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排序方式: 共有1060条查询结果,搜索用时 15 毫秒
1.
Gabriela P. Mendes Vivian M.A. Magalhães Lélia C.R. Soares Rayanne M. Aranh Claudio A.O. Nascimento Marilda M.G.R. Viann Osvaldo Chiavone-Filho 《环境科学学报(英文版)》2020,32(4):67-77
Chemical oxidation was applied to an artificially contaminated soil with naphthalene (NAP). Evaluation of NAP distribution and mass reduction in soil, water and air phases was carried out through mass balance. Evaluation of NAP distribution and mass reduction in soil, water and air phases was carried out through mass balance. The importance of the air phase analysis was emphasized by demonstrating how NAP behaves in a sealed system over a 4 hr reaction period. Design of Experiments method was applied to the following variables: sodium persulfate concentration [SP], ferrous sulfate concentration [FeSO4], and pH. The system operated with a prefixed solid to liquid ratio of 1:2. The following conditions resulted in optimum NAP removal [SP] = 18.37 g/L, [FeSO4] = 4.25 g/L and pH = 3.00. At the end of the 4 hr reaction, 62% of NAP was degraded. In the soil phase, the chemical oxidation reduced the NAP concentration thus achieving levels which comply with Brazilian and USA environmental legislations. Besides the NAP partitioning view, the monitoring of each phase allowed the variabilities assessment over the process, refining the knowledge of mass reduction. Based on NAP distribution in the system, this study demonstrates the importance of evaluating the presence of semi-volatile and volatile organic compounds in the air phase during remediation, so that there is greater control of the system as to the distribution and presence of the contaminant in the environment. The results highlight the importance of treating the contaminant in all its phases at the contaminated site. 相似文献
2.
Fractionation of heavy metals and phosphorus in suspended sediments of the Yamuna river,India 总被引:2,自引:0,他引:2
The Yamuna river is the largest tributary of the Ganges river system. It originates in the Himalayas and flows through a varied geological terrain encompassing a large basin area. Metals Fe, Mn, Pb, Zn, Cu in different chemical fractions of suspended sediments such as exchangeable, carbonates, Fe–Mn oxides, organics and residual fractions were studied. Phosphorus associated with different chemical forms are discussed. The metals are mostly associated with residual fractions in the sediments followed by organics, Fe–Mn oxides, exhangeable and carbonates. Intensive use of chemical fertilizers and pesticides in agriculture in the basin affects the high inorganic phosphorus content in sediments. 相似文献
3.
中国乳腺癌与土壤环境中化学元素的相关性研究 总被引:12,自引:1,他引:12
利用土壤元素资料2069448个数据、乳腺癌死亡调查资料31320例,研究了乳腺癌死亡率与人群生存的土壤环境中64个元素的相关性。结果表明,砷、汞、钡、铊、钕、铀、锆、锑等元素与乳腺癌死亡率有相关性。等级相关系数分别为-0.6820(P〈0.0005)、0.4567(P〈0.01)、-0.3773(P〈0.025)、-0.3852(P〈0.025)、0.3179(P〈0.05)、-0.4377(P〈 相似文献
4.
介绍了SBR- COR 工艺处理高浓度、多品种混合化工污水的工艺流程、工作原理及闲置保养情况,详细地阐述了活性污泥生物相与运行状况的关系。实际运行表明,SBR- COR 具有重新启动所需时间短、微生物激活快,对浓度高、毒性大的化工污水具有耐冲击特性,外理效果显著。 相似文献
5.
Chemical process simulation (CPS) software has been widely used by chemical (process) engineers to design, test, optimise, and integrate process plants. It is expected that industrial ecologists to bring these same problem-solving benefits to the design and operation of industrial ecosystems can use CPS. This paper provides industrial ecology researchers and practitioners with an introduction to CPS and an overview of chemical engineering design principles. The paper highlights recent research showing that CPS can be used to model industrial ecosystems, and discusses the benefits of using CPS to address some of the technical challenges facing companies participating in an industrial ecosystem. CPS can be used to (i) quantitatively evaluate and compare the potential environmental and financial benefits of material and energy linkages; (ii) solve general design, retrofit, or operational problems; (iii) help to identify complex and often counter-intuitive solutions; and (iv) evaluate what-if scenarios. CPS should be a useful addition to the industrial ecology toolbox. 相似文献
6.
颗粒物质金属形态逐级提取技术问题的探讨 总被引:2,自引:0,他引:2
本文综述了国内外对颗粒物质中金属形态逐级提取测定技术方面的研究情况,重点阐述了颗粒物质金属形态分离方法,并对各相态的浸取技术和金属总量提取方法进行了讨论.从而为开展颗粒物质的金属化学形态的分析和研究,提出几点认识. 相似文献
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9.
基于营养液培养,添加外源稀土和ICP-MS分析技术,研究了无机配体PO43-(Pi)及有机配体柠檬酸(Cit)对小麦器官中稀土元素积累和分异的影响.结果表明,不同Pi水平对小麦根中的稀土总含量(∑REE)影响较小,但显著降低叶中∑REE含量;而不同Cit水平对小麦根、叶中∑REE含量都有明显降低作用.对照植物(无Pi、Cit添加)中,稀土元素在小麦根中具有中稀土(MREE)富集及M-型四重效应分布特征,叶中有重稀土(HREE)富集及W-型四重效应分布特征.不同Pi处理对四重效应无明显作用,但进一步加强HREE在小麦叶片中的富集.添加柠檬酸使对照植物根和叶中的分异有逐渐减弱的趋势,在高浓度处理时(Cit≥150μmol.L-1),小麦根和叶中出现轻稀土(LREE)富集. 相似文献
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