Here we synthesize key findings from a series of experiments to gain new insight on inter-plant competition between juvenile beech (Fagus sylvatica) and spruce (Picea abies) under the influence of increased O3 and CO2 concentrations. Competitiveness of plants was quantified and mechanistically interpreted as space-related resource investments and gains. Stable isotopes were addressed as temporal integrators of plant performance, such as photosynthesis and its relation to water use and nitrogen uptake. In the weaker competitor, beech, efficiency in space-related aboveground resource investment was decreased in competition with spruce and positively related to Δ13C, as well as stomatal conductance, but negatively related to δ18O. Likewise, our synthesis revealed that strong belowground competition for water in spruce was paralleled in this species by high N assimilation capacity. We suggest combining the time-integrative potential of stable isotopes with space-related investigations of competitiveness to accomplish mechanistic understanding of plant competition for resources. 相似文献
13C CP-MAS NMR spectroscopy is a technique that has proved to be useful in studying soil organic matter (SOM). Nevertheless, NMR spectra exhibit a weak signal and have very low resolution due to: the low natural abundance of 13C (1.1 % of C) in SOM, the generally low SOM content of soils, and the presence of paramagnetic impurities. This paper studies the effects of soil chemical pre-treatments on 13CP-MAS NMR spectra quality and spectra representativity i.e. soil C mass balance.
After chemical pre-treatment to increase total organic carbon (TOC) content and C/Fe ratio, eight soils characterized by different levels of organic carbon content and C/Fe ratios were studied using 13CP-MAS NMR. Moreover, where chemical treatments were not applicable due to high carbon losses, the number of 13CP-MAS NMR scans was increased in order to obtain satisfactory spectra.
Results show that chemical pre-treatment of soils with C/Fe > 1 caused high C losses. Bulk soils were therefore studied by increasing the number of 13CP-MAS NMR scans. Acceptable spectra were obtained from 8K scans (1K = 1024 transient). On the other hand, even when a large number of scan (32K) are used, soil with C/Fe < 1 cannot be studied. As these soils are characterized by low C losses after HCl treatments (range of 2.9–25.4%), a pre-treatment of at least 1.39 mol l−1 HCl removes excess Fe and at the same time increases C/Fe ratio resulting in 32K scans providing good spectra. 相似文献
Sewage sludges are frequently used as soil amendments due to their high contents of organic matter and nutrients, particularly N and P. However, their effects upon the chemistry of soil humic acids, one of the main components of the soil organic matter, need to be more deeply studied in order to understand the relation between organic matter structure and beneficial soil properties. Two sewage sludges subjected to different types of pre-treatment (composted and thermally dried) with very different chemical compositions were applied for three consecutive years to an agricultural soil under long-term field study. Thermal analysis (TG–DTG–DTA) and solid-state 13C NMR spectroscopy were used to compare molecular and structural properties of humic acids isolated from sewage sludges, and to determine changes in amended soils. Thermally dried sewage sludge humic acids showed an important presence of alkyl and O/N-alkyl compounds (70%) while composted sludge humic acids comprised 50% aromatic and carbonyl carbon. In spite of important differences in the initial chemical and thermal properties of the two types of sewage sludges, the chemical and thermal properties of the soil humic acids were quite similar to one another after 3 years of amendment. Long-term application of both sewage sludges resulted in 80–90% enrichment in alkyl carbon and organic nitrogen contents of the soil humic acid fraction. 相似文献
The critical issue of China's modernization is whether it can free itself from the traditional modernization plan based on the relatively abundant natural capital, and innovatively create a developmental model of a large country under the scarcity of natural capital. This is why China is so keen on circular economy and economical use of resources. Focused on this issue, this paper summarizes the theoretical elements of the development under the scarcity of natural capital, points out that Plan C is the strategic choice for China's future development, emphasizes that China needs to enhance the new industrialization, new urbanization and new modernization based on the restriction of natural capital, and discusses the technological and mechanistic support required to realize the development under the scarcity of natural capital. 相似文献
We augment the standard cartel formation game from non-cooperative coalition theory, often applied in the context of international environmental agreements, with the possibility that singletons support coalition formation without becoming coalition members themselves. We assume their support takes the form of a monetary transfer to the coalition, in order to induce larger coalitions, higher levels of public good provision and higher payoffs. We show that, under mild conditions on the costs and benefits of contributing to the public good (e.g. abatement of greenhouse gas emissions), there exist equilibria with support. Allowing for support increases payoffs to each of three types of agents: members, supporters and free-riders. 相似文献
An incubation experiment lasting 111 d was carried out to study the effect of the addition of three clay minerals (Na-bentonite, Ca-bentonite, and zeolite) to soil derived from sewage sludge on water-extractable and exchangeable forms of four heavy metals (Zn, Cd, Cu, and Ni), as well as on soil organic matter mineralization, microbial biomass C and the release of inorganic N. The addition of clay minerals led to a significant decrease in water-extractable and exchangeable forms of heavy metals. The extent of decrease ranged from 14 to 75% for the water-extractable heavy metals and from 12 to 42% for the exchangeable form over the incubation time, as compared with untreated soil. The reduction in extractability of heavy metals was greater due to the addition of Na-bentonite and Ca-bentonite than that due to the addition of zeolite. Addition of clay minerals did not affect any of the following microbiological parameters in the soil: microbial biomass C, organic C (Corg) mineralization, and metabolic quotient (qCO2), and release of inorganic N during the first 3 weeks of incubation. However, as the incubation period increased, these parameters were significantly increased by the addition of clay minerals, especially by the addition of Na-bentonite and Ca-bentonite. This result is explained by a strong reduction in extractability of heavy metals after the addition of Na-bentonite and Ca-bentonite. 相似文献
In India, millions of tones of livestock excreta are produced. Our study explores the potential of an epigeic earthworm Eisenia foetida to compost different livestock excreta (cow, buffalo, horse, donkey, sheep, goat and camel) into value added product (vermicompost)
at the laboratory scale. Vermicomposting resulted in lowering of pH, electrical conductivity, potassium and C:N ratio and
increase in nitrogen and phosphorus contents. Total K was lower in the final cast than in the initial feed. C:N ratios of
the vermicomposts ranged from 16.2 ± 2.17 to 75.4 ± 6.84. Microbial activity measured as dehydrogenase activity in buffalo,
donkey and camel wastes increased with time up to day 90. But in sheep and goat wastes, maximum dehydrogenase activity was
recorded on day 60 and decreased thereafter. The cocoons and hatchlings production by Eisenia foetida in different excreta were also investigated. The greatest number and biomass of hatchlings was recorded in horse excreta
followed by cow, goat and sheep excreta. Thus, cow, horse, sheep and goat excreta show potential as good substrates in vermicomposting
using Eisenia foetida, although further research is required to explore the feasibility of use of buffalo, donkey and camel excreta in combination
with cow/sheep/goat excreta. 相似文献