,对计算壁面处饱和空气含湿量的方法进行了改进,将饱和空气含湿量与温度的关系拟合为二次曲线;建立了在考虑壁面水分蒸发情况下解算巷道围岩温度场分布及围岩向风流的散热量的数学方程,并采用异步长有限差分法对其进行了数值模拟求解;解算出巷道壁面水分蒸发情况下围岩温度分布、壁面温度和围岩散热量的变化规律;并与将饱和空气含湿量与温度的关系拟合为线型关系曲线时的解算结果进行了对比,将饱和空气含湿量和温度之间的关系拟合为线性的计算结果存在一定的误差,通风时间越长,湿度系数越大,风流相对湿度越小,拟合为线性时计算出来的壁面温度和围岩散热量的误差越大。