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41.
铁炭复配修复地下水中NO_3~--N的条件研究 总被引:2,自引:0,他引:2
采用了铁炭复配修复地下水中NO3--N,探讨了实验条件对修复效果的影响。结果表明,在pH值近中性条件(初始pH 6.42)下,反应时间为1 h时NO3--N修复率达到60.85%;Fe/C=1∶1时介质最佳用量分别为4~5 g;Fe/C=1/1.5时修复率为72.80%;反应速率在高振荡强度下大于低振荡强度;氧化铜的催化效果最好,可使修复率提高7.5个百分点。铁炭复配介质修复地下水中NO3--N是有效可行的,修复率随反应时间的增加而提高,在Fe/C=1∶1时修复率与介质用量呈正相关,无限减小Fe/C比并不能无限提高修复率,振荡强度对修复具有显著影响,低振荡强度下的修复过程较高强度存在滞后现象,并非所有金属氧化物催化剂对铁炭修复NO3--N均有促进作用。 相似文献
42.
Given that the gold market and the crude oil market are the main representatives of the large commodity markets, it is of crucial practical significance to analyze their cointegration relationship and causality, and investigate their respective contribution, from the perspective of price discovery, to the common price trend so as to interpret the dynamics of the whole large commodity market and forecast the fluctuation of crude oil and gold prices. 相似文献
43.
This paper models the monthly price volatilities of four precious metals (gold, silver, platinum and palladium prices) and investigates the macroeconomic determinants (business cycle, monetary environment and financial market sentiment) of these volatilities. Gold volatility is shown to be explained by monetary variables, but this is not true for silver. Overall, there is limited evidence that the same macroeconomic factors jointly influence the volatility processes of the four precious metal price series, although there is evidence of volatility feedback between the precious metals. These results are consistent with the view that precious metals are too distinct to be considered a single asset class, or represented by a single index. This finding is of importance for portfolio managers and investors. 相似文献
44.
The aim of this study was to investigate the mechanism of cadmium (Cd) adsorbed by microalgae Chlamydomonas reinhardtii (C.reinhardtii). The kinetic and adsorption isotherm of the process could be well described by mathematical models. Chemical modification experiments and Fourier transform infrared spectra indicated that carboxyl and amine groups were the important functional groups for adsorption of Cd. The maximum contribution of physical adsorption in the overall adsorption process was evaluated as 5.5%... 相似文献
45.
Petia S. Nikolova Christian P. Andersen Rainer Matyssek 《Environmental pollution (Barking, Essex : 1987)》2010,158(4):1071-1078
The effects of experimentally elevated O3 on soil respiration rates, standing fine-root biomass, fine-root production and δ13C signature of newly produced fine roots were investigated in an adult European beech/Norway spruce forest in Germany during two subsequent years with contrasting rainfall patterns. During humid 2002, soil respiration rate was enhanced under elevated O3 under beech and spruce, and was related to O3-stimulated fine-root production only in beech. During dry 2003, the stimulating effect of O3 on soil respiration rate vanished under spruce, which was correlated with decreased fine-root production in spruce under drought, irrespective of the O3 regime. δ13C signature of newly formed fine-roots was consistent with the differing gs of beech and spruce, and indicated stomatal limitation by O3 in beech and by drought in spruce. Our study showed that drought can override the stimulating O3 effects on fine-root dynamics and soil respiration in mature beech and spruce forests. 相似文献
46.
Cristina Barazzetti Barbieri Jorge Eduardo Souza Sarkis Luiz Antonio Martinelli Isabella C. A. C. Bordon Horst Mitteregger Jr. Marcos Antônio Hortellani 《Environmental Forensics》2014,15(2):134-146
A forensic approach was used to evaluate sediments from Portão Stream, including analysis of metals, carbon (C) and nitrogen (N) stable isotopes, and C:N ratios. Samples collected at various points located along the stream were tested in order to investigate a possible illegal leachate input. The studied stream is heavily impacted by sewage and industrial discharges from two cities along its course. Among the metals analyzed, chromium (Cr) was noticeably the main pollutant, showing the highest levels, above regulatory limits, downstream from some potential sources of effluents enriched with this metal. Isotope analyses revealed a general trend of depletion in the heavier isotope along the stream for C and N. The exception was one point near a hazardous waste landfill, where relatively more enriched δ13C and δ15N values were found. The isotope and metal analysis results indicated that this site was affected by a particular source, demonstrating the combination of these parameters could be used for the discrimination of sources in a heavily polluted stream. Nevertheless, further investigations are necessary to provide a comprehensive evaluation of the biogeochemical processes involved in the incorporation of leachate in sediments to use this analysis as evidence for the illegal leachate discharge. 相似文献
47.
针对杭州西湖钱塘江引水低碳高氮的特点,提出以改性水草塘—复合垂直流人工湿地(IVCW)相耦合的生物—生态工艺进行引水处理,对该引水降氮示范工程的构建和运行效果进行了跟踪研究。结果表明,整个稳定运行期间(2012年7月19日至11月19日),耦合工艺对COD、TN、硝酸盐氮、TP的平均去除率分别为52.27%、52.49%、53.69%、52.79%,系统出水满足《地表水环境质量标准》(GB 3838—2002)Ⅳ标准;改性水草塘和IVCW单元作为耦合工艺的两个重要组成部分,在脱氮、除磷方面优势互补,从而共同保证出水水质的稳定;在改性水草塘单元,温度与COD的去除效果呈负相关关系,进水C/N与TN去除效果呈正相关关系;而在IVCW单元,温度与COD、TN的去除效果均呈线性正相关关系,进水C/N与两者的去除效果也呈正相关关系,且对COD的影响要大于对TN的影响。 相似文献
48.
Concentration factors for Cs-137 and Ra-226 transfer from seawater, and dried sediment or mud with detritus, have been determined for whole, fresh weight, Chelon labrosus individuals and selected organs. Cesium was detected in 5 of 22 fish individuals, and its activity ranged from 1.0 to 1.6 Bq kg−1. Radium was detected in all fish, and ranged from 0.4 to 2.1 Bq kg−1, with an arithmetic mean of 1.0 Bq kg−1. In regards to fish organs, cesium activity concentration was highest in muscles (maximum - 3.7 Bq kg−1), while radium was highest in skeletons (maximum - 25 Bq kg−1). Among cesium concentration factors, those for muscles were the highest (from seawater - an average of 47, from sediment - an average of 3.3, from mud with detritus - an average of 0.8). Radium concentration factors were the highest for skeleton (from seawater - an average of 130, from sediment - an average of 1.8, from mud with detritus - an average of 1.5). Additionally, annual intake of cesium and radium by human adults consuming muscles of this fish species has been estimated to provide, in aggregate, an effective dose of about 4.1 μSv y−1. 相似文献
49.
Development of a combined isotopic and mass-balance approach to determine dissolved organic carbon sources in eutrophic reservoirs 总被引:1,自引:0,他引:1
Pierson-Wickmann AC Gruau G Jardé E Gaury N Brient L Lengronne M Crocq A Helle D Lambert T 《Chemosphere》2011,83(3):356-366
A combined mass-balance and stable isotope approach was set up to identify and quantify dissolved organic carbon (DOC) sources in a DOC-rich (9 mg L−1) eutrophic reservoir located in Western France and used for drinking water supply (so-called Rophemel reservoir). The mass-balance approach consisted in measuring the flux of allochthonous DOC on a daily basis, and in comparing it with the effective (measured) DOC concentration of the reservoir. The isotopic approach consisted, for its part, in measuring the carbon isotope ratios (δ13C values) of both allochthonous and autochthonous DOC sources, and comparing these values with the δ13C values of the reservoir DOC. Results from both approaches were consistent pointing out for a DOC of 100% allochthonous origin. In particular, the δ13C values of the DOC recovered in the reservoir (−28.5 ± 0.2‰; n = 22) during the algal bloom season (May-September) showed no trace of an autochthonous contribution (δ13C in algae = −30.1 ± 0.3‰; n = 2) being indistinguishable from the δ13C values of allochthonous DOC from inflowing rivers (−28.6 ± 0.1‰; n = 8). These results demonstrate that eutrophication is not responsible for the high DOC concentrations observed in the Rophemel reservoir and that limiting eutrophication of this reservoir will not reduce the potential formation of disinfection by-products during water treatment. The methodology developed in this study based on a complementary isotopic and mass-balance approach provides a powerful tool, suitable to identify and quantify DOC sources in eutrophic, DOC-contaminated reservoirs. 相似文献
50.
The chemical composition and physical conformation of natural organic matter (NOM) play a major role in regulating its capacity to retain hydrophobic organic compounds. Naphthalene and phenanthrene were used to study the correlations between sorption/desorption isotherm nonlinearity and compositional data obtained from quantitative 13C solid-state DPMAS NMR spectroscopy for soil and peat organic matter with or without lipids. Sorption experiments were conducted using a batch equilibration method. Desorption experiments were carried out immediately following the sorption experiments by three successive decant-refill cycles. Hysteresis was observed in all samples. Nonlinear sorption behavior was increased by removal of lipids from the NOM. The hysteresis index, obtained from the ratio of the Freundlich exponents (N values) for the desorption and sorption isotherms, was lower in the lipid-extracted NOM samples than in the same samples without lipid extraction. The relationship between the extent of hysteresis and the characteristics of the 13C DPMAS NMR spectra indicates that altering NOM composition through lipid extraction not only increased the proportion of aromatic-C content, but also increased sorption/desorption hysteresis. Our data also suggest that the hysteresis index is negatively related to aromaticity. 相似文献