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471.
Yulong Zhang Jianming Wu Liping Chang Junfeng Wang Zhengfeng Li 《Journal of Loss Prevention in the Process Industries》2013,26(6):1221-1229
A study of the initial stage of the low-temperature oxidation of coal is important, not only for the prevention for fires in coal industry, but also in reducing emissions of hazardous gases. A batch reactor was introduced and a series of simulated experiments of coal oxidation was carried out in this paper. The time-dependent rates of CO emission and oxygen consumption during oxidation experiments of coal samples with different particle size ranges were obtained simultaneously from the measurements of CO and O2 concentration in the reactor. The experimental results show that the rate of CO emission presents three stages in the duration of coal oxidation. Based on the rates of oxygen consumption, the reaction order and reaction rate were obtained from the reaction rate equation. These results indicate that the reaction regime switches during coal oxidation in confined spaces. The initial decrease of reaction rate is due to the decrease of the active sites in coal. While the decrease of reaction rate in the following period of coal oxidation is attributed to the reaction-inhibition mechanism of oxidation products. And it is mainly represented by the chemisorption sequence of coal oxidation. The oxidative activity of coal can be restored when the oxidation products are evacuated. A mechanism of low-temperature oxidation of coal in confined spaces was also suggested. 相似文献
472.
The minimum ignition temperature of dust suspension (MIT) and the hot surface ignition temperature of the dust layer (LIT) are essential safety parameters for the process industry. However, the knowledge of the ignition behavior when solid mixtures of flammable fuels and phosphorous-free inhibitors are considered is still scarce and further experimental and theoretical analyses are requested. In this work, the ignition temperature of phosphorous-free inhibitors (coal fly ash and calcium carbonate) mixed with lycopodium dust have been studied in terms of LIT analysis (hot plate thickness: 5 mm, 12.5 mm and 15 mm), and by the Godbert-Greenwald test for the MIT. Both coal fly ash and calcium carbonate have been tested at different concentrations and particle sizes.Results show that the effects of the inhibitor can be counter-productive when layer ignition temperature is considered even if the minimum ignition temperature of the dust suspension shows a positive effect from the safety point of view. This behavior has been analyzed in the terms of thermal conductivity and diffusivity of the mixture, by using Maxwell's equation for two-phase solid mixtures. Standard empirical correlations for the ignition temperature of solid mixtures have been also tested, showing their weakness in reproducing mixture behavior. 相似文献
473.
Devising effective strategies to facilitate waste reuse depends on the solid understanding of reuse behaviors. However, previous studies of reuse behavior have been limited in scope, focusing mostly on household recycling behaviors or very limited types of industrial wastes. To gain a better understanding of the business reuse behaviors, this study examined the impact of various factors in technical, economic, regulatory, and behavioral categories in the case of coal ash generated in the United States. The results of fixed effect models for fly ash and bottom ash particularly showed the significance role of the behavioral factor. In both models, a proxy variable, which represents knowledge sharing among the power plants or the utility's decision-making, turned out to be statistically significant and had the largest coefficient estimates among a group of variables. This finding may imply that the characteristics of waste reuse behavior are determined more by business decision-making behaviors than by market or institutional factors. However, the role of the behavioral variable was stronger in the bottom ash models than in the fly ash models. While the reuse of bottom ash was determined primarily by the behavioral variable, fly ash reuse was determined by more diverse factors including economic and regulatory variables. This could be explained by material characteristics in relation to competing resources and the nature of reuse applications. 相似文献
474.
Yang J 《Environmental geochemistry and health》2006,28(6):567-576
The concentration, mode of occurrence, and origin of trace elements in the Late Permian coals from the Puan Coalfield, southwestern
Guizhou, China, were examined using inductively coupled plasma-mass spectrometry (ICP-MS), X-ray fluorescence (XRF), cold-vapor
atomic absorption spectrometry (CV-AAS), ion-selective electrode method (ISE), sequential chemical extraction procedure (SCEP),
scanning electron microscopy equipped with energy-dispersive X-ray (SEM-EDX), and optical microscope. Results show that minerals
in the No. 2 Coal from the Puan Coalfield were mainly made up of epigenetic pyrite of low-temperature hydrothermal fluid origin
and kaolinite of detrital terrigenous origin. Elements including As (36.9 μg/g), Cd (10.2 μg/g), Cr (167.3 μg/g), Cu (365.4 μg/g),
Hg (2.82 μg/g), Mo (92.6 μg/g), Ni (82.6 μg/g), Pb (184.6 μg/g), Se (6.23 μg/g), Zn (242.3 μg/g), and U (132.7 μg/g) are significantly
enriched in the No. 2 Coal from the Puan Coalfield. However, concentrations of trace elements in the other four coals, the
No. 1, No. 8, No. 11, and No. 18 Coals, were close to the usual ranges found for Guizhou of China, China, and USA. Results
of SEM-EDX and SCEP showed that As, Cd, Hg, Mo, Ni, Pb, and Zn occur mainly in veined pyrite, while Cr, Cu, and U distribute
mainly in kaolinite, indicating that the low-temperature hydrothermal fluid and detrital materials of terrigenous origin are
the main contributors to the enrichment of these trace elements in the No. 2 Coal. 相似文献
475.
476.
兖州矿区循环经济与可持续发展研究 总被引:1,自引:0,他引:1
按照循环经济的理论,结合兖州矿区产业链,提出了兖州矿区循环经济的初步模式和对策。最后,以济三煤矿为例,介绍了兖州矿区循环经济的实践。 相似文献
477.
This paper presents detailed measurements of gaseous species during the reburning process with high CO2 concentration in a bench-scale furnace. Superfine pulverized coal, with the average particle size below or around 20 μm, is used as the reburning fuel. The data of flue gas concentration (NOx, HCN, NH3, CH4, O2, CO, CO2 etc.) is obtained in order to reveal the intrinsic connection between NOx emissions and other influential gaseous species at different positions of the furnace. The finding concludes that the advantage of superfine pulverized coal with regard to NO reduction is more efficient in homogeneous stage rather than heterogeneous stage. Meanwhile, the evolution of HCN and CH4 agrees well with each stage of NO reduction, which indicates that these gaseous species are favorable for NO abatement. Eventually, oxygen consumption rate for superfine pulverized coal is relatively faster, conducive to strengthen both homogeneous and heterogeneous NO reduction under CO2 reburning condition. 相似文献
478.
The lack of microbial degradation of polycyclic aromatic hydrocarbons from coal-rich soils 总被引:1,自引:0,他引:1
Achten C Cheng S Straub KL Hofmann T 《Environmental pollution (Barking, Essex : 1987)》2011,159(2):623-629
Analytical techniques used to assess the environmental risk of contamination from polycyclic aromatic hydrocarbons (PAHs) typically consider only abiotic sample parameters. Supercritical fluid extraction and sorption enthalpy experiments previously suggested slow desorption rates for PAH compounds in two coal-contaminated floodplain soils. In this study, the actual PAH availability for aerobic soil microorganisms was tested in two series of soil-slurry experiments. The experimental conditions supported microbial degradation of phenanthrene if it was weakly sorbed onto silica gel. Native coals and coal-derived particles in two soils effectively acted as very strong sorbents and prevented microbial PAH degradation. The long history of PAH exposure and degree of coal contamination apparently had no influence on the capability of the microbial soil community to overcome constraints of PAH availability. Within the context of the experimental conditions and the compounds chosen, our results confirm that coal-bound PAHs are not bioavailable and hence of low environmental concern. 相似文献
479.
对伊犁地区民用燃煤放射性限值的探讨 总被引:1,自引:0,他引:1
探讨了将煤炭中铀含量10mg/kg作为伊犁地区民用燃煤放射性限制指标的合理性. 相似文献
480.