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31.
利用粉煤灰合成Linde type F(K)沸石吸附重金属Zn2+,考察吸附剂量、pH值、反应温度对Zn 2+吸附效果影响,研究沸石吸附Zn2+的等温线与动力学,得到了相应的模型。结果表明:吸附剂量、pH值、反应温度均对Zn2+去除效果影响显著。随着吸附剂量增大,Zn 2+去除效果不断提高,饱和吸附量逐渐减小。初始pH值为3~7时,沸石对Zn2+去除率随pH值升高迅速提高。反应温度越高,沸石吸附Zn2+到达平衡时间越短。沸石对Zn2+吸附过程符合Langmuir吸附等温式,其吸附为单分子层吸附;准二级反应动力学方程能很好描述沸石对Zn2+的吸附行为。 相似文献
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33.
本文介绍了氮氧化物产生的机理以及低氮燃烧技术在火电厂大型燃煤锅炉的应用,简述其技术特点和改造措施,并通过试验测试了改造后的效果。 相似文献
34.
在煤炭开采过程中,煤炭被采出后其所在地下煤层会形成一定区域的采空区,并使煤层上方的顶板岩层失去支撑,由于顶板岩层的抗拉强度比较有限,因此在其顶板岩层自身重力与上覆岩层压力的影响下,很容易因顶板断裂、破碎而出现采空塌陷问题,这不仅会影响煤矿所在区域的生态安全,同时还会使地下水受到较大的负面影响。为此,本文结合煤矿采空塌陷的特点,围绕采空塌陷对地下水的影响展开了分析,并在此基础上提出了一些较为可行的采空塌陷区域地下水治理保护建议。 相似文献
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36.
Kangjoo Kim Sung-Min Park Jinsam Kim Seok-Hwi Kim Yeongkyoo Kim Jeong-Tae Moon Gab-Soo Hwang Wang-Seog Cha 《Chemosphere》2009,77(2):222-227
The geochemical behavior of As in porewaters of an alkaline coal ash disposal site was investigated using multilevel samplers. The disposal site was in operation from 1983 until 1994 and was covered with 0.3–0.5 m thick soils in 2001 when this study was initiated. Sequential extraction analyses and batch leaching experiments were also performed using the coal ash samples collected from the disposal site. The results suggest the important roles of siderite (FeCO3) precipitation/dissolution and soil cover, which have been ignored previously. Arsenic levels in the porewater were very low (average of 10 μg L−1) when the site was covered with soil due to coprecipitation with siderite. The soil cover enabled the creation of anoxic conditions, which raised the Fe concentration by the reductive dissolution of Fe-(hydr)oxides. Because of the high alkalinity generated from the alkaline coal ash, even a small increase in the Fe concentration (0.66 mg L−1 on average) could cause siderite precipitation. When the soil cover was removed, however, an oxidizing condition was created and triggered the precipitation of dissolved Fe as (hydr)oxides. As a result, the dissolution of previously precipitated As-rich siderite caused higher As concentration in the porewater (average of 345 μg L−1). 相似文献
37.
Long-term evaluation of coal fly ash and mine tailings co-placement: A site-specific study 总被引:2,自引:0,他引:2
Muluken B. Yeheyis Julie Q. Shang Ernest K. Yanful 《Journal of environmental management》2009,91(1):237-244
This study presents the results of a laboratory investigation conducted to evaluate the efficiency of coal fly ash to control the formation of acid mine drainage (AMD) from mine waste. Site-specific materials, coal fly ash from Atikokan Thermal Generating Station and mine tailings from Musselwhite mine, were mixed at different proportions for the investigation of the drainage chemistry and the optimal mix using static testing (acid–base accounting) and kinetic (column) testing. The acid–base accounting (ABA) results indicated that the fly ash possessed strong alkaline (neutralization) potential (NP) and could be used in the management of reactive mine tailings, thus ensuring prevention of AMD in the long-term. Column tests conducted in the laboratory to further investigate long-term performance of fly ash in the neutralization and prevention of acid mine drainage from tailings similarly showed that mixing fly ash with mine tailings reduces dissolution of many heavy metals from tailings by providing alkalinity to the system. It was found that a fly ash to tailings mass ratio equal to or greater than 15% can effectively prevent AMD generation from Musselwhite mine tailings in the co-placement approach. 相似文献
38.
Reclamation and revegetation of fly ash disposal sites - Challenges and research needs 总被引:1,自引:1,他引:0
Haynes RJ 《Journal of environmental management》2009,90(1):43-53
Coal-fired power generation is a principal energy source throughout the world. Approximately, 70-75% of coal combustion residues are fly ash and its utilization worldwide is only slightly above 30%. The remainder is disposed of in landfills and fly ash basins. It is desirable to revegetate these sites for aesthetic purposes, to stabilize the surface ash against wind and water erosion and to reduce the quantity of water leaching through the deposit. Limitations to plant establishment and growth in fly ash can include a high pH (and consequent deficiencies of Fe, Mn, Cu, Zn and P), high soluble salts, toxic levels of elements such as B, pozzalanic properties of ash resulting in cemented/compacted layers and lack of microbial activity. An integrated organic/biotechnological approach to revegetation seems appropriate and should be investigated further. This would include incorporation of organic matter into the surface layer of ash, mycorrhizal inoculation of establishing vegetation and use of inoculated legumes to add N. Leaching losses from ash disposal sites are likely to be site-specific but a sparse number of studies have revealed enriched concentrations of elements such as Ca, Fe, Cd, Pb, and Sb in surrounding groundwater. This aspect deserves further study particularly in the longer-term. In addition, during weathering of the ash and deposition of organic matter during plant growth, a soil will form with properties vastly different to that of the parent ash. In turn, this will influence the effect that the disposal site has on the surrounding environment. Nevertheless, the effects of ash weathering and organic matter accumulation over time on the chemical, physical and biological properties of the developing ash-derived soil are not well understood and require further study. 相似文献
39.
Xunpeng Shi Author Vitae 《Journal of Safety Research》2009,40(3):207-213
Problem
Empirical studies on the effectiveness of workplace safety regulations are inconclusive. This study hypothesizes that the asynchronous effects of safety regulations occur because regulations need time to become effective. Safety regulations will work initially by reducing the most serious accidents, and later by improving overall safety performance.Method
The hypothesis is tested by studying a provincial level aggregate panel dataset for China's coal industry using two different models with different sets of dependent variables: a fixed-effects model on mortality rate, which is defined as fatalities per 1,000 employees; and a negative binominal model on the annual number (frequency) of disastrous accidents.Results
Safety regulations can reduce the frequency of disastrous accidents, but have not reduced mortality rate, which represents overall safety performance.Discussion and summary
Policy recommendations are made, including shifting production from small to large mines through industrial consolidation, improving the safety performance of large mines, addressing consequences of decentralization, and facilitating the implementation of regulations through carrying on institutional actions and supporting legislation.Impact on industry
Until recently, about 4,000 coal miners perished annually in China, demonstrating that workplace safety in China's coal industry is an urgent and important issue. This research provides evidence that safety regulations have asynchronous effects and identifies the priorities in improving safety in China's current coal mining. This may assist the Chinese government to design more effective safety improvement policies and improve the effectiveness of safety regulations and safety performance. 相似文献40.
Effects of sewage sludge blending on the coal combustion: a thermogravimetric assessment 总被引:3,自引:0,他引:3
Combustion of urban sewage sludge together with coal in existing infrastructures may be a sustainable management option energetically interesting for these materials, usually considered wastes. Thermogravimetric analysis was used to study the combustion of a semianthracite coal and the modifications undergone when adding a small percentage (2%, 5%, 10%) of sewage sludge. Both Differential Scanning Calorimetric analysis and Differential Thermogravimetry burning profiles showed differences between coal and sewage sludge combustion. However, the effects of adding a percentage of sewage sludge equal or smaller than 10% was hardly noticeable in terms of heat release and weight loss during the coal combustion. This was further proved by non-isothermal kinetic analysis, which was used to evaluate the Arrhenius activation energy corresponding to the co-combustion of the blends. This work shows that thermogravimetric analysis may be used as an easy rapid tool to asses the co-combustion of sewage sludge together with coal. 相似文献