利用混合C9重芳烃回收磺酸盐装置的技术经济分析

介绍了回收磺酸盐生产工艺 ,对其装置的产品成本进行了测算 ,并对盈亏平衡及其敏感性进行了分析 ,进而确定了主要经济指标。     

产酸脱硫反应器中COD/SO_4~(2-)比制约的群落生态演替规律

通过产酸脱硫反应器的动态试验和配套的静态试验 ,考察致变因子COD/SO2 - 4比制约的乙酸型顶极群落的结构、优势种群的组成和生态演替的规律 ;阐明乙酸型代谢和乙酸型顶极群落是产酸脱硫生态系统的典型特征 ;揭示乙酸型顶极群落内平衡与反馈调节的生理代谢机制 ,并以因变因子 pH值、氧化还原电位和碱度来表征生态演替过程中优势种群的三维实现生态位     

新型结构ABR的设计与水力特性研究

针对ABR自身的缺点,设计出一种新型结构的ABR.该反应器为双层结构,共有5部分组成,各部分容积各不相同.该反应器的设计思想是将ABR与生物滤池以及活性炭吸附等工艺相联合.这种设计能够最大程度地发挥各工艺的优势,进而达到更好的处理效果.通过脉冲响应实验对该反应器的水力特性进行研究,得出不同水力停留时间(HRT)下的停留...     

污水处理厂剩余污泥对凤仙花和万寿菊生长的影响

采用盆栽方式,通过对花卉植物生长状况和各项生理指标的考察,研究了不同污泥施用比对凤仙花(Impatiens balsamina)和万寿菊(Tagetes erecta L.)生长的影响。结果表明,污泥施用比不高于5%(质量分数)时对两种花卉植物发芽有促进作用。在前期,对照组凤仙花和万寿菊生长较好,其株高、叶绿素和可溶性糖含量高于污泥施用组,丙二醛(MDA)含量低于污泥施用组。而在后期,污泥的施用对两种花卉生长促进作用明显,污泥施用组的两种花卉植物株高和各项生理指标优于对照组,尤其是开花状况显著好于对照组。凤仙花和万寿菊较优的污泥施用比分别为3%~5%和1%~5%。     

Ce-PbO_2/C电极的制备及其去除水中酸性红B

采用电沉积法制备铈修饰的PbO2/C电极,通过SEM、XRD、XPS及循环伏安对PbO2/C、Ce-PbO2/C电极进行表征,结果表明,Ce-PbO2/C电极比PbO2/C颗粒细小,表面均匀致密,电化学氧化能力较强,修饰电极中Ce以CeO2的形态存在。以Ce-PbO2/C为工作电极,电解浓度为1 000 mg/L的高盐酸性红B模拟活性染料废水,考察了电压、pH、电解质浓度、极间距对脱色率、氨氮去除率及COD去除率的影响。确定适宜工艺条件为：初始酸性红B溶液浓度为1 000 mg/L,pH值为6,电压10 V,电解时间1 h,电极间距1.5 cm,该条件下脱色率、氨氮去除率和COD去除率分别为99.98%、97.23%和90.17%。通过UV-Vis及GC-MS初步分析了降解过程可能存在的中间产物及降解途径。     

阿什河水系枯水期氮污染特征与同位素源解析

在阿什河水系设置20个采样点,采用水质监测技术和稳定氮同位素示踪技术,研究了枯水期阿什河氮污染特征和硝酸盐氮污染来源。结果表明:(1)阿什河枯水期大部分采样点氨氮浓度较低,大部分区域达到或优于《地表水环境质量标准》(GB3838—2002)中Ⅲ类。上游河段硝酸盐氮浓度较低,中游河段较高,到下游河段略有降低。总氮浓度较高,最高达19.4mg/L。(2)阿什河水系采样点15 N的丰度(δ15 N)主要处于0.11%~0.21%、0.42%~0.78%、0.83%~0.88%和1.09%~1.26%。稳定15 N同位素示踪解析阿什河硝酸盐氮污染来源表明,阿什河上游污染源主要为大气沉降、土壤有机氮和人工化肥;中游主要受畜禽养殖污水和生活污水污染;下游主要受城镇生活污水和工业废水影响。     

Assessing the recovery potential of alpine moss-sedge heath: reciprocal transplants along a nitrogen deposition gradient

The potential of alpine moss-sedge heath to recover from elevated nitrogen (N) deposition was assessed by transplanting Racomitrium lanuginosum shoots and vegetation turfs between 10 elevated N deposition sites (8.2-32.9 kg ha⁻¹ yr⁻¹) and a low N deposition site, Ben Wyvis (7.2 kg ha⁻¹ yr⁻¹). After two years, tissue N of Racomitrium shoots transplanted from higher N sites to Ben Wyvis only partially equilibrated to reduced N deposition whereas reciprocal transplants almost matched the tissue N of indigenous moss. Unexpectedly, moss shoot growth was stimulated at higher N deposition sites. However, moss depth and biomass increased in turfs transplanted to Ben Wyvis, apparently due to slower shoot turnover (suggested to result partly from decreased tissue C:N slowing decomposition), whilst abundance of vascular species declined. Racomitrium heath has the potential to recover from the impacts of N deposition; however, this is constrained by the persistence of enhanced moss tissue N contents.     

Soil nitrogen transformations under elevated atmospheric CO₂ and O₃ during the soybean growing season

We investigated the influence of elevated CO₂ and O₃ on soil N cycling within the soybean growing season and across soil environments (i.e., rhizosphere and bulk soil) at the Soybean Free Air Concentration Enrichment (SoyFACE) experiment in Illinois, USA. Elevated O₃ decreased soil mineral N likely through a reduction in plant material input and increased denitrification, which was evidenced by the greater abundance of the denitrifier gene nosZ. Elevated CO₂ did not alter the parameters evaluated and both elevated CO₂ and O₃ showed no interactive effects on nitrifier and denitrifier abundance, nor on total and mineral N concentrations. These results indicate that elevated CO₂ may have limited effects on N transformations in soybean agroecosystems. However, elevated O₃ can lead to a decrease in soil N availability in both bulk and rhizosphere soils, and this likely also affects ecosystem productivity by reducing the mineralization rates of plant-derived residues.     

N deposition as a threat to the World's protected areas under the Convention on Biological Diversity

This paper combines the world’s protected areas (PAs) under the Convention on Biological Diversity (CBD), common classification systems of ecosystem conservation status, and current knowledge on ecosystem responses to nitrogen (N) deposition to determine areas most at risk. The results show that 40% (approx. 11% of total area) of PAs currently receive >10 kg N/ha/yr with projections for 2030 indicating that this situation is not expected to change. Furthermore, 950 PAs are projected to receive >30 kg N/ha/yr by 2030 (approx. twice the 2000 number), of which 62 (approx. 11,300 km²) are also Biodiversity Hotspots and G200 ecoregions; with forest and grassland ecosystems in Asia particularly at risk. Many of these sites are known to be sensitive to N deposition effects, both in terms of biodiversity changes and ecosystem services they provide. Urgent assessment of high risk areas identified in this study is recommended to inform the conservation efforts of the CBD.     

The impact of nitrogen deposition on acid grasslands in the Atlantic region of Europe

A survey of 153 acid grasslands from the Atlantic biogeographic region of Europe indicates that chronic nitrogen deposition is changing plant species composition and soil and plant-tissue chemistry. Across the deposition gradient (2-44 kg N ha⁻¹ yr⁻¹) grass richness as a proportion of total species richness increased whereas forb richness decreased. Soil C:N ratio increased, but soil extractable nitrate and ammonium concentrations did not show any relationship with nitrogen deposition. The above-ground tissue nitrogen contents of three plant species were examined: Agrostis capillaris (grass), Galium saxatile (forb) and Rhytidiadelphus squarrosus (bryophyte). The tissue nitrogen content of neither vascular plant species showed any relationship with nitrogen deposition, but there was a weak positive relationship between R. squarrosus nitrogen content and nitrogen deposition. None of the species showed strong relationships between above-ground tissue N:P or C:N and nitrogen deposition, indicating that they are not good indicators of deposition rate.