Methodology for CO2 chain analysis

The paper presents a methodology for CO₂ chain analysis with particular focus on the impact of technology development on the total system economy. The methodology includes the whole CO₂ chain; CO₂ source, CO₂ capture, transport and storage in aquifers or in oil reservoirs for enhanced oil recovery. It aims at supporting the identification of feasible solutions and assisting the selection of the most cost-effective options for carbon capture and storage. To demonstrate the applicability of the methodology a case study has been carried out to illustrate the possible impact of technology improvements and market development. The case study confirms that the CO₂-quota price to a large extent influence the project economy and dominates over potential technology improvements. To be economic feasible, the studied chains injecting the CO₂ in oil reservoirs for increased oil production require a CO₂-quota price in the range of 20–27 €/tonne CO₂, depending on the technology breakthrough. For the chains based on CO₂ storage in saline aquifers, the corresponding CO₂-quota price varies up to about 40 €/tonne CO₂.     

Separation and recovery of carbon dioxide by a membrane flash process

A novel process for carbon dioxide (CO₂) separation, which was named a membrane flash process, was developed to realize an energy-saving technology and to substitute it for a conventional regenerator. The electric energy for CO₂ recovery in a membrane flash process using aluminum oxide and diethanolamine was lower than the thermal energy of the conventional chemical absorption process. Flashing at elevated temperature by the low temperature energy significantly reduced the electric energy and required much less membrane area. This process has potentiality of low cost capture of CO₂ when the low temperature energy, which is not available for other purposes, can be utilized to elevate flashing temperature.     

Corrosion and polarization behavior of carbon steel in MEA-based CO2 capture process

This work reveals levels of corrosion rate and polarization behavior of carbon steel immersed in aqueous solutions of monoethanolamine (MEA) used in the absorption-based carbon dioxide (CO₂) capture process for greenhouse gas reduction from industrial flue gas streams. Such information was obtained from electrochemical-based corrosion experiments under a wide range of the CO₂ capture process conditions. The corrosion of carbon steel was evaluated in respect to process parameters including partial pressure of oxygen (O₂), CO₂ loading in solution, solution velocity, solution temperature, MEA concentration and metal surface condition. Results show that the aqueous MEA solution containing CO₂ provides a favorable condition for the corrosion of carbon steel to proceed. Corrosion rate is increased by all tested process parameters. These parametric effects were explained by the electrochemical kinetic data obtained from polarization curves and by the thermodynamic data obtained from Pourbaix diagram.     

A combined plasma photolysis (CPP) method for removal of CS2 from gas streams at atmospheric pressure

A combined plasma photolysis (CPP) reactor that utilizes a dielectric barrier discharge (DBD) plasma and 207 nm UV radiation from discharge-driven KrBr^* excimers was designed and constructed. Gas streams containing CS₂ were treated with stand-alone DBD and CPP at atmospheric pressure. In comparison to DBD, CPP greatly enhanced the removal efficiency at the same applied voltage, waste gas concentration and gas residence time. Thus the applied voltage could be reduced to a certain extent in the plasma processing of industrial wastes. Influences of the KrBr^* radiation, inlet CS₂ concentration and gas residence time on CS₂ removal by CPP were also studied. In addition, the likely reaction mechanisms for the removal of CS₂ by CPP are suggested based on the byproducts analysis. The enhanced removal efficiency and reaction mechanisms implied that the CPP process would probably be suitable for the removal of a large number of gaseous pollutants.     

某市南郊水源地土壤四氯化碳污染特征

含四氯化碳废水在排放的过程中沿排污渠侧壁和底部的渗漏对土壤造成污染.在对某市南郊受四氯化碳污染的水源地进行钻孔检测的过程中发现,土壤四氯化碳污染的特征:靠近排污沟的钻孔均检测出四氯化碳,而远离排污沟的钻孔则未检出;四氯化碳的垂向分布存在不连续性,且受降雨影响较大;大部分钻孔浅层土壤中基本未检测到四氯化碳,而在3 m以下的土层和基岩中检测到四氯化碳;抽水井的抽水行为导致抽水井附近土壤中四氯化碳明显高于其他钻孔点位检测结果.     

Performance assessments for the geological storage of carbon dioxide: Learning from the radioactive waste disposal experience

The geological storage of carbon dioxide is currently being considered as a possible technology for reducing emissions to atmosphere. Although there are several operational sites where carbon dioxide is stored in this way, methods for assessing the long-term performance and safety of geological storage are at an early stage of development. In this paper the similarities and differences between this field and the geological disposal of radioactive wastes are considered. Priorities are suggested for the development of performance assessment methods for carbon dioxide storage based on areas where experience from radioactive waste disposal can be usefully applied. These include, inter alia, dealing with the various types of uncertainty, using systematic methodologies to ensure an auditable and transparent assessment process, developing whole system models and gaining confidence to model the long-term system evolution by considering information from natural systems. An important area of data shortage remains the potential impacts on humans and ecosystems.     

天然气管道泄漏爆炸后果评价模型对比分析

天然气管道失效可能导致多种严重后果,爆炸灾害给周围的人员和建筑物造成重大的危害,对其爆炸危害范围的评价进行研究具有重要现实意义。笔者综合分析蒸气云爆炸(VCE)定量评价模型和API pub 581后果评价模型;并以某输气管道为实例对爆炸后果进行了定量模拟评价;得到死亡区域与泄漏时间的关系,确定了其爆炸事故的伤害范围;对两种模型的评价结果进行了对比分析。爆炸后果评价模型的研究与其对比探讨,为今后输气管线的定量风险后果评价模型选取提供参考依据。     

城镇煤气管道漏损分析与风险评价

在管道漏损的各种因素分析与分类的基础上,建立管道漏损综合评价模型,结合事故树法和专家评分法,实现对管道运行状况的评价。事故树模型采用最小割集的方法描述事故树相应的结构函数,从而评价事故树各底层事件的结构重要度。根据专家评分法,对危害因素指标和后果进行评分,实现管道工作状态的风险评价。该分析和评价方法,为实现基于风险评价的风险控制与管理提供理论依据。     

单室燃气火灾后果模拟研究

燃气泄漏着火是引发火灾的一个重要原因，其发展过程包括多相湍流流动、燃烧、传热多个分过程。本文将理想单室燃气泄漏火灾的传热传质过程采用CFD（Compulational Fluid Dynamics）方法进行了计算机模拟，对其发展规律及危害性进行了深入研究，得出了火场中的流场、泻度场及有害气体浓度场的分布，为定量研究火灾烟气流动过程以及建立不同危险等级的危险区域提出了依据和研究方法。     

供热管道波纹管补偿器裂纹泄漏的分析及对策

通过对热电厂直埋供热管道波纹管补偿器裂纹泄漏事故的调查分析,找出了问题所在,并提出了解决应力腐蚀问题可行的对策.