全文获取类型
收费全文 | 742篇 |
免费 | 10篇 |
国内免费 | 114篇 |
专业分类
安全科学 | 47篇 |
废物处理 | 23篇 |
环保管理 | 159篇 |
综合类 | 285篇 |
基础理论 | 159篇 |
环境理论 | 1篇 |
污染及防治 | 125篇 |
评价与监测 | 32篇 |
社会与环境 | 35篇 |
出版年
2023年 | 23篇 |
2022年 | 31篇 |
2021年 | 14篇 |
2020年 | 14篇 |
2019年 | 28篇 |
2018年 | 17篇 |
2017年 | 26篇 |
2016年 | 41篇 |
2015年 | 45篇 |
2014年 | 40篇 |
2013年 | 48篇 |
2012年 | 27篇 |
2011年 | 95篇 |
2010年 | 39篇 |
2009年 | 62篇 |
2008年 | 68篇 |
2007年 | 68篇 |
2006年 | 24篇 |
2005年 | 24篇 |
2004年 | 18篇 |
2003年 | 15篇 |
2002年 | 13篇 |
2001年 | 11篇 |
2000年 | 9篇 |
1999年 | 4篇 |
1998年 | 15篇 |
1997年 | 9篇 |
1996年 | 8篇 |
1995年 | 4篇 |
1994年 | 6篇 |
1993年 | 2篇 |
1992年 | 3篇 |
1991年 | 4篇 |
1990年 | 1篇 |
1989年 | 3篇 |
1985年 | 3篇 |
1984年 | 1篇 |
1978年 | 2篇 |
1969年 | 1篇 |
排序方式: 共有866条查询结果,搜索用时 796 毫秒
91.
92.
Titania (TiO2) has been the focus of attention of researchers since the first demonstration of its capability to generate the photocatalytic splitting of water into hydrogen and oxygen. However, there seems to be a recent surge in the research activity, involving modified TiO2 nanoparticles (NP), which are considered to be more effective due to different physicochemical properties in comparison to unmodified fine particle analogs. Several strategies have been employed to modify TiO2 to reduce recombination rates of photogenerated charge carriers to enhance the optimal functioning of TiO2. Doping with cations and anions and coupling it with another semiconductor are the most well-known modification methods used. Titania nanocomposites are known to have a plethora of applications. Photoexcitation of these particles are seen to be extraordinarily effective in eliciting microbial death which makes it an attractive candidate for the manufacturing of antimicrobial coatings. On the other hand, TiO2 induces the oxidation of various organic refractory compounds like tetracycline, sulfamethazine, and bisphenol. The photo-electrocatalytic oxidation technique which amalgamates the principle of photocatalysis and electrolysis serves as a newer, unswerving, and cost effective water treatment process. In the biomedical arena, use is now acknowledged for the photodynamic therapy of cancer, cell imaging, biological sensors, drug delivery system, and as endonucleases. In the commercial front, it is utilized in creams owing to its small particle size, which facilitates absorption through skin. It is also employed as ultraviolet blocking agents in sunscreen and commonly encountered as a brilliant white pigment in paint due to its brightness, high refractive index and resistance to discoloration. Its use in solar cells has also been reported. This review aims to encompass the new progress of modified TiO2 nanocomposites for efficient applications, emphasizing the future trends of TiO2 in arenas like healthcare, environment, biomedical, food, personal care, and pharmacy and also highlights the commercial implications of this promising nanomaterial. 相似文献
93.
Vegetation and carbon sequestration and their relation to water resources in an inland river basin of Northwest China 总被引:1,自引:0,他引:1
In the Heihe River Basin in the arid inland area of northwest China, the distribution of water resources in vegetation landscape zones controls the ecosystems. The carbon sequestration capacity of vegetation is analyzed in relation to water resources and vegetation growing conditions. During the last 20 years, the vegetation ecosystems have degenerated in the Heihe River Basin. Simulation using the C-FIX model indicates that, at present, the total amount of NPP of vegetation accounts for about 18.16 TgC, and the average value is 106 gC/m(2)/yr over the whole basin. NPP has generally the highest value in the upperstream mountain area, middlestream artificial oases area, downstream river bank area, alluvial fan and the terminal lake depression where vegetation grows relatively well. The lowest value is found in the vast downstream desert and Gobi area. Protection of vegetation ecosystems and enhancement of carbon sequestration require such inland river basins as the Heihe River Basin to be brought under management in a comprehensive way, taking water as a key, to carry out a rational and efficient allocation and utilization of water resources. 相似文献
94.
El-Shafey EI 《Journal of environmental management》2007,84(4):620-627
A carbonaceous sorbent was prepared from peanut shell via sulphuric acid treatment. Se(IV) removal from aqueous solution on the sorbent was studied varying time, pH, Se(IV) concentration, temperature and sorbent status (wet and dry). Se(IV) removal was faster using the wet sorbent than the dry sorbent following a pseudo-first-order model. Se(IV) removal increases at low pH values, and decreases as pH increases until pH 7. Sorption was found to fit the Langmuir equation and sorption capacity for the wet sorbent was higher than that for the dry one. Both sorbents showed an increased selenium sorption by rising the temperature. Redox processes between Se(IV) and the carbon sorbent are involved. Analysis by scanning electron microscope and X-ray powder diffraction for the sorbent after the reaction with acidified Se(IV) confirmed the availability of elemental selenium as particles on the sorbent surface as a result of Se(IV) reduction. Physicochemical tests showed an increase in sorbent acidity, cation exchange capacity (CEC) and surface functionality after the reaction with acidified Se(IV), indicating the oxidation processes occurring on the sorbent surface. Due to its reduction properties, the sorbent seems efficient for Se(IV) removal from aqueous solution. 相似文献
95.
Wood carbon content of tree species in Eastern China: interspecific variability and the importance of the volatile fraction 总被引:5,自引:0,他引:5
Data on the mass density and carbon content of tree organs, and in particular stem wood, are essential for accurate assessments of forest carbon sequestration. However most available data, including that for East Asia, has neglected the volatile C fraction. Wood samples were collected and assayed for C content from 14 native tree species in Jilin Province, NE China. C content showed statistically significant variation among species, ranging from 48.4% to 51.0%. The volatile C fraction was non-negligible, averaging 2.2%, and showed high variation among species. As found in prior studies, wood C content was appreciably higher in conifer than hardwood (angiosperm) species (50.8+/-0.1% vs. 49.5+/-0.2%, respectively). Wood carbon density (gC/cm(3)) showed very high inter-specific variation, due mainly to differences in wood specific gravity. Our analyses, in conjunction with recently published data from North America, indicate a global mean value of 47.5+/-0.5% wood C content exclusive of volatile C; the widely used 50% figure corresponds more closely to total wood C inclusive of the volatile fraction. Failure to include volatile C or to use species- or higher-taxon-specific C content values in forest C assessments is likely to introduce biases on the order approximately 4-6%. In addition, the stocks and flows of the volatile C fraction in wood are in themselves an important and sorely neglected aspect of forest C processes likely to be strongly impacted by harvests and other management practices. 相似文献
96.
Robin Hickman Patricia Austin David Banister 《Journal of Environmental Policy & Planning》2014,16(3):419-435
AbstractA number of cities around the world are associated with very high levels of private motor car usage, and Auckland provides an example of one of these ‘hyperautomobile’ cities. There are many problems with this system of transportation and dependence on the private car, including environmental, social and city design dimensions. Though there is a clear aspiration to move towards reduced levels of car usage in the city's transport and spatial planning strategies, there are major difficulties in implementation terms. We develop and consider future scenarios to 2041 to reduce these levels of motorization, and subsequent transport CO2 emissions, with a much greater use of public transport, walking and cycling, urban planning, and low emission vehicles. The current implementability of such a ‘sustainable mobility’ future is however questioned in the current political and social context, and critically debated in terms of the available governance mechanisms and the limited attempts to shape the behaviour of the public. We conclude by calling for a reconsideration of the policy measures being considered, including the range and levels of application and investment; with a much wider framing of the transport planning remit, and carried out within a much stronger participatory framework for decision-making. 相似文献
97.
生物质能(Biomass energy)是最为广泛的可再生能源,其中多年生芒属C4植物(Miscanthus)由于具有巨大碳固定能力而成为潜力巨大的生物质能植物。中国是芒属植物芒草起源中心,但相对于欧洲国家应对能源危机和温室效应而采取的芒草研究与应用来说,仍处于起步阶段。我国长期以来传统的草地利用模式,决定了在南方草地的研究显著少于北方,近年来芒草在华南地区的运用研究集中于生态修复,对草本植物群落基于生态系统水平的 CO2气体交换能力的研究仍然相当缺乏,在二氧化碳浓度持续增长及全球变暖背景下,生物质能植物及其碳汇功能的相关研究尤显重要。我国南方近6700万hm2退化丘陵草坡急待恢复或处于恢复中,草坡地芒属植物符合生物质能植物标准,施肥少,害虫少,农药输入少,能够有效地利用光、水等自然资源。考虑到C4植物具有比C3植物更强的光合作用能力,高光能利用率C4芒属植物的碳固定能力及能源潜力值得重视,但缺乏科学的碳动态和碳收支评估。综述了国内外芒草生物量特征与生物质能潜力研究现状,重点论述芒属植物生态系统水平的碳动态和收支能力研究,探讨了系统水平更客观评估芒属碳源汇(Carbon sequestration)功能的方法,基于生物量过程的研究结果及华南地区草坡研究历史和现状,为草坡地生物质能的合理开发利用提出了相关对策,强调在我国南方开发和利用芒属植物资源具有重要能源价值和经济、环境效益。 相似文献
98.
Marina Cabrini Manuela Andri Sara Cok Irene Pecchiar Serena Fonda Umani 《Chemistry and Ecology》2013,29(1-2):95-105
In the frame of PRISMA II Project samples for plankton analyses were carried out during four cruises (June, 1996; February and June, 1997; February, 1998) in order to assess the relative importance in term of biomasses of the three main size fractions (pico- <2 r µm, nano- 2-20 r µm and micro-plankton >20 r µm). Spatial and temporal distribution of the three plankton fractions were described as abundance and contribution to the total carbon content in an area between Po River mouth and Rimini. The relative contribution of picoplankton resulted higher in the offshore zone, while that of nanoplankton in the inshore waters. In February 1998 microphytoplankton, mainly constituted by diatoms, was very abundant in the inshore waters. Micro-zooplankton was always very scarce. Cluster analyses performed on these data grouped the stations on the basis of their community structure, and agreed with the hydrological features. Small size classes contributed more significantly to the total plankton carbon content in most of the situations. Microplankton fraction contribution was relevant only during spring diatom bloom of February 1998 and with a less extent in the confined coastal summer blooms. 相似文献
99.
Urban horticulture, defined as plant production activities that are conducted in a city or suburb that produce horticultural
plants that are wholly or partially edible, and which are economically viable, has the potential to reduce CO2 emissions caused by the transportation of produce. Moreover, to increase productivity in limited areas and use limited resources
effectively, closed or semi-closed systems (i.e., greenhouses) are considered more advantageous than open systems (i.e., fields)
from which resources can easily escape into the surrounding environment. In this paper the significance of urban horticulture
in reducing CO2 emissions in the transportation process is discussed with reference to simple case studies. In the context of building or
rebuilding greenhouses suitable for urban horticulture, the present situation regarding resource inputs and outputs in greenhouses
is compared to that in open fields. The reduction of resource inputs and outputs in greenhouse production is also discussed. 相似文献
100.
Emo Chiellini Andrea Corti Salvatore D’Antone Norman C. Billingham 《Journal of Polymers and the Environment》2007,15(3):169-178
Most of the standardized biodegradation tests used to assess the ultimate biodegradation of environmentally degradable polymers
are based solely on the determination of net evolved carbon dioxide. However, under aerobic conditions, it has to be considered
that heterotrophic microbial consortia metabolize carbon substrates both to carbon dioxide and in the production of new cell
biomass. It is generally accepted that in the relatively short term, 50% of the carbon content of most organic substrates
is converted to CO2, with the remaining carbon being assimilated as biomass or incorporated into humus. The latter is particularly important
when the metabolism of the organic matter occurs in a soil environment. A straightforward relationship between the free-energy
content of a carbon substrate (expressed as the standard free-energy of combustion) and its propensity for conversion to new
microbial biomass rather than mineralization to CO2 has been established. This can potentially lead to underestimation of biodegradation levels of test compounds, especially
when they consist of carbon in a fairly low formal oxidation state and relatively high free-energy content. In the present
work, the metabolism of different kind of carbon substrates, especially in soil, is reviewed and compared with our own experimental
results from respirometric tests. The results show that conversion of highly oxidized materials, such as the commonly used
reference materials, cellulose or starch, to CO2 may be significantly overestimated. The addition of glucosidic material to soil leads to greatly increased respiration and
is accompanied by a very low conversion to biomass or humic substances. In contrast, relatively less oxidized substrates metabolize
more slowly to give both CO2 and biomass to an extent which may be significantly underestimated if glucosidic materials are used as the reference. The
need for an overall carbon balance taking into account both the carbon immobilized as biomass and that volatized as CO2 must be considered in standard respirometric procedures for assessing the biodegradability of slowly degrading macromolecules. 相似文献