The contemporary copper cycle of Asia

A regional stock and flow model for an industrial metal was developed based on the substance-flow framework. Using this model, the contemporary copper cycle of the Asian region was constructed by aggregating country-level production and import and export data for different stages of the copper cycle. The reliability and availability of data were assessed both qualitatively and quantitatively. Asia as a region is a net importer of copper. There is a significant build-up of copper in use at a rate of nearly 3TgCu/year. The per capita generation of copper waste (0.4kgCu/(capita-year)) and the rate of secondary recovery of copper are low compared with Europe and North America. Japan's rates of use, waste generation, and recycling of copper are all much larger than the continental average. A tremendous potential exists in the region to utilize the copper content of the in-use reservoir, and subsequently to enhance copper recycling rates in the future. A set of metrics for the copper cycle is suggested in order to address sustainability issues related to resource policy and the environmental management of copper.     

Mechanisms of copper tolerance by Armeria maritima in Dolfrwyong Bog,north Wales--initial studies

Preliminary field studies were carried out at Dolfrwynog Bog in July 2000. Replicate samples of water, Armeria maritima plants and the soils adhering to its roots were collected and analysed for copper. Concentrations of up to 6486 mg kg^–1 of copper in the soils were recorded. Accumulation of copper by the plant as expressed by concentration factors (CF) show that it is acting mainly as a copper excluder. Of the copper that is taken up, most of it is retained within the roots with very little being transported to the shoots of the plant. Moreover, a further possible mechanism of tolerance is exhibited by the excretion of copper through its decaying leaves. Towards the use of in vitro cultures to study the copper tolerance mechanisms in A. maritima a micropropagation protocol has been developed. The ex vitro plants have been rooted and established in compost.     

Toxicity of copper in sewage sludge

Sewage sludge is a source of organic matter and nutrients, but a major obstacle for its recycling is that the municipal wastewater sludge has low but significant levels of contaminants. This investigation, on the acute toxicity of copper in sewage sludge, was conducted with three organisms, Daphnia magna, Lemna minor and Raphanus sativus (seeds). The toxicity of the leakage water from sewage sludge spiked with CuSO(4) was studied for 64 days. The toxicity increased during the first 8-16 days and then started to decrease. The first increase in toxicity was due to ammonia, but after 32 days, a dose-related effect of copper was found. After 64 days, L. minor had an EC50 of 3800 mg Cu/kg dw for 7 days growth inhibition, a LOEC of 3200 mg Cu/kg dw and a NOEC of 1600 mg Cu/kg dw. D. magna had an EC50 of 18100 mg Cu/kg dw (24-h immobility) and a NOEC of 12800 mg Cu/kg dw. Root elongation of R. sativus was reduced at 25600 mg Cu/kg dw. Both for Daphnia and Lemna, the pH of the leakage water had an effect of the toxicity. This means that chemical speciation and bioavailability is very important for the hazard assessment of copper in sludge and soil.     

栽种沙枣以改善黄河三角洲地区生态环境

胜利油田位于我国黄河三角洲地区，潜水位高，水的矿化度大。生态环境恶劣，对植物尤其对木本植物的生长不利，整个地区生长的多是抗盐碱能力强的草本植物。针对油田的特殊环境条件，综合有关资料，介绍了以沙枣为代表的植物特性，特别强调了其抗盐碱、降低土壤矿化度和潜水位、增加土壤有机质和引起植被变化的特性。指出黄河三角洲也有些土质较好的、适于作物和木本植物生长的地区，改良盐碱地可以以这些地区为基点，放射性地向外逐步试验沙枣的种植，以探索改善生态环境的途径。努力做到边发展经济，边改善环境，达到经济效益、社会效益和环境效益三统一。     

催化动力学光度法测定痕量铜（Ⅱ）

研究了在稀硫酸介质中，用α，α‘－联吡啶作活化剂，痕量铜催化高碘酸钾氧化茂红Ｔ的褪色反应及动力学条件，建立了催化动力学光度法测定痕量铜的方法。检测限为０．４１μｇ／ＬＣｕ，线性范围为０－０．８μｇ／２５ｍＬＣｕ。方法操作简单，灵敏度高，准确性好，可用于水质及人发中痕量铜的测定，结果满意。     

火焰原子吸收法间接测定环境水中的硫化物

利用空气-乙炔火焰原子吸收法间接测定水中硫化物,方法适用于环境水中硫化物的测定.用改进后的装置进行预处理,样品中加入10ml磷酸,用氮气作载气将生成的硫化氢吹出,载气流量50ml/min,吹气40min.用pH4.5的乙酸-乙酸钠缓冲介质中的Cu(Ⅱ)作吸收液,并加入95％的乙醇作气泡分散剂.测定吸收液水相中剩余的Cu(Ⅱ),以达到间接测定硫化物的目的.方法相对标准偏差为1.6％～3.4％,检测下限0.02mg/L.     

Niche separation in two species of hare. Metabolic costs of plant phenolics

Summary The distributions of mountain hare (Lepus timidus) and European hare (L. europaeus) overlap in central Sweden, but they occupy separate food niches in winter. In Scandinavia, the European hare is mainly a grazer while mountain hare is a predominant browser. Browse contain high amounts of secondary metabolites, such as phenols, compared to grass. This raises the question if the two hare species differ in their metabolic tolerance of plant phenols and that these differences influence their food choice.Phenolic excretion in urine increased significantly with phenolic intake in both species. Excretion of glucuronic acid conjugates, one of the major pathways of elimination of phenols in both hare species, is positively correlated to phenolic intake and excretion. However, the extent of excretion of phenolics by this route was different in the two species of hare. European hares excreted substantially more glucuronic acid per amount of phenolics than mountain hare. The phenols were metabolized to a larger extent in the mountain hare, indicating a higher detoxification capacity. From these results it is likely that European hare have a higher cost for the detoxification of plant phenols compared to mountain hare. This cost and negative effect on sodium balance when feeding on browse may prevent exploitation of forest habitats by European hares, whereas mountain hare are better able to do so.     

Population differences in susceptibility to stress in Littorina saxatilis from metal contaminated and uncontaminated sites in the Isle of Man

Introduction Pollution-induced stress indices at various levels of organization, from sub-cellular to organism al level, have been investigated as a m eans of identifying and m onitoring environm ental contam ination. Since changes elicited by toxic m aterials m ust occur at the biochem ical, cellular and tissue levels of organization before effects w ould be observed at the organism al level, such m easures have been suggested as potential short-term , functional indices w hich can be used to…     

直升机尾部结构疲劳及缺陷容限试验装置研制及应用

目的 获得尾部结构的疲劳寿命和检查周期,满足民用直升机适航验证要求,保证飞机的飞行安全,开展复合材料尾部结构疲劳及缺陷容限试验技术研究。方法 介绍了尾部结构疲劳及缺陷容限试验专用试验台、气动冲击设备、柔性自动特征扫描成像无损检测系统等的设计及研制,采用研制的成套试验装置,实现尾部结构试验件连接约束和载荷边界的全面真实模拟、复杂载荷谱的精确控制、冲击损伤缺陷预制及缺陷自动识别与检测。结果 经试验验证,载荷误差小于2%,冲击能量误差小于2%,缺陷检测误差小于1 mm,各项指标都满足项目研究目标和技术指标要求。结论 研究成果在民用直升机研制中得到了成功应用,可为后续其他直升机尾部结构疲劳及缺陷容限疲劳试验提供良好的借鉴,具有重要的工程应用价值。     

植物铝胁迫发生机制及其内在缓解途径研究进展

本文总结了土壤中铝的存在形式及其化学行为,分析了以针叶人工林为例的诱发植物铝胁迫效应的内外部机制,以及铝胁迫在不同生态水平上对植物生长的影响。比较了环境铝胁迫下,植物体自身缓解环境铝威胁的不同途径。